Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > ORNL scientists crack materials mystery in vanadium dioxide

Theoretical research at Oak Ridge National Laboratory can help explain experimental results in vanadium dioxide, such as the formation of thin conductive channels (seen in white) that can appear under strain in a nanoscale vanadium dioxide sample.
Theoretical research at Oak Ridge National Laboratory can help explain experimental results in vanadium dioxide, such as the formation of thin conductive channels (seen in white) that can appear under strain in a nanoscale vanadium dioxide sample.

Abstract:
A systematic study of phase changes in vanadium dioxide has solved a mystery that has puzzled scientists for decades, according to researchers at the Department of Energy's Oak Ridge National Laboratory.

ORNL scientists crack materials mystery in vanadium dioxide

Oak Ridge, TN | Posted on November 24th, 2010

Scientists have known that vanadium dioxide exhibits several competing phases when it acts as an insulator at lower temperatures. However, the exact nature of the phase behavior has not been understood since research began on vanadium dioxide in the early 1960s.

Alexander Tselev, a research associate from the University of Tennessee-Knoxville working with ORNL's Center for Nanophase Materials Sciences, in collaboration with Igor Luk'yanchuk from the University of Picardy in France used a condensed matter physics theory to explain the observed phase behaviors of vanadium dioxide, a material of significant technological interest for optics and electronics.

"We discovered that the competition between several phases is purely driven by the lattice symmetry," Tselev said. "We figured out that the metallic phase lattice of vanadium oxide can 'fold' in different ways while cooling, so what people observed was different types of its folding."

Vanadium dioxide is best known in the materials world for its speedy and abrupt phase transition that essentially transforms the material from a metal to an insulator. The phase change takes place at about 68 degrees Celsius.

"These features of electrical conductivity make vanadium dioxide an excellent candidate for numerous applications in optical, electronic and optoelectronic devices," Tselev said.

Devices that might take advantage of the unusual properties of VO2 include lasers, motion detectors and pressure detectors, which could benefit from the increased sensitivity provided by the property changes of vanadium dioxide. The material is already used in technologies such as infrared sensors.

Researchers said their theoretical work could help guide future experimental research in vanadium dioxide and ultimately aid the development of new technologies based on VO2.

"In physics, you always want to understand how the material ticks," said Sergei Kalinin, a senior scientist at the CNMS. "The thermodynamic theory will allow you to predict how the material will behave in different external conditions."

The results were published in the American Chemical Society's Nano Letters. The research team also included Ilia Ivanov, John Budai and Jonathan Tischler at ORNL and Evgheni Strelcov and Andrei Kolmakov at Southern Illinois University.

The team's theoretical research expands upon previous experimental ORNL studies with microwave imaging that demonstrated how strain and changes of crystal lattice symmetry can produce thin conductive wires in nanoscale vanadium dioxide samples.

This research was supported in part by the Department of Energy's Office of Science and by the National Science Foundation. Researchers also used instrumentation at the Office of Science-supported Center for Nanophase Materials Sciences and Advanced Photon Source User Facilities at Oak Ridge and Argonne national laboratories, respectively.

####

About Oak Ridge National Laboratory
CNMS is one of the five DOE Nanoscale Science Research Centers, premier national user facilities for interdisciplinary research at the nanoscale supported by the DOE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please visit nano.energy.gov. ORNL is managed by UT-Battelle for the Department of Energy's Office of Science.

For more information, please click here

Contacts:
Media Contact: Morgan McCorkle
Communications and External Relations
865.574.7308

Copyright © Oak Ridge National Laboratory

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

In borophene, boundaries are no barrier: Rice U., Northwestern researchers make and test atom-thick boron's unique domains July 17th, 2018

Tuning into quantum: Scientists unlock signal frequency control of precision atom qubits July 16th, 2018

Nano-kirigami: 'Paper-cut' provides model for 3D intelligent nanofabrication July 13th, 2018

UMBC researchers develop nanoparticles to reduce internal bleeding caused by blast trauma July 13th, 2018

Physics

A refined magnetic sense: Algorithms and hardware developed in the context of quantum computation are shown to be useful for quantum-enhanced sensing of magnetic fields July 2nd, 2018

Evidence for a new property of quantum matter revealed: Electrical dipole activity detected in a quantum material unlike any other tested June 11th, 2018

Theory gives free rein to superconductivity at room temperature May 28th, 2018

Scientists Pinpoint Energy Flowing Through Vibrations in Superconducting Crystals: Interactions between electrons and the atomic structure of high-temperature superconductors impacted by elusive and powerful vibrations May 4th, 2018

