Nanotechnology Now





Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > New Highly Stable Fuel-Cell Catalyst Gets Strength from its Nano Core

This high-angle annular dark field (HAADF) scanning transmission electron microscopy (STEM) image shows a bright shell on a relatively darker nanoparticle, signifying the formation of a core/shell structure — a platinum monolayer shell on a palladium nanoparticle core.
This high-angle annular dark field (HAADF) scanning transmission electron microscopy (STEM) image shows a bright shell on a relatively darker nanoparticle, signifying the formation of a core/shell structure — a platinum monolayer shell on a palladium nanoparticle core.

Abstract:
Palladium core protects precious platinum; enhances reactivity/stability

New Highly Stable Fuel-Cell Catalyst Gets Strength from its Nano Core

Upton, NY | Posted on November 10th, 2010

Stop-and-go driving can wear on your nerves, but it really does a number on the precious platinum that drives reactions in automotive fuel cells. Before large fleets of fuel-cell-powered vehicles can hit the road, scientists will have to find a way to protect the platinum, the most expensive component of fuel-cell technology, and to reduce the amount needed to make catalytically active electrodes.

Now, scientists at the U.S. Department of Energy's (DOE) Brookhaven National Laboratory have developed a new electrocatalyst that uses a single layer of platinum and minimizes its wear and tear while maintaining high levels of reactivity during tests that mimic stop-and-go driving. The research — described online in Angewandte Chemie, International Edition, and identified by the journal as a "very important paper" — may greatly enhance the practicality of fuel-cell vehicles and may also be applicable for improving the performance of other metallic catalysts.

The newly designed catalysts are composed of a single layer of platinum over a palladium (or palladium-gold alloy) nanoparticle core. Their structural characterization was performed at Brookhaven's Center for Functional Nanomaterials and the National Synchrotron Light Source.

"Our studies of the structure and activity of this catalyst — and comparisons with platinum-carbon catalysts currently in use — illustrate that the palladium core ‘protects' the fine layer of platinum surrounding the particles, enabling it to maintain reactivity for a much longer period of time," explained Brookhaven Lab chemist Radoslav Adzic, who leads the research team.

In conventional fuel-cell catalysts, the oxidation and reduction cycling — triggered by changes in voltage that occur during stop-and-go driving — damages the platinum. Over time, the platinum dissolves, causing irreversible damage to the fuel cell.

In the new catalyst, palladium from the core is more reactive than platinum in these oxidation and reduction reactions. Stability tests simulating fuel cell voltage cycling revealed that, after 100,000 potential cycles, a significant amount of palladium had been oxidized, dissolved, and migrated away from the cathode. In the membrane between the cathode and anode, the dissolved palladium ions were reduced by hydrogen diffusing from the anode to form a "band," or dots.

In contrast, platinum was almost unaffected, except for a small contraction of the platinum monolayer. "This contraction of the platinum lattice makes the catalyst more active and the stability of the particles increases," Adzic said.

Reactivity of the platinum monolayer/palladium core catalyst also remained extremely high. It was reduced by merely 37 percent after 100,000 cycles.

Building on earlier work that illustrated how small amounts of gold can enhance catalytic activity, the scientists also developed a form of the platinum monolayer catalyst with a palladium-gold alloy core. The addition of gold further increased the stability of the electrocatalyst, which retained nearly 70 percent of reactivity after 200,000 cycles of testing.

"This indicates the excellent durability of this electrocatalyst, especially when compared with simpler platinum-carbon catalysts, which lose nearly 70 percent of their reactivity after much shorter cycling times. This level of activity and stability indicates that this is a practical catalyst. It exceeds the goal set by DOE for 2010-2015 and it can be used for automotive applications," Adzic said.

He noted that fuel cells made using the new catalyst would require only about 10 grams of platinum per car — and less than 20 grams of palladium. Currently, in catalytic convertors used to treat exhaust gases, 5 to 10 grams of platinum is used. Since fuel-cell-powered cars would emit no exhaust gases, there would be no need for such catalytic converters, and therefore no net increase in the amount of platinum used.

"In addition to developing electrocatalysts for automotive fuel cell applications, these findings indicate the broad applicability of platinum monolayer catalysts and the possibility of extending this concept to catalysts based on other noble metals," Adzic said.

