Nanotechnology Now







Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > New Nanostructure for Batteries Keeps Going and Going ...

The new double-walled silicon nanotube anode is made by a clever four-step process: Polymer nanofibers (green) are made, then heated (with, and then without, air) until they are reduced to carbon (Image courtesy Hui Wu, Stanford, and Yi Cui)
The new double-walled silicon nanotube anode is made by a clever four-step process: Polymer nanofibers (green) are made, then heated (with, and then without, air) until they are reduced to carbon

(Image courtesy Hui Wu, Stanford, and Yi Cui)

Abstract:
For more than a decade, scientists have tried to improve lithium-based batteries by replacing the graphite in one terminal with silicon, which can store 10 times more charge. But after just a few charge/discharge cycles, the silicon structure would crack and crumble, rendering the battery useless.

New Nanostructure for Batteries Keeps Going and Going ...

Menlo Park, CA | Posted on May 10th, 2012

Now a team led by materials scientist Yi Cui of Stanford and SLAC has found a solution: a cleverly designed double-walled nanostructure that lasts more than 6,000 cycles, far more than needed by electric vehicles or mobile electronics.

"This is a very exciting development toward our goal of creating smaller, lighter and longer-lasting batteries than are available today," Cui said. The results were published March 25 in Nature Nanotechnology.

Lithium-ion batteries are widely used to power devices from electric vehicles to portable electronics because they can store a relatively large amount of energy in a relatively lightweight package. The battery works by controlling the flow of lithium ions through a fluid electrolyte between its two terminals, called the anode and cathode.

The promise - and peril - of using silicon as the anode in these batteries comes from the way the lithium ions bond with the anode during the charging cycle. Up to four lithium ions bind to each of the atoms in a silicon anode - compared to just one for every six carbon atoms in today's graphite anode - which allows it to store much more charge.

However, it also swells the anode to as much as four times its initial volume. What's more, some of the electrolyte reacts with the silicon, coating it and inhibiting further charging. When lithium flows out of the anode during discharge, the anode shrinks back to its original size and the coating cracks, exposing fresh silicon to the electrolyte.

Within just a few cycles, the strain of expansion and contraction, combined with the electrolyte attack, destroys the anode through a process called "decrepitation."

Over the past five years, Cui's group has progressively improved the durability of silicon anodes by making them out of nanowires and then hollow silicon nanoparticles. His latest design consists of a double-walled silicon nanotube coated with a thin layer of silicon oxide, a very tough ceramic material.

This strong outer layer keeps the outside wall of the nanotube from expanding, so it stays intact. Instead, the silicon swells harmlessly into the hollow interior, which is also too small for electrolyte molecules to enter. After the first charging cycle, it operates for more than 6,000 cycles with 85 percent capacity remaining.

Cui said future research is aimed at simplifying the process for making the double-wall silicon nanotubes. Others in his group are developing new high-performance cathodes to combine with the new anode to form a battery with five times the performance of today's lithium-ion technology.

In 2008, Cui founded a company, Amprius, which licensed rights to Stanford's patents for his silicon nanowire anode technology. Its near-term goal is to produce a battery with double the energy density of today's lithium-ion batteries.

####

For more information, please click here

Copyright © SLAC National Accelerator Laboratory,

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

New technique for exploring structural dynamics of nanoworld: Developed in a Nobel laureate's laboratory at Caltech, hybrid approach allows ultrafast EM analysis of materials, showing tiny electronic changes in individual atoms within a material on ultrafast time scales April 28th, 2015

When mediated by superconductivity, light pushes matter million times more April 28th, 2015

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

Self-assembling biomaterial forms nanostructure templates for human tissue formation April 27th, 2015

Cacao Seed Extract Used in Production of Catalytic Nanoparticles April 27th, 2015

Laboratories

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

More is less in novel electronic material: Adding electrons actually shrinks the system April 27th, 2015

Govt.-Legislation/Regulation/Funding/Policy

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

International research team discovers new mechanism behind malaria progression: Findings provide a new avenue for research in malaria treatment April 27th, 2015

More is less in novel electronic material: Adding electrons actually shrinks the system April 27th, 2015

Two-dimensional semiconductor comes clean April 27th, 2015

Nanotubes/Buckyballs/Fullerenes

SouthWest NanoTechnologies CEO Dave Arthur to Speak at NanoBCA DC Roundtable on May 19 in Washington DC April 20th, 2015

How to maximize the superconducting critical temperature in a molecular superconductor: International team led by Tohoku University opens new route for discovering high Tc superconductors April 19th, 2015

Nanotubes with two walls have singular qualities: Rice University lab calculates unique electronic qualities of double-walled carbon nanotubes April 16th, 2015

MIT sensor detects spoiled meat: Tiny device could be incorporated into 'smart packaging' to improve food safety April 15th, 2015

Discoveries

New technique for exploring structural dynamics of nanoworld: Developed in a Nobel laureate's laboratory at Caltech, hybrid approach allows ultrafast EM analysis of materials, showing tiny electronic changes in individual atoms within a material on ultrafast time scales April 28th, 2015

When mediated by superconductivity, light pushes matter million times more April 28th, 2015

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

More is less in novel electronic material: Adding electrons actually shrinks the system April 27th, 2015

Announcements

New technique for exploring structural dynamics of nanoworld: Developed in a Nobel laureate's laboratory at Caltech, hybrid approach allows ultrafast EM analysis of materials, showing tiny electronic changes in individual atoms within a material on ultrafast time scales April 28th, 2015

When mediated by superconductivity, light pushes matter million times more April 28th, 2015

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

Sensor Designed in Iran Able to Remove Formaldehyde Gas from Environment April 27th, 2015

Patents/IP/Tech Transfer/Licensing

Long Island Capital Alliance Announces Participants for Brookhaven National Laboratory Technology Transfer Capital Forum on May 8: Keynote Speaker Dr. Doon Gibbs, Director of Brookhaven National Laboratory April 16th, 2015

MIT sensor detects spoiled meat: Tiny device could be incorporated into 'smart packaging' to improve food safety April 15th, 2015

Heat-Converting Material Patents Licensed April 8th, 2015

From tobacco to cyberwood March 31st, 2015

Energy

Pseudoparticles travel through photoactive material: KIT scientists measure important process in the conversion of light energy -- publication in Nature Communications April 24th, 2015

Scientists Use Nanoscale Building Blocks and DNA 'Glue' to Shape 3D Superlattices: New approach to designing ordered composite materials for possible energy applications April 23rd, 2015

'Holey' graphene for energy storage: Charged holes in graphene increase energy storage capacity April 22nd, 2015

Expanding the reach of metallic glass April 22nd, 2015

Automotive/Transportation

Chemists strike nano-gold: 4 new atomic structures for gold nanoparticle clusters: Research builds upon work by Nobel Prize-winning team from Stanford University April 28th, 2015

Nanoparticles Used to Improve Mechanical, Thermal Properties of Cellulose Fibers April 23rd, 2015

'Holey' graphene for energy storage: Charged holes in graphene increase energy storage capacity April 22nd, 2015

Expanding the reach of metallic glass April 22nd, 2015

Battery Technology/Capacitors/Generators/Piezoelectrics/Thermoelectrics/Energy storage

Phonons, arise! Small electric voltage alters conductivity in key materials April 22nd, 2015

New class of 3D-printed aerogels improve energy storage April 22nd, 2015

'Holey' graphene for energy storage: Charged holes in graphene increase energy storage capacity April 22nd, 2015

‘Oxford Instruments Young Nanoscientist India Award 2015’ to Prof. Arindam Ghosh April 20th, 2015

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More










ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project