Home > Press > UCSB researchers identify specific defects in LED diodes that lead to less efficient solid state lighting
A conceptual illustration of how defects in a crystal lattice might contribute to nonradiative recombination of electrons and holes in LEDs. CREDIT: Peter Allen/UCSB illustration |
Abstract:
Using state-of-the-art theoretical methods, UCSB researchers have identified a specific type of defect in the atomic structure of a light-emitting diode (LED) that results in less efficient performance. The characterization of these point defects could result in the fabrication of even more efficient, longer lasting LED lighting.
"Techniques are available to assess whether such defects are present in the LED materials and they can be used to improve the quality of the material," said materials professor Chris Van de Walle, whose research group carried out the work.
In the world of high-efficiency solid-state lighting, not all LEDs are alike. As the technology is utilized in a more diverse array of applications -- including search and rescue, water purification and safety illumination, in addition to their many residential, industrial and decorative uses -- reliability and efficiency are top priorities. Performance, in turn, is heavily reliant on the quality of the semiconductor material at the atomic level.
"In an LED, electrons are injected from one side, holes from the other," explained Van de Walle. As they travel across the crystal lattice of the semiconductor -- in this case gallium-nitride-based material -- the meeting of electrons and holes (the absence of electrons) is what is responsible for the light that is emitted by the diode: As electron meets hole, it transitions to a lower state of energy, releasing a photon along the way.
Occasionally, however, the charge carriers meet and do not emit light, resulting in the so-called Shockley-Read-Hall (SRH) recombination. According to the researchers, the charge carriers are captured at defects in the lattice where they combine, but without emitting light.
The defects identified involve complexes of gallium vacancies with oxygen and hydrogen. "These defects had been previously observed in nitride semiconductors, but until now, their detrimental effects were not understood," explained lead author Cyrus Dreyer, who performed many of the calculations on the paper.
"It was the combination of the intuition that we have developed over many years of studying point defects with these new theoretical capabilities that enabled this breakthrough," said Van de Walle, who credits co-author Audrius Alkauskas with the development of a theoretical formalism necessary to calculate the rate at which defects capture electrons and holes.
The method lends itself to future work identifying other defects and mechanisms by which SRH recombination occurs, said Van de Walle.
"These gallium vacancy complexes are surely not the only defects that are detrimental," he said. "Now that we have the methodology in place, we are actively investigating other potential defects to assess their impact on nonradiative recombination."
###
This work was funded by U. S. Department of Energy Office of Science, and by Marie Sklodowska-Curie Action of the European Union.
####
For more information, please click here
Contacts:
Sonia Fernandez
805-893-4765
Copyright © University of California, Santa Barbara
If you have a comment, please Contact us.Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.
Related Links |
Related News Press |
News and information
Simulating magnetization in a Heisenberg quantum spin chain April 5th, 2024
NRL charters Navy’s quantum inertial navigation path to reduce drift April 5th, 2024
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
Good as gold - improving infectious disease testing with gold nanoparticles April 5th, 2024
Display technology/LEDs/SS Lighting/OLEDs
Utilizing palladium for addressing contact issues of buried oxide thin film transistors April 5th, 2024
Light guide plate based on perovskite nanocomposites November 3rd, 2023
Simple ballpoint pen can write custom LEDs August 11th, 2023
Govt.-Legislation/Regulation/Funding/Policy
NRL charters Navy’s quantum inertial navigation path to reduce drift April 5th, 2024
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
Chemical reactions can scramble quantum information as well as black holes April 5th, 2024
Possible Futures
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
With VECSELs towards the quantum internet Fraunhofer: IAF achieves record output power with VECSEL for quantum frequency converters April 5th, 2024
Discoveries
Chemical reactions can scramble quantum information as well as black holes April 5th, 2024
New micromaterial releases nanoparticles that selectively destroy cancer cells April 5th, 2024
Utilizing palladium for addressing contact issues of buried oxide thin film transistors April 5th, 2024
Announcements
NRL charters Navy’s quantum inertial navigation path to reduce drift April 5th, 2024
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers/Posters
Simulating magnetization in a Heisenberg quantum spin chain April 5th, 2024
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
Research partnerships
Discovery points path to flash-like memory for storing qubits: Rice find could hasten development of nonvolatile quantum memory April 5th, 2024
Researchers’ approach may protect quantum computers from attacks March 8th, 2024
'Sudden death' of quantum fluctuations defies current theories of superconductivity: Study challenges the conventional wisdom of superconducting quantum transitions January 12th, 2024
The latest news from around the world, FREE | ||
Premium Products | ||
Only the news you want to read!
Learn More |
||
Full-service, expert consulting
Learn More |
||