Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Nanoscale 'conversations' create complex, multi-layered structures: New technique leverages controlled interactions across surfaces to create self-assembled materials with unprecedented complexity

The added color in this scanning electron microscope (SEM) image showcases the discrete, self-assembled layers within these novel nanostructures. The pale blue bars are each roughly 4,000 times thinner than a single human hair.
CREDIT
Brookhaven National Laboratory
The added color in this scanning electron microscope (SEM) image showcases the discrete, self-assembled layers within these novel nanostructures. The pale blue bars are each roughly 4,000 times thinner than a single human hair. CREDIT Brookhaven National Laboratory

Abstract:
Building nanomaterials with features spanning just billionths of a meter requires extraordinary precision. Scaling up that construction while increasing complexity presents a significant hurdle to the widespread use of such nano-engineered materials.

Nanoscale 'conversations' create complex, multi-layered structures: New technique leverages controlled interactions across surfaces to create self-assembled materials with unprecedented complexity

Upton, NY | Posted on December 22nd, 2016

Now, scientists at the U.S. Department of Energy's Brookhaven National Laboratory have developed a way to efficiently create scalable, multilayer, multi-patterned nanoscale structures with unprecedented complexity.

The Brookhaven team exploited self-assembly, where materials spontaneous snap together to form the desired structure. But they introduced a significant leap in material intelligence, because each self-assembled layer now guides the configuration of additional layers.

The results, published in the journal Nature Communications, offer a new paradigm for nanoscale self-assembly, potentially advancing nanotechnology used for medicine, energy generation, and other applications.

"There's something amazing and rewarding about creating structures no one has ever seen before," said study coauthor Kevin Yager, a scientist at Brookhaven Lab's Center for Functional Nanomaterials (CFN). "We're calling this responsive layering-like building a tower, but where each brick is intelligent and contains instructions for subsequent bricks."

The technique was pioneered entirely at the CFN, a DOE Office of Science User Facility.

"The trick was chemically 'sealing' each layer to make it robust enough that the additional layers don't disrupt it," said lead author Atikur Rahman, a Brookhaven Lab postdoc during the study and now an assistant professor at the Indian Institute of Science Education and Research, Pune. "This granted us unprecedented control. We can now stack any sequence of self-organized layers to create increasingly intricate 3D structures."

Guiding nanoscale conversations

Other nano-fabrication methods-such as lithography-can create precise nano-structures, but the spontaneous ordering of self-assembly makes it faster and easier. Further, responsive layering pushes that efficiency in new directions, enabling, for example, structures with internal channels or pockets that would be exceedingly difficult to make by any other means.

"Self-assembly is inexpensive and scalable because it's driven by intrinsic interactions," said study coauthor and CFN scientist Gregory Doerk. "We avoid the complex tools that are traditionally used to carve precise nano-structures."

The CFN collaboration used thin films of block copolymers (BCP)-chains of two distinct molecules linked together. Through well-established techniques, the scientists spread BCP films across a substrate, applied heat, and watched the material self-assemble into a prescribed configuration. Imagine spreading LEGOs over a baking sheet, sticking it in the oven, and then seeing it emerge with each piece elegantly snapped together in perfect order.

However, these materials are conventionally two-dimensional, and simply stacking them would yield a disordered mess. So the Brookhaven Lab scientists developed a way to have self-assembled layers discretely "talk" to one another.

The team infused each layer with a vapor of inorganic molecules to seal the structure-a bit like applying nanoscale shellac to preserve a just-assembled puzzle.

"We tuned the vapor infiltration step so that each layer's structure exhibits controlled surface contours," Rahman said. "Subsequent layers then feel and respond to this subtle topography."

Coauthor Pawel Majewski added, "Essentially, we open up a 'conversation' between layers. The surface patterns drive a kind of topographic crosstalk, and each layer acts as a template for the next one."

Exotic configurations

As often occurs in fundamental research, this crosstalk was an unexpected phenomenon.

"We were amazed when we first saw templated ordering from one layer to the next, Rahman said. "We knew immediately that we had to exhaustively test all the possible combinations of film layers and explore the technique's potential."