The fundamental science leading to the development of the new electrocatalyst and early scale-up work was funded by the DOE Office of Science. Additional funding came from the Toyota Motor Corporation.

The Center for Functional Nanomaterials at Brookhaven National Laboratory is one of the five DOE Nanoscale Science Research Centers (NSRCs), premier national user facilities for interdisciplinary research at the nanoscale. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos national laboratories.

####

About Brookhaven National Laboratory
One of ten national laboratories overseen and primarily funded by the Office of Science of the U.S. Department of Energy (DOE), Brookhaven National Laboratory conducts research in the physical, biomedical, and environmental sciences, as well as in energy technologies and national security. Brookhaven Lab also builds and operates major scientific facilities available to university, industry and government researchers. Brookhaven is operated and managed for DOE's Office of Science by Brookhaven Science Associates, a limited-liability company founded by the Research Foundation of State University of New York on behalf of Stony Brook University, the largest academic user of Laboratory facilities, and Battelle, a nonprofit, applied science and technology organization.

For more information, please click here

Contacts:
Karen McNulty Walsh
(631) 344-8350

Peter Genzer
(631) 344-3174

Copyright © Brookhaven National Laboratory

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Researchers develop new way to manufacture nanofibers May 21st, 2015

Nanotherapy effective in mice with multiple myeloma May 21st, 2015

Turn that defect upside down: Twin boundaries in lithium-ion batteries May 21st, 2015

INSIDDE: Uncovering the real history of art using a graphene scanner May 21st, 2015

Chemistry

Nanosorbent Produced in Iran to Adsorb Tiny Amounts of Aromatic Hydrocarbon from Seawater May 18th, 2015

Science and Technology of Advanced Materials (STAM): Reported successes and failures aid hot pursuit of superconductivity May 15th, 2015

ORNL demonstrates first large-scale graphene fabrication May 14th, 2015

First theoretical proof: Measurement of a single nuclear spin in biological samples May 11th, 2015

Govt.-Legislation/Regulation/Funding/Policy

Nanotherapy effective in mice with multiple myeloma May 21st, 2015

Turn that defect upside down: Twin boundaries in lithium-ion batteries May 21st, 2015

INSIDDE: Uncovering the real history of art using a graphene scanner May 21st, 2015

SUNY Poly CNSE and NIOSH Launch Federal Nano Health and Safety Consortium: May 20th, 2015

Possible Futures

Simulations predict flat liquid May 21st, 2015

Nature inspires first artificial molecular pump: Simple design mimics pumping mechanism of life-sustaining proteins found in living cells May 19th, 2015

NNCO and Museum of Science Fiction to Collaborate on Nanotechnology and 3D Printing Panels at Awesome Con May 19th, 2015

Quantum 'gruyères' for spintronics of the future: Topological insulators become a little less 'elusive' May 12th, 2015

Announcements

Researchers develop new way to manufacture nanofibers May 21st, 2015

Nanotherapy effective in mice with multiple myeloma May 21st, 2015

Turn that defect upside down: Twin boundaries in lithium-ion batteries May 21st, 2015

INSIDDE: Uncovering the real history of art using a graphene scanner May 21st, 2015

Energy

Sandia researchers first to measure thermoelectric behavior by 'Tinkertoy' materials May 20th, 2015

Industrial Nanotech, Inc. Announces Official Launch of the Eagle Platinum Tile™ May 19th, 2015

FEI and Weatherford Enter Into Joint Agreement for Advanced Reservoir Characterization Services May 18th, 2015

Efficiency record for black silicon solar cells jumps to 22.1 percent: Aalto University's researchers improved their previous record by over 3 absolute percents in cooperation with Universitat Politècnica de Catalunya May 18th, 2015

Fuel Cells

Unique microscopic images provide new insights into ionic liquids April 28th, 2015

Expanding the reach of metallic glass April 22nd, 2015

Newly-Developed Nanocatalysts Increase Performance of Fuel Cells April 16th, 2015

Cobalt film a clean-fuel find: Rice University discovery is efficient, robust at drawing hydrogen and oxygen from water April 15th, 2015

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More










ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project