Govt.-Legislation/Regulation/Funding/Policy

In borophene, boundaries are no barrier: Rice U., Northwestern researchers make and test atom-thick boron's unique domains July 17th, 2018

Tuning into quantum: Scientists unlock signal frequency control of precision atom qubits July 16th, 2018

Nano-kirigami: 'Paper-cut' provides model for 3D intelligent nanofabrication July 13th, 2018

Carbon is the new black: Researchers use carbon nanotubes to develop clothing that can double as batteries July 10th, 2018

Academic/Education

The Institute of Applied Physics at the University of Tsukuba near Tokyo in Japan uses Deben's ARM2 detector to better understand catalytic reaction mechanisms June 27th, 2018

Powering the 21st Century with Integrated Photonics: UCSB-Led Team Selected for Demonstration of a Novel Waveguide Platform Which is Transparent Throughout the MWIR and LWIR Spectral Bands June 19th, 2018

SUNY Poly Professor Eric Lifshin Selected for ‘Fellow of the Microanalysis Society’ Position for Significant Contributions to Microanalysis June 13th, 2018

Grand Opening of UC Irvine Materials Research Institute (IMRI) to Spotlight JEOL Center for Nanoscale Solutions: Renowned Materials Scientists to Present at the 1st International Symposium on Advanced Microscopy and Spectroscopy (ISAMS) April 18th, 2018

Nanoelectronics

GLOBALFOUNDRIES Surpasses $2 Billion in Design Win Revenue on 22FDX® Technology : With 50 client designs and growing, 22FDX proves its value as a cost-effective solution for power-sensitive applications July 9th, 2018

High-power electronics keep their cool with new heat-conducting crystals July 6th, 2018

Leti Presenting Strategic Vision and Hosting a Workshop at SEMICON West: “From Electrons to Photons” Leti Workshop and CEO Media Briefing Set for Tuesday, July 10 in W Hotel, San Francisco June 12th, 2018

Quantum Interference May Be Key to Smaller Insulators: Breakthrough could jumpstart further miniaturization of transistors June 6th, 2018

Discoveries

In borophene, boundaries are no barrier: Rice U., Northwestern researchers make and test atom-thick boron's unique domains July 17th, 2018

Tuning into quantum: Scientists unlock signal frequency control of precision atom qubits July 16th, 2018

Nano-kirigami: 'Paper-cut' provides model for 3D intelligent nanofabrication July 13th, 2018

UMBC researchers develop nanoparticles to reduce internal bleeding caused by blast trauma July 13th, 2018

Announcements

In borophene, boundaries are no barrier: Rice U., Northwestern researchers make and test atom-thick boron's unique domains July 17th, 2018

Tuning into quantum: Scientists unlock signal frequency control of precision atom qubits July 16th, 2018

Nano-kirigami: 'Paper-cut' provides model for 3D intelligent nanofabrication July 13th, 2018

UMBC researchers develop nanoparticles to reduce internal bleeding caused by blast trauma July 13th, 2018

Photonics/Optics/Lasers

SUNY Poly-Led AIM Photonics and Partners Attend SEMICON West 2018 to Showcase High-Tech Advances, Collaboration, and Future R&D Opportunities: New York’s Tech Valley Makes a Major Showing in Silicon Valley July 3rd, 2018

Cleaning or Etching Items with Unique Geometries Requires Specialized Expertise June 27th, 2018

Powering the 21st Century with Integrated Photonics: UCSB-Led Team Selected for Demonstration of a Novel Waveguide Platform Which is Transparent Throughout the MWIR and LWIR Spectral Bands June 19th, 2018

Executives Explore Key Megatrends and Innovations in MEMS, Sensors, Imaging Tech at SEMI-MSIG European Summits: Speakers to share developments in smart automotive, smart cities, smart industrial, biomedical, consumer and IoT, September 19-21, 2018 in Grenoble, France June 19th, 2018

Research partnerships

In borophene, boundaries are no barrier: Rice U., Northwestern researchers make and test atom-thick boron's unique domains July 17th, 2018

Nano-kirigami: 'Paper-cut' provides model for 3D intelligent nanofabrication July 13th, 2018

Leti and Soitec Launch a New Substrate Innovation Center to Develop Engineered Substrate Solutions: Industry-inclusive hub promotes early collaboration and learning from substrate to system level July 11th, 2018

Leti & Partners Launch Pilot Program to Assess New Perception Sensors for Autonomous Vehicles July 5th, 2018

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project