Nanotechnology Now

Our NanoNews Digest Sponsors
Heifer International



Home > Press > Making dreams come true: Making graphene from plastic?

How to manufacture transparent and conductive carbon nanosheet using PIM-1 polymer solution: (a) Quart substrate is being coated with PIM-1 polymer solution with ladder structure and conducts heating in high temperature to manufacture carbon nanosheet. Without any additional process OSC (organic solar cell) can be made directly on the sheet to manufacture solar cells. (b), (c), (d) show thickness, surface resistivity and transparency of the carbon nanosheet, respectively in relation to the concentration of PIM-1. Also, the new method easily controls the unwanted effects from the electronic and optical characteristics of carbon nanosheet, which is produced when the polymer solution is concentrated. As the high molecule solution concentration gets higher as shown in (Axis X, (b),(c)), the thicker it gets as shown in Figure (b) but, it becomes less resistant as shown in Figure (c), and the current flow better.
How to manufacture transparent and conductive carbon nanosheet using PIM-1 polymer solution: (a) Quart substrate is being coated with PIM-1 polymer solution with ladder structure and conducts heating in high temperature to manufacture carbon nanosheet. Without any additional process OSC (organic solar cell) can be made directly on the sheet to manufacture solar cells. (b), (c), (d) show thickness, surface resistivity and transparency of the carbon nanosheet, respectively in relation to the concentration of PIM-1. Also, the new method easily controls the unwanted effects from the electronic and optical characteristics of carbon nanosheet, which is produced when the polymer solution is concentrated. As the high molecule solution concentration gets higher as shown in (Axis X, (b),(c)), the thicker it gets as shown in Figure (b) but, it becomes less resistant as shown in Figure (c), and the current flow better.

Abstract:
Graphene is gaining heated attention, dubbed a "wonder material" with great conductivity, flexibility and durability. However, graphene is hard to come by due to the fact that its manufacturing process is complicated and mass production not possible. Recently, a domestic research team developed a carbon material without artificial defects commonly found during the production process of graphene while maintaining its original characteristics. The newly developed material can be used as a substitute for graphene in solar cells and semiconductor chips. Further, the developed process is based on the continuous and mass-produced process of carbon fiber, making it much easier for full-scale commercialization. In recognition of the innovative approach, the research was introduced on the cover of Nanoscale, a high impacting peer-reviewed journal in the field of nano science.

Making dreams come true: Making graphene from plastic?

Seoul, South Korea | Posted on July 2nd, 2014

The research team led by Dr. Han-Ik Joh at KIST along with Dr. Seok-In Na at Chonbuk National University and Dr. Byoung Gak Kim at KRICT synthesized carbon nanosheets similar to graphene using polymer, and directly used the transparent electrodes for organic solar cells. The research outcome was introduced in Nanoscale, a journal of Royal Society of Chemistry in the UK under the title of "One-step Synthesis of Carbon Nanosheets Converted from a Polycylic Compound and Their Direct Use as Transparent Electrodes of ITO-free Organic Solar Cells" and was selected as a cover story in the January 21st edition in recognition for this innovative and superb research findings.

To manufacture high quality graphene in large volume, the CVD (chemical vapor deposition)* method is widely used. However, this method requires intensive post-processing (transfer process) as it has to remove used metal after the manufacturing process and move the manufactured graphene to another board such as a solar cell substrate. In this process the quality quickly degrades as it is prone to wrinkles or cracks.
* CVD (Chemical Vapor Deposition): It is a method of manufacturing graphene on the board of metal film that serves as a catalyst. It manufactures the material by blowing out gas called the source gas onto the board. After it is done the metal has to be removed and graphene has to be transported to another board.

The research team developed "carbon nanosheet" in a two-step process, which consists of coating the substrate with a plymer solution and heating. Considering that the existing process consists of 8 steps to manufacture graphene, the new method makes it much simpler. In addition, the new method can be directly used as solar cell without any additional process.

The research team synthesized a polymer with a rigid ladder structure, namely PIM-1(Polymer of intrinsic microporosity-1) to form the CNS through the simpole process, which is spin-coated on the quarts substrates using PIM-1 solution with light green color and then heat-treated at 1,200 °C, leading to transparent and conductive CNS.

The carbon nanosheet can be mass-produced in a simpler process while having high quality since the new process bypasses the steps that are prone to formation of defects such as elimination of the metal substrate or transfer of graphene to another board. The final product is as effective as graphene.

