Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Novel 'crumpling' of hybrid nanostructures increases SERS sensitivity

Illustration of SERS enhancement from a crumpled graphene-Au nanoparticles hybrid structure. Raman spectrum is enhanced the most when the target molecule is situated at the center of Au nanoparticles in valley of crumpled graphene as depicted in inset.
CREDIT: University of Illinois
Illustration of SERS enhancement from a crumpled graphene-Au nanoparticles hybrid structure. Raman spectrum is enhanced the most when the target molecule is situated at the center of Au nanoparticles in valley of crumpled graphene as depicted in inset.

CREDIT: University of Illinois

Abstract:
By "crumpling" to increase the surface area of graphene-gold nanostructures, researchers from the University of Illinois at Urbana-Champaign have improved the sensitivity of these materials, opening the door to novel opportunities in electronics and optical sensing applications.

Novel 'crumpling' of hybrid nanostructures increases SERS sensitivity

Urbana, IL | Posted on November 4th, 2015

"I believe that this work will benefit researchers in the area of surface plasmonics by providing a new strategy/design for enhancing the surface enhanced Raman spectroscopy (SERS) detection limit," explained SungWoo Nam, an assistant professor of mechanical science and engineering at Illinois. "This mechanical self-assembly strategy will enable a new class of 3D crumpled graphene?gold (Au) nanostructures. The enhanced limit of detection will allow biomedical and environment monitoring of important molecules at high sensitivity by SERS."

SERS substrates are used to analyze the composition of a mixture at the nanoscale for environmental analysis, pharmaceuticals, material sciences, art and archeological research, forensic science, drug detection, food quality analysis, and single cell detection. Using a combination of gold and silver nanoparticles and Raman-active dyes, SERS substrates also can target specific DNA and RNA sequences.

"This work demonstrates the unique capability of micro-to-nanoscale topographies of the crumpled graphene-Au nanoparticles--higher density, three-dimensional optically active materials--that are further enhanced by the formation of hot spots, bringing the nanoparticles closer," explained Juyoung Leem, a graduate student and first author of the study, "Mechanically Self-Assembled, Three-Dimensional Graphene?Gold Hybrid Nanostructures for Advanced Nanoplasmonic Sensors," published in Nano Letters. "We achieve a 3D crumpled graphene?Au hybrid structure by the delamination and buckling of graphene on a thermally activated, shrinking polymer substrate. This process enables precise control and optimization of the size and spacing of integrated Au nanoparticles on crumpled graphene for higher SERS enhancement."

According to Nam, the 3D crumpled graphene?Au nanostructure exhibits at least one order of magnitude higher SERS detection sensitivity than that of conventional, flat graphene?Au nanoparticles. The hybrid structure is further adapted to arbitrary curvilinear structures for advanced, in situ, nonconventional, nanoplasmonic sensing applications.

"One of the key advantages of our platform is its ability to shrink and adapt to complex 3D surfaces, a function that has not been previously demonstrated," Nam stated. An earlier study by Nam's research group was the first to demonstrate graphene integration onto a variety of different microstructured geometries, including pyramids, pillars, domes, inverted pyramids, and the 3D integration of gold nanoparticle/graphene hybrid structures.

###

In addition to Leem and Nam, the study's co-authors include post-doctoral researcher Pilgyu Kang and graduate student Michael Cai Wang in the Department of Mechanical Sciences and Engineering. Experiments were carried out in part in the Frederick Seitz Materials Research Laboratory, the Micro and Nano Technology Laboratory, and the Beckman Institute Imaging Technology Group at Illinois.

####

For more information, please click here

Contacts:
SungWoo Nam

217-300-0267

Copyright © University of Illinois

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

X-ray photoelectron spectroscopy under real ambient pressure conditions June 28th, 2017

Nanometrics to Participate in the 9th Annual CEO Investor Summit 2017: Accredited investor and publishing research analyst event held concurrently with SEMICON West and Intersolar 2017 in San Francisco June 27th, 2017

NMRC, University of Nottingham chooses the Quorum Q150 coater for its reliable and reproducible film thickness when coating samples with iridium June 27th, 2017

Picosunís ALD solutions enable novel high-speed memories June 27th, 2017

Graphene/ Graphite

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

Thought Leaders and Experts Join National Graphene Association Advisory Board June 16th, 2017

Seeing the invisible with a graphene-CMOS integrated device June 6th, 2017

Graphene and quantum dots put in motion a CMOS-integrated camera that can see the invisible May 29th, 2017

