Nanotechnology Now

Our NanoNews Digest Sponsors
Heifer International



Home > Press > Gas storage method could help next-generation clean energy vehicles: Tremendous amounts of hydrogen and methane can be stored in nanoscopic pores

A one-gram sample of the Northwestern material (with a volume of six M&Ms) has a surface area that would cover 1.3 football fields. (Credit: Northwestern University)
A one-gram sample of the Northwestern material (with a volume of six M&Ms) has a surface area that would cover 1.3 football fields. (Credit: Northwestern University)

Abstract:
•New materials are safer and less expensive than conventional materials
•Structure of modified organic frameworks is like Tinkertoys
•The surface area of more than a football field fits in one gram of the material

Gas storage method could help next-generation clean energy vehicles: Tremendous amounts of hydrogen and methane can be stored in nanoscopic pores

Evanston, IL | Posted on April 17th, 2020

A research team led by Northwestern University has designed and synthesized new materials with ultrahigh porosity and surface area for the storage of hydrogen and methane for fuel cell-powered vehicles. These gases are attractive clean energy alternatives to carbon dioxide-producing fossil fuels.

The designer materials, a type of a metal-organic framework (MOF), can store significantly more hydrogen and methane than conventional adsorbent materials at much safer pressures and at much lower costs.



“We’ve developed a better onboard storage method for hydrogen and methane gas for next-generation clean energy vehicles,” said Omar K. Farha, who led the research. “To do this, we used chemical principles to design porous materials with precise atomic arrangement, thereby achieving ultrahigh porosity.”



Adsorbents are porous solids which bind liquid or gaseous molecules to their surface. Thanks to its nanoscopic pores, a one-gram sample of the Northwestern material (with a volume of six M&Ms) has a surface area that would cover 1.3 football fields.



The new materials also could be a breakthrough for the gas storage industry at large, Farha said, because many industries and applications require the use of compressed gases such as oxygen, hydrogen, methane and others.



Farha is an associate professor of chemistry in the Weinberg College of Arts and Sciences. He also is a member of Northwestern’s International Institute for Nanotechnology.



The study, combining experiment and molecular simulation, will be published on April 17 by the journal Science.



Farha is the lead and corresponding author. Zhijie Chen, a postdoctoral fellow in Farha’s group, is co-first author. Penghao Li, a postdoctoral fellow in the lab of Sir Fraser Stoddart, Board of Trustees Professor of Chemistry at Northwestern, also is a co-first author. Stoddart is an author on the paper.



The ultraporous MOFs, named NU-1501, are built from organic molecules and metal ions or clusters which self-assemble to form multidimensional, highly crystalline, porous frameworks. To picture the structure of a MOF, Farha said, envision a set of Tinkertoys in which the metal ions or clusters are the circular or square nodes and the organic molecules are the rods holding the nodes together.



Hydrogen- and methane-powered vehicles currently require high-pressure compression to operate. The pressure of a hydrogen tank is 300 times greater than the pressure in car tires. Because of hydrogen’s low density, it is expensive to accomplish this pressure, and it also can be unsafe because the gas is highly flammable.



Developing new adsorbent materials that can store hydrogen and methane gas onboard vehicles at much lower pressures can help scientists and engineers reach U.S. Department of Energy targets for developing the next generation of clean energy automobiles.



To meet these goals, both the size and weight of the onboard fuel tank need to be optimized. The highly porous materials in this study balance both the volumetric (size) and gravimetric (mass) deliverable capacities of hydrogen and methane, bringing researchers one step closer to attaining these targets.



“We can store tremendous amounts of hydrogen and methane within the pores of the MOFs and deliver them to the engine of the vehicle at lower pressures than needed for current fuel cell vehicles,” Farha said.



The Northwestern researchers conceived the idea of their MOFs and, in collaboration with computational modelers at the Colorado School of Mines, confirmed that this class of materials is very intriguing. Farha and his team then designed, synthesized and characterized the materials. They also collaborated with scientists at the National Institute for Standards and Technology (NIST) to conduct high-pressure gas sorption experiments.