The collaboration demonstrated the formation of a broad range of nano-structures-including many configurations never before observed. Some contained hollow chambers, round pegs, rods, and winding shapes.

"This was really a Herculean effort on the part of Atikur," Yager said. "The multi-layer samples covered a staggering range of combinations."

Mapping never-before-seen structures

The scientists used scanning electron microscopy (SEM) to probe the nanoscale features, getting cross-sectional details of the emergent structures. A focused electron beam bombarded the sample, bouncing off surface features before being detected to enable reconstruction of an image depicting the exact configuration.

They complemented this with x-ray scattering at Brookhaven's National Synchrotron Light Source II-another DOE Office of Science User Facility. The penetrative scattering technique allowed the researchers to probe the internal structure.

"CFN brings together a unique concentration of skills, interests, and technology," said CFN Director and coauthor Charles Black. "In one facility, we have people interested in creating, converting, and measuring structures-that's how we can have these kinds of unanticipated and highly collaborative breakthroughs."

This fundamental breakthrough substantially broadens the diversity and complexity of structures that can be made with self-assembly, and correspondingly broadens the range of potential applications. For example, intricate three-dimensional nanostructures could yield transformative improvements in nano-porous membranes for water purification, bio-sensing, or catalysis.

###

This work was supported by the DOE Office of Science.

####

About Brookhaven National Laboratory
Brookhaven National Laboratory is supported by the Office of Science of the U.S. Department of Energy. The Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit science.energy.gov.

One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry and government researchers. Brookhaven is operated and managed for DOE's Office of Science by Brookhaven Science Associates, a limited-liability company founded by the Research Foundation for the State University of New York on behalf of Stony Brook University, the largest academic user of Laboratory facilities, and Battelle, a nonprofit applied science and technology organization.

For more information, please click here

Contacts:
Karen McNulty Walsh

631-344-8350

Copyright © Brookhaven National Laboratory

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Scientific paper: "Non-native Three-dimensional Block Copolymer Morphologies:

Related News Press

News and information

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

European & Korean Project To Demo World’s First 5G Platform During Winter Games February 15th, 2018

Imaging

Graphene on toast, anyone? Rice University scientists create patterned graphene onto food, paper, cloth, cardboard February 13th, 2018

New method enables high-resolution measurements of magnetism February 7th, 2018

Leti Presents Optical-Equipment Curving Technology that Improves Performance, Cuts Costs: ‘Disruptive Approach’ for Imaging Applications Presented in Paper At Photonics West and Demonstrated in Leti’s Booth February 2nd, 2018

New technology aiming to improve trueness in the piezoelectric microscopy characterization of ceramic materials January 26th, 2018

Laboratories

Atomic Flaws Create Surprising, High-Efficiency UV LED Materials: Subtle surface defects increase UV light emission in greener, more cost-effective LED and catalyst materials February 8th, 2018

Govt.-Legislation/Regulation/Funding/Policy

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Possible Futures

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Self Assembly

Liquid crystal molecules form nano rings: Quantized self-assembly enables design of materials with novel properties February 7th, 2018

Particle size matters for porous building blocks: Rice University scientists find porous nanoparticles get tougher under pressure, but not when assembled December 19th, 2017

Physicists gain new insights into nanosystems with spherical confinement: Enormous potential for the targeted delivery of pharmaceutical agents and the creation of tailored nanoparticles July 27th, 2017

Oddball enzyme provides easy path to synthetic biomaterials May 17th, 2017

Nanomedicine

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Discoveries

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Announcements

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

European & Korean Project To Demo World’s First 5G Platform During Winter Games February 15th, 2018

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Energy

Round-the-clock power from smart bowties February 5th, 2018

Silk fibers could be high-tech ‘natural metamaterials’ January 31st, 2018

A simple new approach to plastic solar cells: Osaka University researchers intelligently design new highly efficient organic solar cells based on amorphous electronic materials with potential for easy printing January 28th, 2018

Nature paper by Schlumberger researchers used photothermal based nanoscale IR spectroscopy to analyze heterogeneous process of petroleum generation January 23rd, 2018

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project