Nanotechnology Now

Our NanoNews Digest Sponsors



Heifer International

Wikipedia Affiliate Button


android tablet pc

Home > Press > Berkeley Lab Scientists Achieve Breakthrough in Nanocomposite for High-Capacity Hydrogen Storage

This schematic shows high-capacity magnesium nanocrystals encapsulated in a gas-barrier polymer matrix to create a new and revolutionary hydrogen storage composite material. (Image from Jeff Urban)
This schematic shows high-capacity magnesium nanocrystals encapsulated in a gas-barrier polymer matrix to create a new and revolutionary hydrogen storage composite material. (Image from Jeff Urban)

Abstract:
Since the 1970s, hydrogen has been touted as a promising alternative to fossil fuels due to its clean combustion —unlike the combustion of fossil fuels, which spews greenhouse gases and harmful pollutants, hydrogen's only combustion by-product is water. Compared to gasoline, hydrogen is lightweight, can provide a higher energy density and is readily available. But there's a reason we're not already living in a hydrogen economy: to replace gasoline as a fuel, hydrogen must be safely and densely stored, yet easily accessed. Limited by materials unable to leap these conflicting hurdles, hydrogen storage technology has lagged behind other clean energy candidates.

Berkeley Lab Scientists Achieve Breakthrough in Nanocomposite for High-Capacity Hydrogen Storage

Berkeley, CA | Posted on March 14th, 2011

In recent years, researchers have attempted to tackle both issues by locking hydrogen into solids, packing larger quantities into smaller volumes with low reactivity—a necessity in keeping this volatile gas stable. However, most of these solids can only absorb a small amount of hydrogen and require extreme heating or cooling to boost their overall energy efficiency.

Now, scientists with the U.S. Department of Energy (DOE) Lawrence Berkeley National Laboratory (Berkeley Lab) have designed a new composite material for hydrogen storage consisting of nanoparticles of magnesium metal sprinkled through a matrix of polymethyl methacrylate, a polymer related to Plexiglas. This pliable nanocomposite rapidly absorbs and releases hydrogen at modest temperatures without oxidizing the metal after cycling—a major breakthrough in materials design for hydrogen storage, batteries and fuel cells.

"This work showcases our ability to design composite nanoscale materials that overcome fundamental thermodynamic and kinetic barriers to realize a materials combination that has been very elusive historically," says Jeff Urban, Deputy Director of the Inorganic Nanostructures Facility at the Molecular Foundry, a DOE Office of Science nanoscience center and national user facility located at Berkeley Lab. "Moreover, we are able to productively leverage the unique properties of both the polymer and nanoparticle in this new composite material, which may have broad applicability to related problems in other areas of energy research."

Urban, along with coauthors Ki-Joon Jeon and Christian Kisielowski used the TEAM 0.5 microscope at the National Center for Electron Microscopy (NCEM), another DOE Office of Science national user facility housed at Berkeley Lab, to observe individual magnesium nanocrystals dispersed throughout the polymer. With the high-resolution imaging capabilities of TEAM 0.5, the world's most powerful electron microscope, the researchers were also able to track defects—atomic vacancies in an otherwise-ordered crystalline framework—providing unprecedented insight into the behavior of hydrogen within this new class of storage materials.

"Discovering new materials that could help us find a more sustainable energy solution is at the core of the Department of Energy's mission. Our lab provides outstanding experiments to support this mission with great success," says Kisielowski. "We confirmed the presence of hydrogen in this material through time-dependent spectroscopic investigations with the TEAM 0.5 microscope. This investigation suggests that even direct imaging of hydrogen columns in such materials can be attempted using the TEAM microscope."

"The unique nature of Berkeley Lab encourages cross-division collaborations without any limitations," said Jeon, now at the Ulsan National Institute of Science and Technology, whose postdoctoral work with Urban led to this publication

To investigate the uptake and release of hydrogen in their nanocomposite material, the team turned to Berkeley Lab's Energy and Environmental Technologies Division (EETD), whose research is aimed at developing more environmentally friendly technologies for generating and storing energy, including hydrogen storage.

"Here at EETD, we have been working closely with industry to maintain a hydrogen storage facility as well as develop hydrogen storage property testing protocols," says Samuel Mao, director of the Clean Energy Laboratory at Berkeley Lab and an adjunct engineering faculty member at the University of California (UC), Berkeley. "We very much enjoy this collaboration with Jeff and his team in the Materials Sciences Division, where they developed and synthesized this new material, and were then able to use our facility for their hydrogen storage research."

Adds Urban, "This ambitious science is uniquely well-positioned to be pursued within the strong collaborative ethos here at Berkeley Lab. The successes we achieve depend critically upon close ties between cutting-edge microscopy at NCEM, tools and expertise from EETD, and the characterization and materials know-how from MSD."

