Nanotechnology Now

Our NanoNews Digest Sponsors



Heifer International

Wikipedia Affiliate Button


android tablet pc

Home > Press > Shapes of Things to Come: Exotic Shapes for Liquid Drops Have Many Possible Uses

Schematic shows how the application of an electrical field transforms a spherical drop clad with nanoparticle surfactants into an ellipsoid.
Schematic shows how the application of an electrical field transforms a spherical drop clad with nanoparticle surfactants into an ellipsoid.

Abstract:
Oil and water don't mix, as any chemist or cook knows. Tom Russell, a polymer scientist from the University of Massachusetts who now holds a Visiting Faculty appointment with Berkeley Lab's Materials Sciences Division, is using that chemical and culinary truth to change the natural spherical shape of liquid drops into ellipsoids, tubes and even fibrous structures similar in appearance to glass wool. Through the combination of water, oil and nanoparticle surfactants plus an external field, Russell is able to stabilize water drops into non-equilibrium shapes that could find valuable uses as therapeutic delivery systems, biosensors, microfluidic lab-on-a-chip devices, or possibly as the basis for an all-liquid electrical battery.

Shapes of Things to Come: Exotic Shapes for Liquid Drops Have Many Possible Uses

Berkeley, CA | Posted on December 3rd, 2013

"Using the in situ formation of nanoparticle surfactants on a water drop that's been suspended in oil, we've demonstrated a simple route to produce and stabilize fluid drops having shapes far removed from their equilibrium spherical shape," says Russell.

In a study he carried out at UMass with Mengmeng Cui and Todd Emrick, a drop of water was suspended in silicone oil and carboxylated nanoparticles were added to the water. The nanoparticles self-assembled at the oil/water interface to form a sphere-shaped surfactant drop - like a soap bubble. Applying an electric field to the drop overcame the equilibrium energy that stabilizes its spherical shape and deformed the sphere into an ellipsoid.

Since an ellipsoid has a greater surface area than a sphere of the same volume, a great many more nanoparticles can attach themselves to it. When the electric field was removed, the nanoparticle drop tried to return to the spherical shape of its equilibrium energy. However, the swollen number of nanoparticles jammed together at the oil/water interface, essentially "gridlocking" the drop into a stable ellipsoid shape.

"You can think of it like traffic getting jammed at an exit ramp or particles of sand getting jammed in an hourglass," Russell says. "We start out by deforming a drop shaped like a basketball into a drop shaped like a football. The jamming effect locks in the football shape. If we continue the deforming and jamming process, we can create a wide assortment of shapes that are stable even though far removed from equilibrium."

In the original experiment, a drop of water was suspended in oil, but Russell says the experiment could just as easily have been done with a drop of oil suspended in water. He also says the shape deformation can be accomplished by mechanical stirring and that the degree of deformation is determined by the strength of the applied electrical field or how long and vigorously the liquid is stirred. While he and his colleagues never changed the volume of their drops in the original study, just the shape, Russell says the volume of the drops can be inflated with the addition of more liquids, or deflated with the removal of liquids.

"When you can control the shape of one liquid in another liquid and the shapes of the liquids are locked-in you can think about microfluidic devices-devices that are completely liquid inside the drop, or reactive liquid systems for packaging, delivery and storage," Russell says. "You can also conceive of batteries in which ions flow through water tubes. You might even make droplets that display really high shock resistance because they're basically a liquid surrounded by another liquid."

Russell was the corresponding author on a paper describing this work that was published in Science. The paper was titled "Stabilizing Liquid Drops in Nonequilibrium Shapes by the Interfacial Jamming of Nanoparticles." Cui and Emrick were the co-authors.

At Berkeley Lab, he will continue to develop these concepts with responsive nanoparticle surfactants, exploring the application of magnetic and ultrasonic fields to deform droplet shapes. He will capitalize on the resources of the Advanced Light Source, the Molecular Foundry and the National Center for Electron Microscopy, all DOE national user facilities hosted by Berkeley Lab.