Dr. Han Ik Joh at KIST said, "It is expected to be applied for commercialization of transparent and conductive 2D carbon materials without difficulty since this process is based on the continuous and mass-produced process of carbon fiber."
This is a follow-up research from the team that recently released its findings on the carbon nanosheet manufacturing based on polyacrylonitrile (published in the 2013 Carbon Vol. 55 and Applied Physics Letters Vol. 102). The new findings are even more meaningful as it offers deeper understanding on the growth mechanism of carbon nanosheet and much simpler manufacturing process.

The research was conducted with the funding from the KIST Proprietary Research Project and National Research Foundation of Korea.

####

For more information, please click here

Contacts:
Dr. Han-Ik Joh

82-102-732-5608

Copyright © Korea Institute of Science and Technology

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Researchers develop artificial building blocks of life March 8th, 2024

How surface roughness influences the adhesion of soft materials: Research team discovers universal mechanism that leads to adhesion hysteresis in soft materials March 8th, 2024

Two-dimensional bimetallic selenium-containing metal-organic frameworks and their calcinated derivatives as electrocatalysts for overall water splitting March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

Graphene/ Graphite

First human trial shows ‘wonder’ material can be developed safely: A revolutionary nanomaterial with huge potential to tackle multiple global challenges could be developed further without acute risk to human health, research suggests February 16th, 2024

NRL discovers two-dimensional waveguides February 16th, 2024

$900,000 awarded to optimize graphene energy harvesting devices: The WoodNext Foundation's commitment to U of A physicist Paul Thibado will be used to develop sensor systems compatible with six different power sources January 12th, 2024

First direct imaging of small noble gas clusters at room temperature: Novel opportunities in quantum technology and condensed matter physics opened by noble gas atoms confined between graphene layers January 12th, 2024

Govt.-Legislation/Regulation/Funding/Policy

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

Researchers’ approach may protect quantum computers from attacks March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

Optically trapped quantum droplets of light can bind together to form macroscopic complexes March 8th, 2024

Chip Technology

New chip opens door to AI computing at light speed February 16th, 2024

HKUST researchers develop new integration technique for efficient coupling of III-V and silicon February 16th, 2024

Electrons screen against conductivity-killer in organic semiconductors: The discovery is the first step towards creating effective organic semiconductors, which use significantly less water and energy, and produce far less waste than their inorganic counterparts February 16th, 2024

NRL discovers two-dimensional waveguides February 16th, 2024

Announcements

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers/Posters

Researchers develop artificial building blocks of life March 8th, 2024

How surface roughness influences the adhesion of soft materials: Research team discovers universal mechanism that leads to adhesion hysteresis in soft materials March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Tools

First direct imaging of small noble gas clusters at room temperature: Novel opportunities in quantum technology and condensed matter physics opened by noble gas atoms confined between graphene layers January 12th, 2024

New laser setup probes metamaterial structures with ultrafast pulses: The technique could speed up the development of acoustic lenses, impact-resistant films, and other futuristic materials November 17th, 2023

Ferroelectrically modulate the Fermi level of graphene oxide to enhance SERS response November 3rd, 2023

The USTC realizes In situ electron paramagnetic resonance spectroscopy using single nanodiamond sensors November 3rd, 2023

Energy

Development of zinc oxide nanopagoda array photoelectrode: photoelectrochemical water-splitting hydrogen production January 12th, 2024

Shedding light on unique conduction mechanisms in a new type of perovskite oxide November 17th, 2023

Inverted perovskite solar cell breaks 25% efficiency record: Researchers improve cell efficiency using a combination of molecules to address different November 17th, 2023

The efficient perovskite cells with a structured anti-reflective layer – another step towards commercialization on a wider scale October 6th, 2023

Industrial

Boron nitride nanotube fibers get real: Rice lab creates first heat-tolerant, stable fibers from wet-spinning process June 24th, 2022

Nanotubes: a promising solution for advanced rubber cables with 60% less conductive filler June 1st, 2022

Protective equipment with graphene nanotubes meets the strictest ESD safety standards March 25th, 2022

OCSiAl receives the green light for Luxembourg graphene nanotube facility project to power the next generation of electric vehicles in Europe March 4th, 2022

Solar/Photovoltaic

Development of zinc oxide nanopagoda array photoelectrode: photoelectrochemical water-splitting hydrogen production January 12th, 2024

Shedding light on unique conduction mechanisms in a new type of perovskite oxide November 17th, 2023

Inverted perovskite solar cell breaks 25% efficiency record: Researchers improve cell efficiency using a combination of molecules to address different November 17th, 2023

Charged “molecular beasts” the basis for new compounds: Researchers at Leipzig University use “aggressive” fragments of molecular ions for chemical synthesis November 3rd, 2023

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project