Nanotechnology Now

Our NanoNews Digest Sponsors





Heifer International

Wikipedia Affiliate Button


android tablet pc

Home > Press > UNH Chemists Create Molecule With Promising Semiconductor Properties

Abstract:
A team of chemists from the University of New Hampshire has synthesized the first-ever stable derivative of nonacene, creating a compound that holds significant promise in the manufacture of flexible organic electronics such as large displays, solar cells and radio frequency identification tags.

UNH Chemists Create Molecule With Promising Semiconductor Properties

Durham, NH | Posted on February 13th, 2010

The team, led by professor of organic chemistry and materials science Glen Miller and including two UNH undergraduates, published their findings in January 2010 in the Journal of the American Chemical Society.

Nonacene, a compound with nine rings of benzene fused in a linear fashion, belongs to a class of organic semiconductors called acenes, widely recognized to be among the very best in terms of electronic performance. Yet they are highly unstable - they oxidize rapidly.

"We have known that nonacene would have very desirable electronic properties, but it was just a tease, because you couldn't make it, you couldn't use it," says Miller, who has been working to prepare large acenes since 2007.

Miller and his team - research scientist Irvinder Kaur, postdoctoral fellow Mikael Jazdzyk, and UNH seniors Polina Prusevich and Nathan Stein - built the large nonacene derivative from smaller pieces, the way one might build a Lego structure. The key to the molecule's stability is the addition of arylthio functional groups, stable collections of atoms that contain sulfur.

"The skeleton of the molecule is still there, but it's got additional functional groups attached to the skeleton," says Miller. This not only made the derivative stable, it also made it soluble, further enhancing its usefulness.

Nonacenes hold promise for further development of flexible organic electronic devices: computer displays so thin they could be rolled up or even worn. Miller notes that the military is interested in the technology that would allow for chameleon-like camouflage clothing that could change with the environment. Organic solar cells are another potential application of nonacenes; such cells could cut the cost of solar power by making use of inexpensive organic molecules rather than the expensive crystalline silicon that is used in most solar cells.

While Miller notes that his team's work is but a first step toward creating stable nonacene devices, "these compounds push all of these technologies further."

"Before our work, the thought of preparing flexible organic electronic devices using nonacene or a nonacene derivative was just a dream," he adds. "With this major step forward, we are much closer to realizing the dream."

The complete paper, "Design, Synthesis, and Characterization of a Persistent Nonacene Derivative", is available at the Journal of the American Chemical Society Web site:

pubs.acs.org/doi/full/10.1021/ja9095472.

Funding was provided by the National Science Foundation through the Nanoscale Science & Engineering Center for High-Rate Nanomanufacturing.

####

About University of New Hampshire
The University of New Hampshire, founded in 1866, is a world-class public research university with the feel of a New England liberal arts college. A land, sea, and space-grant university, UNH is the state's flagship public institution, enrolling 12,200 undergraduate and 2,200 graduate students.

For more information, please click here

Contacts:
Glen Miller
603-862-2456

Copyright © University of New Hampshire

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Novel Rocket Design Flight Tested: New Rocket Propellant and Motor Design Offers High Performance and Safety October 23rd, 2014

MEMS & Sensors Technology Showcase: Finalists Announced for MEMS Executive Congress US 2014 October 23rd, 2014

Nanoparticle technology triples the production of biogas October 23rd, 2014

SUNY Polytechnic Institute Invites the Public to Attend its Popular Statewide 'NANOvember' Series of Outreach and Educational Events October 23rd, 2014

Display technology/LEDs/SS Lighting/OLEDs

Strengthening thin-film bonds with ultrafast data collection October 23rd, 2014

QD Vision Wins Prestigious Presidential Green Chemistry Challenge Award from the U.S. Environmental Protection Agency October 16th, 2014

Beyond LEDs: Brighter, new energy-saving flat panel lights based on carbon nanotubes - Planar light source using a phosphor screen with highly crystalline single-walled carbon nanotubes (SWCNTs) as field emitters demonstrates its potential for energy-efficient lighting device October 14th, 2014

Aledia’s Nanowire LED Technology Endorsed By 2014 Physics Nobel Prize Winner: Hiroshi Amano Serves on Company’s Scientific Advisory Board October 13th, 2014

Govt.-Legislation/Regulation/Funding/Policy

Novel Rocket Design Flight Tested: New Rocket Propellant and Motor Design Offers High Performance and Safety October 23rd, 2014

Strengthening thin-film bonds with ultrafast data collection October 23rd, 2014

Brookhaven Lab Launches Computational Science Initiative:Leveraging computational science expertise and investments across the Laboratory to tackle "big data" challenges October 22nd, 2014

Bipolar Disorder Discovery at the Nano Level: Tiny structures found in brain synapses help scientists better understand disorder October 22nd, 2014

Possible Futures

Imaging electric charge propagating along microbial nanowires October 20th, 2014

Superconducting circuits, simplified: New circuit design could unlock the power of experimental superconducting computer chips October 18th, 2014

Nanocoatings Market By Product Is Expected To Reach USD 8.17 Billion By 2020: Grand View Research, Inc. October 15th, 2014

Perpetuus Carbon Group Receives Independent Verification of its Production Capacity for Graphenes at 140 Tonnes per Annum: Perpetuus Becomes the First Manufacturer in the Sector to Allow Third Party Audit October 7th, 2014

Chip Technology

Strengthening thin-film bonds with ultrafast data collection October 23rd, 2014

NIST offers electronics industry 2 ways to snoop on self-organizing molecules October 22nd, 2014

Materials for the next generation of electronics and photovoltaics: MacArthur Fellow develops new uses for carbon nanotubes October 21st, 2014

Nitrogen Doped Graphene Characterized by Iranian, Russian, German Scientists October 21st, 2014

Announcements

Nanoparticle technology triples the production of biogas October 23rd, 2014

SUNY Polytechnic Institute Invites the Public to Attend its Popular Statewide 'NANOvember' Series of Outreach and Educational Events October 23rd, 2014

Advancing thin film research with nanostructured AZO: Innovnano’s unique and cost-effective AZO sputtering targets for the production of transparent conducting oxides October 23rd, 2014

Strengthening thin-film bonds with ultrafast data collection October 23rd, 2014

Energy

Nanoparticle technology triples the production of biogas October 23rd, 2014

Advancing thin film research with nanostructured AZO: Innovnano’s unique and cost-effective AZO sputtering targets for the production of transparent conducting oxides October 23rd, 2014

Researchers patent a nanofluid that improves heat conductivity October 22nd, 2014

Could I squeeze by you? Ames Laboratory scientists model molecular movement within narrow channels of mesoporous nanoparticles October 21st, 2014

Solar/Photovoltaic

Advancing thin film research with nanostructured AZO: Innovnano’s unique and cost-effective AZO sputtering targets for the production of transparent conducting oxides October 23rd, 2014

Magnetic mirrors enable new technologies by reflecting light in uncanny ways October 16th, 2014

Dyesol Signs Letter of Intent with Tata Steel October 13th, 2014

DNA nano-foundries cast custom-shaped metal nanoparticles: DNA's programmable assembly is leveraged to form precise 3D nanomaterials for disease detection, environmental testing, electronics and beyond October 10th, 2014

NanoNews-Digest
The latest news from around the world, FREE





  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More














ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







© Copyright 1999-2014 7th Wave, Inc. All Rights Reserved PRIVACY POLICY :: CONTACT US :: STATS :: SITE MAP :: ADVERTISE