Govt.-Legislation/Regulation/Funding/Policy

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Research accelerates quest for quicker, longer-lasting electronics: UC Riverside-led research makes topological insulators magnetic well above room temperatures June 25th, 2017

U.S. Air Force Research Lab Taps IBM to Build Brain-Inspired AI Supercomputing System: Equal to 64 million neurons, new neurosynaptic supercomputing system will power complex AI tasks at unprecedented speed and energy efficiency June 23rd, 2017

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

Chip Technology

Nanometrics to Participate in the 9th Annual CEO Investor Summit 2017: Accredited investor and publishing research analyst event held concurrently with SEMICON West and Intersolar 2017 in San Francisco June 27th, 2017

New TriboLab CMP Provides Cost-Effective Characterization of Chemical Mechanical Wafer Polishing Processes: Bruker Updates Industry-Standard CP-4 Platform for Most Flexible and Reliable Testing June 27th, 2017

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Research accelerates quest for quicker, longer-lasting electronics: UC Riverside-led research makes topological insulators magnetic well above room temperatures June 25th, 2017

Optical computing/Photonic computing

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Learning with light: New system allows optical ďdeep learningĒ: Neural networks could be implemented more quickly using new photonic technology June 12th, 2017

Researchers find new way to control light with electric fields May 25th, 2017

Plasmon-powered upconversion nanocrystals for enhanced bioimaging and polarized emission: Plasmonic gold nanorods brighten lanthanide-doped upconversion superdots for improved multiphoton bioimaging contrast and enable polarization-selective nonlinear emissions for novel nanoscal May 19th, 2017

Sensors

Bosch announces high-performance MEMS acceleration sensors for wearables June 27th, 2017

Letiís Autonomous-Vehicle System Embedded in Infineonís AURIX Platform: Letiís Low-Power, Multi-Sensor System that Transforms Distance Data into Clear Information About the Driving Environment Will Be Demonstrated at ITS Meeting in Strasbourg, June 19-22 June 20th, 2017

New diode features optically controlled capacitance: Israeli researchers have developed a new optically tunable capacitor with embedded metal nanoparticles, creating a metal-insulator-semiconductor diode that is tunable by illumination. June 8th, 2017

Graphene and quantum dots put in motion a CMOS-integrated camera that can see the invisible May 29th, 2017

Discoveries

X-ray photoelectron spectroscopy under real ambient pressure conditions June 28th, 2017

Physicists make quantum leap in understanding life's nanoscale machinery June 27th, 2017

Picosunís ALD solutions enable novel high-speed memories June 27th, 2017

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Materials/Metamaterials

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

Alloying materials of different structures offers new tool for controlling properties June 19th, 2017

Smart materials used in ultrasound behave similar to water, Penn chemists report June 16th, 2017

Announcements

X-ray photoelectron spectroscopy under real ambient pressure conditions June 28th, 2017

Nanometrics to Participate in the 9th Annual CEO Investor Summit 2017: Accredited investor and publishing research analyst event held concurrently with SEMICON West and Intersolar 2017 in San Francisco June 27th, 2017

NMRC, University of Nottingham chooses the Quorum Q150 coater for its reliable and reproducible film thickness when coating samples with iridium June 27th, 2017

Picosunís ALD solutions enable novel high-speed memories June 27th, 2017

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers

X-ray photoelectron spectroscopy under real ambient pressure conditions June 28th, 2017

Physicists make quantum leap in understanding life's nanoscale machinery June 27th, 2017

Picosunís ALD solutions enable novel high-speed memories June 27th, 2017

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Military

Atomic imperfections move quantum communication network closer to reality June 25th, 2017

Research accelerates quest for quicker, longer-lasting electronics: UC Riverside-led research makes topological insulators magnetic well above room temperatures June 25th, 2017

U.S. Air Force Research Lab Taps IBM to Build Brain-Inspired AI Supercomputing System: Equal to 64 million neurons, new neurosynaptic supercomputing system will power complex AI tasks at unprecedented speed and energy efficiency June 23rd, 2017

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

Photonics/Optics/Lasers

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

New carbon nitride material coupled with ruthenium enhances visible-light CO2 reduction in water June 15th, 2017

Changing the color of laser light on the femtosecond time scale: How BiCoO3 achieves second harmonic generation June 14th, 2017

Learning with light: New system allows optical ďdeep learningĒ: Neural networks could be implemented more quickly using new photonic technology June 12th, 2017

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project