The research was supported by the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (award no. DE‐EE0008816).

####

For more information, please click here

Copyright © Northwestern University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

The title of the paper is “Balancing volumetric and gravimetric uptake in highly porous materials for clean energy.”:

Related News Press

News and information

New method in the fight against forever chemicals September 13th, 2024

Energy transmission in quantum field theory requires information September 13th, 2024

Breakthrough in proton barrier films using pore-free graphene oxide: Kumamoto University researchers achieve new milestone in advanced coating technologies September 13th, 2024

Quantum researchers cause controlled ‘wobble’ in the nucleus of a single atom September 13th, 2024

Govt.-Legislation/Regulation/Funding/Policy

Giving batteries a longer life with the Advanced Photon Source: New research uncovers a hydrogen-centered mechanism that triggers degradation in the lithium-ion batteries that power electric vehicles September 13th, 2024

New discovery aims to improve the design of microelectronic devices September 13th, 2024

Physicists unlock the secret of elusive quantum negative entanglement entropy using simple classical hardware August 16th, 2024

Single atoms show their true color July 5th, 2024

Possible Futures

Rice research could make weird AI images a thing of the past: New diffusion model approach solves the aspect ratio problem September 13th, 2024

Giving batteries a longer life with the Advanced Photon Source: New research uncovers a hydrogen-centered mechanism that triggers degradation in the lithium-ion batteries that power electric vehicles September 13th, 2024

NYU Abu Dhabi researchers develop novel covalent organic frameworks for precise cancer treatment delivery: NYU Abu Dhabi researchers develop novel covalent organic frameworks for precise cancer treatment delivery September 13th, 2024

New discovery aims to improve the design of microelectronic devices September 13th, 2024

Announcements

Giving batteries a longer life with the Advanced Photon Source: New research uncovers a hydrogen-centered mechanism that triggers degradation in the lithium-ion batteries that power electric vehicles September 13th, 2024

NYU Abu Dhabi researchers develop novel covalent organic frameworks for precise cancer treatment delivery: NYU Abu Dhabi researchers develop novel covalent organic frameworks for precise cancer treatment delivery September 13th, 2024

New discovery aims to improve the design of microelectronic devices September 13th, 2024

New method in the fight against forever chemicals September 13th, 2024

Environment

New method in the fight against forever chemicals September 13th, 2024

Catalyzing environmental cleanup: A highly active and selective molecular catalyst and electrified membrane: Innovative electrochemical catalyst breaks down trichloroethylene pollutants at unprecedented rate September 13th, 2024

$900,000 awarded to optimize graphene energy harvesting devices: The WoodNext Foundation's commitment to U of A physicist Paul Thibado will be used to develop sensor systems compatible with six different power sources January 12th, 2024

Catalytic combo converts CO2 to solid carbon nanofibers: Tandem electrocatalytic-thermocatalytic conversion could help offset emissions of potent greenhouse gas by locking carbon away in a useful material January 12th, 2024

Energy

Unveiling the power of hot carriers in plasmonic nanostructures August 16th, 2024

Groundbreaking precision in single-molecule optoelectronics August 16th, 2024

Development of zinc oxide nanopagoda array photoelectrode: photoelectrochemical water-splitting hydrogen production January 12th, 2024

Shedding light on unique conduction mechanisms in a new type of perovskite oxide November 17th, 2023

Dental

Getting to the root of tooth replantation challenges: Researchers from Tokyo Medical and Dental University (TMDU) report a delivery system that promotes healing in tooth replantation in rats September 17th, 2021

Innovations in dentistry: Navigational surgery, robotics, and nanotechnology October 2nd, 2020

First measurement of electron energy distributions, could enable sustainable energy technologies June 5th, 2020

Novel nanoparticle-based approach detects and treats oral plaque without drugs August 17th, 2018

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project