Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > New material approach should increase solar cell efficiency

The correlated electron metal SrRuO3 exhibits strong visible slight absorption. Overlaid here on the AM1.5G solar spectrum, it can be seen that SrRuO3 absorbs more than 75 times more light than TiO2. The structural, chemical, and electronic compatibility of TiO2 and SrRuO3 further enables the fabrication of heterojunctions with exciting photovoltaic and photocatalytic response driven by hot-carrier injection.
The correlated electron metal SrRuO3 exhibits strong visible slight absorption. Overlaid here on the AM1.5G solar spectrum, it can be seen that SrRuO3 absorbs more than 75 times more light than TiO2. The structural, chemical, and electronic compatibility of TiO2 and SrRuO3 further enables the fabrication of heterojunctions with exciting photovoltaic and photocatalytic response driven by hot-carrier injection.

Abstract:
"When designing next generation solar energy conversion systems, we must first develop ways to more efficiently utilize the solar spectrum," explained Lane Martin, whose research group has done just that.

"This is a fundamentally new way of approaching these matters," said Martin, who is an assistant professor of materials science and engineering (MatSE) at Illinois. "From these materials we can imagine carbon-neutral energy production of clean-burning fuels, waste water purification and remediation, and much more."

New material approach should increase solar cell efficiency

Urbana, IL | Posted on April 23rd, 2013

Martin's research group brought together aspects of condensed matter physics, semiconductor device engineering, and photochemistry to develop a new form of high-performance solar photocatalyst based on the combination of the TiO2 (titanium dioxide) and other "metallic" oxides that greatly enhance the visible light absorption and promote more efficient utilization of the solar spectrum for energy applications. Their paper, "Strong Visible-Light Absorption and Hot-Carrier Injection in TiO2/SrRuO3 Heterostructures," appears in the journal Advanced Energy Materials.

According to Martin, the primary feature limiting the performance of oxide-based photovoltaic and/or photocatalytic systems has traditionally been the poor absorption of visible light in these often wide band gap materials. One candidate oxide material for such applications is anatase TiO2, which is arguably the most widely-studied photocatalyst due to its chemical stability, non-toxicity, low-cost, and excellent band alignment to several oxidation-reduction reactions. As the backbone of dye-sensitized solar cells, however, the presence of a light-absorbing dye accounts for a large band gap which limits efficient usage of all but the UV portion of sunlight.

"We observed that the unusual electronic structure of SrRuO3 is also responsible for unexpected optical properties including high absorption across the visible spectrum and low reflection compared to traditional metals," stated Sungki Lee, the paper's first author. "By coupling this material to TiO2 we demonstrate enhanced visible light absorption and large photocatalytic activities."

"SrRuO3 is a correlated electron oxide which is known to possess metallic-like temperature dependence of its resistivity and itinerant ferromagnetism and for its widespread utility as a conducting electrode in oxide heterostructures," Lee added. Referring to this material as a "metal," however, is likely inappropriate as the electronic structure and properties are derived from a combination of complex electronic density of states, electron correlations, and more.

Using a process called photo-excited hot-carrier injection from the SrRuO3 to the TiO2, the researchers created new heterostructures whose novel optical properties and the resulting high photoelectrochemical performance provide an interesting new approach that could advance the field of photocatalysis and further broaden the potential applications of other metallic oxides.

This work provides an exciting new approach to the challenge of designing visible-light photosensitive materials and has resulted in a provisional patent application. The work was primarily supported by the ongoing International Institute for Carbon Neutral Energy Research (I2CNER) program, a partnership between Kyushu University in Japan and the University of Illinois.

"The I2CNER project brings together some of the leading energy researchers from around the globe," explained I2CNER Director Petros Sofronis, who is also a professor in the Department of Mechanical Science and Engineering at Illinois. "Results from Dr. Martin's research group and others demonstrate that I2CNER is not only an experiment on international collaboration. It is a concerted institutionalized effort to pursue green innovation and reduced CO2 emissions, as well as to advance fundamental science and develop science-based technological solutions for the reorganization of sustainable and environmentally friendly society."

####

For more information, please click here

Contacts:
Lane Martin
Department of Materials Science and Engineering
217/244-9162


Petros Sofronis
director
International Institute for Carbon Neutral Energy Research
217/333-2636


Writer:
Rick Kubetz
Engineering Communications Office
217/244-7716

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

National Space Society Congratulates SpaceX on the Falcon 9's Return to Flight January 19th, 2017

Eric Berger Wins the National Space Society's 2017 Space Pioneer Award for Mass Media January 19th, 2017

Nanometrics to Announce Fourth Quarter and Full Year Financial Results on February 7, 2017 January 19th, 2017

Discoveries

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

'5-D protein fingerprinting' could give insights into Alzheimer's, Parkinson's January 19th, 2017

Strength of hair inspires new materials for body armor January 18th, 2017

Self-assembling particles brighten future of LED lighting January 18th, 2017

Materials/Metamaterials

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

Strength of hair inspires new materials for body armor January 18th, 2017

Self-assembling particles brighten future of LED lighting January 18th, 2017

Dressing a metal in various colors: DGIST research developed a technology to coat metal with several nanometers of semiconducting materials January 17th, 2017

Announcements

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

National Space Society Congratulates SpaceX on the Falcon 9's Return to Flight January 19th, 2017

Eric Berger Wins the National Space Society's 2017 Space Pioneer Award for Mass Media January 19th, 2017

Nanometrics to Announce Fourth Quarter and Full Year Financial Results on February 7, 2017 January 19th, 2017

Energy

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

Dressing a metal in various colors: DGIST research developed a technology to coat metal with several nanometers of semiconducting materials January 17th, 2017

Stability challenge in perovskite solar cell technology: New research reveals intrinsic instability issues of iodine-containing perovskite solar cells December 26th, 2016

Nanoscale 'conversations' create complex, multi-layered structures: New technique leverages controlled interactions across surfaces to create self-assembled materials with unprecedented complexity December 22nd, 2016

Solar/Photovoltaic

Chemists Cook up New Nanomaterial and Imaging Method: Nanomaterials can store all kinds of things, including energy, drugs and other cargo January 19th, 2017

Dressing a metal in various colors: DGIST research developed a technology to coat metal with several nanometers of semiconducting materials January 17th, 2017

Stability challenge in perovskite solar cell technology: New research reveals intrinsic instability issues of iodine-containing perovskite solar cells December 26th, 2016

Going green with nanotechnology December 21st, 2016

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project