####

For more information, please click here

Contacts:
Lynn Yarris
(510) 486-5375

Copyright © Berkeley Lab

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

For more about the research of Tom Russell, go here:

Related News Press

News and information

Oregon researchers glimpse pathway of sunlight to electricity: Collaboration with Lund University uses modified UO spectroscopy equipment to study 'maze' of connections in photoactive quantum dots December 19th, 2014

Instant-start computers possible with new breakthrough December 19th, 2014

Aculon Hires New Business Development Director December 19th, 2014

Iranian Scientists Use Nanotechnology to Increase Power, Energy of Supercapacitors December 18th, 2014

Laboratories

Switching to spintronics: Berkeley Lab reports on electric field switching of ferromagnetism at room temp December 17th, 2014

ORNL microscopy pencils patterns in polymers at the nanoscale December 17th, 2014

Student Nanotechnology Laboratories Network Set Up in Iran December 15th, 2014

Unusual Electronic State Found in New Class of Unconventional Superconductors: Finding gives scientists a new group of materials to explore to unlock secrets of some materials' ability to carry current with no energy loss December 8th, 2014

New research paves the way for nano-movies of biomolecules: Scientists use X-ray laser as ultra slow-motion camera December 4th, 2014

Microfluidics/Nanofluidics

“Line dancing bacteria win the 2014 Dolomite and Lab on a Chip Video Competition” December 16th, 2014

Govt.-Legislation/Regulation/Funding/Policy

Oregon researchers glimpse pathway of sunlight to electricity: Collaboration with Lund University uses modified UO spectroscopy equipment to study 'maze' of connections in photoactive quantum dots December 19th, 2014

Zenosense, Inc. - Hospital Collaboration - 400 Person Lung Cancer Detection Trial December 17th, 2014

SUNY Poly NanoCollege Faculty Member Selected as American Physical Society Fellow: SUNY Poly Associate Professor of Nanoscience Dr. Vincent LaBella Recognized for Significant Technological Innovations that Enable Interactive Learning December 17th, 2014

Switching to spintronics: Berkeley Lab reports on electric field switching of ferromagnetism at room temp December 17th, 2014

Discoveries

Oregon researchers glimpse pathway of sunlight to electricity: Collaboration with Lund University uses modified UO spectroscopy equipment to study 'maze' of connections in photoactive quantum dots December 19th, 2014

Instant-start computers possible with new breakthrough December 19th, 2014

Creation of 'Rocker' protein opens way for new smart molecules in medicine, other fields December 18th, 2014

Iranian Scientists Use Nanotechnology to Increase Power, Energy of Supercapacitors December 18th, 2014

Materials/Metamaterials

Aculon Hires New Business Development Director December 19th, 2014

ORNL microscopy pencils patterns in polymers at the nanoscale December 17th, 2014

Pb islands in a sea of graphene magnetise the material of the future December 16th, 2014

Graphene Applied in Production of Recyclable Electrodes December 13th, 2014

Announcements

Oregon researchers glimpse pathway of sunlight to electricity: Collaboration with Lund University uses modified UO spectroscopy equipment to study 'maze' of connections in photoactive quantum dots December 19th, 2014

Instant-start computers possible with new breakthrough December 19th, 2014

Aculon Hires New Business Development Director December 19th, 2014

Iranian Scientists Use Nanotechnology to Increase Power, Energy of Supercapacitors December 18th, 2014

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers

Oregon researchers glimpse pathway of sunlight to electricity: Collaboration with Lund University uses modified UO spectroscopy equipment to study 'maze' of connections in photoactive quantum dots December 19th, 2014

Instant-start computers possible with new breakthrough December 19th, 2014

How does enzymatic pretreatment affect the nanostructure and reaction space of lignocellulosic biomass? December 18th, 2014

Iranian Scientists Use Nanotechnology to Increase Power, Energy of Supercapacitors December 18th, 2014

Battery Technology/Capacitors/Generators/Piezoelectrics/Thermoelectrics/Energy storage

Iranian Scientists Use Nanotechnology to Increase Power, Energy of Supercapacitors December 18th, 2014

Nexeon Attracts ex-Nokia Product Executive to its Board of Directors December 15th, 2014

Defects are perfect in laser-induced graphene: Rice University lab discovers simple way to make material for energy storage, electronics December 10th, 2014

Lengthening the life of high capacity silicon electrodes in rechargeable lithium batteries: Novel rubber-like coating could lead to longer lasting batteries December 2nd, 2014

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More










ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







© Copyright 1999-2014 7th Wave, Inc. All Rights Reserved PRIVACY POLICY :: CONTACT US :: STATS :: SITE MAP :: ADVERTISE