Home > Press > 'Mind the gap' between atomically thin materials
Abstract:
When it comes to engineering single-layer atomic structures, "minding the gap" will help researchers create artificial electronic materials one atomic layer at a time, according to a team of materials scientists.
The gap is a miniscule vacuum that researchers in Penn State's Center for 2-Dimensional and Layered Materials believe is an energy barrier keeping electrons from easily crossing from one layer of material to the next.
"We're still trying to understand how electrons move vertically through these layered materials, and we thought it should take a lot less energy," said Joshua Robinson, assistant professor of materials science and engineering and associate director of the 2DLM Center. "Thanks to a combination of theory and experiment, we now know we have to account for this gap when we design new materials."
For the first time, the Penn State researchers grew a single atomic layer of tungsten diselenide on a one- atom-thick substrate of graphene with pristine interfaces between the two layers. When they tried to put a voltage from the top tungsten diselenide layer down to the graphene layer, they encountered a surprising amount of resistance. About half of the resistance was caused by the gap, which introduced a large barrier, about 1 electron volt, to the electrons trying to move between layers. This energy barrier could prove useful in designing next generation electronic devices, such as vertical tunneling field effect transistors, said Robinson.
The interest in this type of material arose with the discovery of methods to make single layer graphite. The Penn State researchers use a more scalable method than early graphene makers -- chemical vapor deposition -- to deposit a single layer of crystalline tungsten diselenide on top of a few layers of graphene grown from silicon carbide.
Although graphene research exploded in the last decade, many similar solids exist that can combine to create entirely new artificial materials with unimaginable properties.
The researchers discovered that the tungsten diselenide layer grew in perfectly aligned triangular islands 1 to 3 microns in size that slowly coalesced into a single crystal up to 1 centimeter square. They reported their results in Nano Letters.
Robinson believes it will be possible to grow these crystals to industrially useful wafer-scale sizes, although it will require a larger furnace than he currently has in his lab.
"One of the really interesting things about this gap," Robinson said, "is that it allows us to grow aligned layers despite the fact that the atoms in the graphene are not lined up with the atoms in the tungsten diselenide. In fact there is a 23 percent lattice mismatch, which is huge."
###
Yu-Chuan Lin, a graduate student in materials science and engineering is lead author on the paper. Other Penn State coauthors were Ram Krishna Ghosh, post-doctoral fellow in electrical engineering; Jie Li, post-doctoral fellow; and Theresa S. Mayer and Suman Datta, professors, all in electrical engineering.
Lain-Jong Li of the Institute of Atomic and Molecular Sciences, Taiwan; Jeremy Robinson, researcher in the Naval Research Laboratory and Joshua Robinson's brother, also worked on this project as did Bogdan Diaconescu and Taisuke Ohta of the Sandia National Laboratory and Robert Wallace, professor and Erik Jonsson Distinguished Chair, Department of Materials Science and Engineering, and his students Hui Zhu, Rafik Addou, Xin Peng, Ning Lu and Moon J. Kim from The University of Texas at Dallas.
The Defense Advance Projects Agency; Semiconductor Corporation; National Institute of Standards and Technology; Office of Naval Research; U.S. Department of Energy; Academic Sinica, Taiwan; King Abdullah University of Science and Technology; U.S. Air Force Research Laboratory; and the National Science Foundation supported this work.
####
For more information, please click here
Contacts:
A'ndrea Elyse Messer
814-865-9481
Copyright © Penn State
If you have a comment, please Contact us.Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.
Related News Press |
News and information
Researchers develop artificial building blocks of life March 8th, 2024
Physics
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Optically trapped quantum droplets of light can bind together to form macroscopic complexes March 8th, 2024
Graphene/ Graphite
NRL discovers two-dimensional waveguides February 16th, 2024
Laboratories
A battery’s hopping ions remember where they’ve been: Seen in atomic detail, the seemingly smooth flow of ions through a battery’s electrolyte is surprisingly complicated February 16th, 2024
NRL discovers two-dimensional waveguides February 16th, 2024
Govt.-Legislation/Regulation/Funding/Policy
What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024
Researchers’ approach may protect quantum computers from attacks March 8th, 2024
Optically trapped quantum droplets of light can bind together to form macroscopic complexes March 8th, 2024
Possible Futures
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Molecular Nanotechnology
Scientists push the boundaries of manipulating light at the submicroscopic level March 3rd, 2023
First electric nanomotor made from DNA material: Synthetic rotary motors at the nanoscale perform mechanical work July 22nd, 2022
Nanotech scientists create world's smallest origami bird March 17th, 2021
Discoveries
What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024
Researchers’ approach may protect quantum computers from attacks March 8th, 2024
High-tech 'paint' could spare patients repeated surgeries March 8th, 2024
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Materials/Metamaterials/Magnetoresistance
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Focused ion beam technology: A single tool for a wide range of applications January 12th, 2024
Announcements
What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers/Posters
Researchers develop artificial building blocks of life March 8th, 2024
Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024
Military
What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024
New chip opens door to AI computing at light speed February 16th, 2024
NRL discovers two-dimensional waveguides February 16th, 2024
Research partnerships
Researchers’ approach may protect quantum computers from attacks March 8th, 2024
'Sudden death' of quantum fluctuations defies current theories of superconductivity: Study challenges the conventional wisdom of superconducting quantum transitions January 12th, 2024
Development of zinc oxide nanopagoda array photoelectrode: photoelectrochemical water-splitting hydrogen production January 12th, 2024
The latest news from around the world, FREE | ||
Premium Products | ||
Only the news you want to read!
Learn More |
||
Full-service, expert consulting
Learn More |
||