Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Self-Assembling Devices

Custom fit: Organic p/n heterojunctions with molecular-level precision have been tailored. An oligothiophene-perylenediimide dyad, when modified with triethylene glycol side chains at one terminus and dodecyl side chains at the other, self-assembles into a photoconducting nanofiber with a well-defined morphology.
Custom fit: Organic p/n heterojunctions with molecular-level precision have been tailored. An oligothiophene-perylenediimide dyad, when modified with triethylene glycol side chains at one terminus and dodecyl side chains at the other, self-assembles into a photoconducting nanofiber with a well-defined morphology.

Abstract:
Design and synthesis of organic devices

Self-Assembling Devices

Tokyo | Posted on June 14th, 2010

Organic devices have greatly benefited from the remarkable advances in synthetic organic chemistry that have allowed for the synthesis of a wide variety of đ-conjugated molecules with attractive electronic functions. In Chemistry—An Asian Journal, Wei-Shi Li, Takanori Fukushima, Takuzo Aida, and co-workers, based at the Shanghai Institute of Organic Chemistry (China), Riken (Saitama, Japan), and the Japan Science and Technology Agency (Tokyo) describe the rational design strategy using side-chain incompatibility of a covalently connected donor-acceptor (D-A) dyad to synthesize organic p/n heterojunctions with molecular-level precision.

Although organic devices can be easily designed, without proper molecular design that allows for long-range ordering of đ-conjugated molecules, the resulting devices will rarely show the expected performances. Thin-film organic photovoltaic devices require electron-donor (D) and -acceptor (A) molecules to assemble homotropically to form a heterojunction. Additionally, to achieve a highly efficient photoinduced charge separation, the resultant p- and n-type semiconducting domains must be connected over a long distance. However, D and A components tend to assemble together by means of a charge-transfer (CT) interaction, unfavorable for photoelectric conversion.

Oligothiophene (OT) and perylenediimide (PDI) have been synthesized to form covalently linked D-A dyads, which bear at their termini either incompatible or compatible side chains. The dyads with the incompatible side chains intrinsically self-assemble into nanofibrous structures, whilst the dyad containing the compatible side chains resulted in ill-defined microfibers. Flash-photolysis time-resolved microwave conductivity measurements, in conjunction with transient absorption spectroscopy, clearly shows that the assembly with the incompatible side chains exhibits a much greater photoconducting output than that with compatible side chains.

This design strategy with "side-chain incompatibility" provides promise for the realization of p/n heterojunctions from covalently connected D-A dyads. Furthermore, this design strategy can give rise to long-range structural integrity that is essential for excellent device performances. Aida writes "elaboration of side-chain-incompatible D-A dyads in terms of absorption range and carrier transport properties is a subject worthy of further investigations for developing molecularly engineered photovoltaic devices."

Author: Takuzo Aida, National Museum of Emerging Science and Innovation, Tokyo (Japan), macro.chem.t.u-tokyo.ac.jp/

Title: Use of Side-Chain Incompatibility for Tailoring Long-Range p/n Heterojunctions: Photoconductive Nanofibers Formed by Self-Assembly of an Amphiphilic Donor-Acceptor Dyad Consisting of Oligothiophene and Perylenediimide

Chemistry - An Asian Journal, Permalink to the article: dx.doi.org/10.1002/asia.201000111

####

For more information, please click here

Copyright © Chemistry - An Asian Journal

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Shining rings: A new material emits white light when exposed to electricity: New synthetic approach could spark development of other dynamic materials July 24th, 2017

Ultrathin device harvests electricity from human motion July 23rd, 2017

The July 23 close fly-by of asteroid 2017 BS5 is explored in a Q&A with Dr. John S. Lewis, chief scientist at Deep Space Industries July 23rd, 2017

Scientists announce the quest for high-index materials: All-dielectric nanophotonics: The quest for better materials and fabrication techniques July 22nd, 2017

Thin films

Studying Argon Gas Trapped in Two-Dimensional Array of Tiny "Cages": Understanding how individual atoms enter and exit the nanoporous frameworks could help scientists design new materials for gas separation and nuclear waste remediation July 17th, 2017

Thinking thin brings new layering and thermal abilities to the semiconductor industry: In a breakthrough for the semiconductor industry, researchers demonstrate a new layer transfer technique called "controlled spalling" that creates many thin layers from a single gallium nitride July 11th, 2017

Nanometrics Expands Position in Advanced Memory Devices with Atlas for Thin Film Process Control: Atlas Films Systems Adopted by Multiple Customers for Advanced Memory Volume Manufacturing July 11th, 2017

ANU invention may help to protect astronauts from radiation in space July 3rd, 2017

Academic/Education

The Physics Department of Imperial College, London, uses the Quorum Q150T to deposit metals and ITO to make plasmonic sensors and electric contact pads July 13th, 2017

Oxford Instruments congratulates Lancaster University for inaugurating the IsoLab, built for studying quantum systems June 20th, 2017

The 2017 Winners for Generation Nano June 8th, 2017

MIT Energy Initiative awards 10 seed fund grants for early-stage energy research May 4th, 2017

Self Assembly

Oddball enzyme provides easy path to synthetic biomaterials May 17th, 2017

Nanotubes that build themselves April 14th, 2017

Nanocages for gold particles: what is happening inside? March 16th, 2017

Most Complex Nanoparticle Crystal Ever Made by Design: Possible applications include controlling light, capturing pollutants, delivering therapeutics March 2nd, 2017

Announcements

Shining rings: A new material emits white light when exposed to electricity: New synthetic approach could spark development of other dynamic materials July 24th, 2017

Ultrathin device harvests electricity from human motion July 23rd, 2017

The July 23 close fly-by of asteroid 2017 BS5 is explored in a Q&A with Dr. John S. Lewis, chief scientist at Deep Space Industries July 23rd, 2017

Scientists announce the quest for high-index materials: All-dielectric nanophotonics: The quest for better materials and fabrication techniques July 22nd, 2017

Energy

'Upconverted' light has a bright future: Rice University professor developing plasmon-powered devices for medicine, security, solar cells July 17th, 2017

Making two out of one: FAU researchers have explained the mechanism behind a process that can increase the efficiency of organic solar cells July 12th, 2017

Argonne National Laboratory’s Continuous ALD Technology Licensed Exclusively to Forge Nano July 7th, 2017

Tiny bubbles provide tremendous propulsion in new microparticles research-Ben-Gurion U. June 21st, 2017

Solar/Photovoltaic

'Upconverted' light has a bright future: Rice University professor developing plasmon-powered devices for medicine, security, solar cells July 17th, 2017

Making two out of one: FAU researchers have explained the mechanism behind a process that can increase the efficiency of organic solar cells July 12th, 2017

Thinking thin brings new layering and thermal abilities to the semiconductor industry: In a breakthrough for the semiconductor industry, researchers demonstrate a new layer transfer technique called "controlled spalling" that creates many thin layers from a single gallium nitride July 11th, 2017

Tiny bubbles provide tremendous propulsion in new microparticles research-Ben-Gurion U. June 21st, 2017

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project