This research is reported in a paper titled, "Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without heavy metal catalysts," appearing in the journal Nature Materials and available in Nature Materials online. Co-authoring the paper with Urban, Kisielowski and Jeon were Hoi Ri Moon, Anne M. Ruminski, Bin Jiang and Rizia Bardhan.

This work was supported by DOE's Office of Science.

The Molecular Foundry is one of the five DOE Nanoscale Science Research Centers (NSRCs), premier national user facilities for interdisciplinary research at the nanoscale. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories.

####

About Berkeley Lab
Lawrence Berkeley National Laboratory is a U.S. Department of Energy (DOE) national laboratory managed by the University of California for the DOE Office of Science. Berkeley Lab provides solutions to the world’s most urgent scientific challenges including sustainable energy, climate change, human health, and a better understanding of matter and force in the universe. It is a world leader in improving our lives through team science, advanced computing, and innovative technology.

For more information, please click here

Contacts:
Aditi Risbud
(510)486-4861

Copyright © Berkeley Lab

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

For more information about the Molecular Foundry vist the Website at

For more information about the National Center for Electron Microscopy Center visit the Website at

For more information about the DOE Hydrogen Storage program, please visit:

Related News Press

News and information

Ad-REIC vaccine: A magic bullet for cancer treatment September 30th, 2014

New Topical Hemostatic Agent: Neutral Self-Assembling Peptide Hydrogel September 30th, 2014

Chemical interactions between silver nanoparticles and thiols: A comparison of mercaptohexanol again September 30th, 2014

A Heartbeat Away? Hybrid "Patch" Could Replace Transplants: TAU researcher harnesses gold nanoparticles to engineer novel biocompatible cardiac patch September 30th, 2014

Discoveries

Ad-REIC vaccine: A magic bullet for cancer treatment September 30th, 2014

New Topical Hemostatic Agent: Neutral Self-Assembling Peptide Hydrogel September 30th, 2014

Chemical interactions between silver nanoparticles and thiols: A comparison of mercaptohexanol again September 30th, 2014

A Heartbeat Away? Hybrid "Patch" Could Replace Transplants: TAU researcher harnesses gold nanoparticles to engineer novel biocompatible cardiac patch September 30th, 2014

Announcements

Ad-REIC vaccine: A magic bullet for cancer treatment September 30th, 2014

New Topical Hemostatic Agent: Neutral Self-Assembling Peptide Hydrogel September 30th, 2014

Chemical interactions between silver nanoparticles and thiols: A comparison of mercaptohexanol again September 30th, 2014

A Heartbeat Away? Hybrid "Patch" Could Replace Transplants: TAU researcher harnesses gold nanoparticles to engineer novel biocompatible cardiac patch September 30th, 2014

Energy

Production of Anticorrosive Chromate Nanocoatings in Iran September 27th, 2014

University of Electro-Communications research: High density quantum dots for powerful solar cells September 25th, 2014

On the Road to Artificial Photosynthesis: Berkeley Lab Study Reveals Key Catalytic Factors in Carbon Dioxide Reduction September 25th, 2014

Solar cell compound probed under pressure September 25th, 2014

Automotive/Transportation

Production of Anticorrosive Chromate Nanocoatings in Iran September 27th, 2014

Teijin Aramid’s carbon nanotube fibers awarded with Paul Schlack prize: New generation super fibers bring wave of innovations to fiber market September 25th, 2014

Next-Gen Luxury RV From Global Caravan Technologies Will Offer MagicView Roof and Windshield Using SPD-SmartGlass Technology From Research Frontiers: Recreational Vehicle Manufacturer Global Caravan Technologies (GCT) Features 28 Square Feet of MagicView™ SPD-SmartGlass September 17th, 2014

Toward making lithium-sulfur batteries a commercial reality for a bigger energy punch September 17th, 2014

Battery Technology/Capacitors/Generators/Piezoelectrics/Thermoelectrics

Graphene and Amaranthus Superparamagnets: Breakthrough nanoparticles discovery of Indian researcher September 23rd, 2014

IEEE International Electron Devices Meeting To Celebrate 60th Anniversary as The Leading Technical Conference for Advanced Semiconductor Devices September 18th, 2014

Toward making lithium-sulfur batteries a commercial reality for a bigger energy punch September 17th, 2014

NEI Corporation and PneumatiCoat Technologies Sign Agreement to Jointly Develop and Market New Materials for Lithium-ion Batteries September 12th, 2014

Fuel Cells

Iranian Researchers Synthesize Stable Ceramic Nanopowders at Room Temperature September 20th, 2014

Media Advisory: Minister Rempel to Announce Support for Alberta's Nanotechnology Sector June 20th, 2014

Evolution of a Bimetallic Nanocatalyst June 6th, 2014

University of Surrey collaborates with India and Tata Steel to revolutionise renewable energy March 26th, 2014

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More














ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







© Copyright 1999-2014 7th Wave, Inc. All Rights Reserved PRIVACY POLICY :: CONTACT US :: STATS :: SITE MAP :: ADVERTISE