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Home > Press > A solution to perovskite solar cell scalability problems

Abstract:
Perovskites are hybrid materials made from metal halides and organic compounds. They have attracted a lot of interest in the field of solar energy because of their light-harvesting capacities combined with a low cost of manufacturing, making them prime candidates for overtake the market from their silicon counterparts. Perovskites also show great potential in a range of applications that include LED lights, lasers, and photodetectors.

A solution to perovskite solar cell scalability problems

Lausanne, Switzerland | Posted on April 22nd, 2022

One of the obstacles on the way to commercializing perovskite solar cells is that scaling them up results to losses in power-conversion efficiency and operational stability. This is due to natural defects in the perovskite molecular structure, which interferes with the flow of electrons. This results in “resistive loss” – a power loss due to resistance. In addition, the processes required to achieve high-quality large-area perovskite films are quite complex.

In a new study published in Nature Nanotechnology, scientists led by Mohammad Nazeeruddin at EPFL have found a way to overcome the scaling up problems of perovskites. The scientists have developed an easy solvothermal method that can produce single-crystalline titanium dioxide rhombohedral nanoparticles that can be used to build a perovskite film.

The new structure features a lower amount of “lattice” mismatches, referring to the “ladder-like” structure of the titanium dioxide nanoparticles. This translates into a lower number of defects, which ensures better electron flow throughout with lower power loss.

Testing the new nanoparticle-based, small-size solar cells, the scientists achieved a power-conversion efficiency of 24.05% and a fill factor (a measure of actual obtainable power) of 84.7%. The cells also maintain about 90% of their initial performance after continuous operation for 1400 hours.

The scientists also fabricated large-area cells, which certified an efficiency of 22.72% with an active area of nearly 24 cm2. This “represents the highest efficiency modules with the lowest loss in efficiency when scaling up,” conclude the authors.

Other contributors

North China Electric Power University
Luxembourg Institute of Science and Technology (LIST)
University of Luxembourg
Chinese Academy of Sciences (CAS)
Xi'an Jiaotong University
Hebei University
Istituto CNR di Scienze e Tecnologie Chimiche “Giulio Natta” (CNR-SCITEC)
University of Perugia
Istituto Italiano di Tecnologia
Prince Mohammad Bin Fahd University
Huazhong University of Science and Technology
University of Würzburg
Westlake University
Huaqiao University
EPFL Laboratory of Organometallic and Medicinal Chemistry
City University of Hong Kong

####

For more information, please click here

Contacts:
Nik Papageorgiou
Ecole Polytechnique Fédérale de Lausanne

Office: 41-216-932-105
Expert Contact

Mohammad Khaja Nazeeruddin
École polytechnique fédérale de Lausanne (EPFL)

Office: +41 21 695 82 51

Copyright © Ecole Polytechnique Fédérale de Lausanne

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