Nanotechnology Now

Our NanoNews Digest Sponsors
Heifer International



Home > Press > You're not so tough, h-BN: Rice University chemists find new path to make strong 2D material better for applications

Rice University scientists have made it much simpler to add carbon chains to hexagonal-boron nitride, a 2D material much stiffer than steel and an excellent conductor of heat. (Credit: Illustration courtesy of the Angel Martí Group/Rice University)
Rice University scientists have made it much simpler to add carbon chains to hexagonal-boron nitride, a 2D material much stiffer than steel and an excellent conductor of heat. (Credit: Illustration courtesy of the Angel Martí Group/Rice University)

Abstract:
Hexagonal-boron nitride is tough, but Rice University scientists are making it easier to get along with.

You're not so tough, h-BN: Rice University chemists find new path to make strong 2D material better for applications

Houston, TX | Posted on August 14th, 2019

Two-dimensional h-BN, an insulating material also known as "white graphene," is four times stiffer than steel and an excellent conductor of heat, a benefit for composites that rely on it to enhance their properties.

Those qualities also make h-BN hard to modify. Its tight hexagonal lattice of alternating boron and nitrogen atoms is highly resistant to change, unlike graphene and other 2D materials that can be easily modified — aka functionalized — with other elements.

The Rice lab of chemist Angel Martí has published a protocol to enhance h-BN with carbon chains. These turn the 2D tough guy into a material that retains its strength but is more amenable to bonding with polymers or other materials in composites.

The lab's paper in the American Chemical Society's Journal of Physical Chemistry suggests h-BN can be made more dispersible in organic solvents as well. Martí and his team modified the Billups-Birch reaction process they had successfully used to alter boron nitride nanotubes to attack the defenses of h-BN and covalently attach carbons.

Birch reduction, discovered in the 1940s and enhanced in 2004 by Rice Professor Emeritus of Chemistry Edward Billups to functionalize carbon nanotubes, frees electrons to bind with other atoms. In the Rice process, Martí and his team can control the amount of h-BN functionalization by varying the amount of lithium in the reaction.

Lithium is an alkali metal that sheds free electrons when combined with liquefied ammonia. Mixed with h-BN flakes and a carbon source, 1-Bromododecane in this case, the reaction produces an alkyl radical, a chemical species that reacts with h-BN and makes a bond.

Martí said it's the best method found so far to modify h-BN, which resists change even under high temperatures. "You take a little bit of graphite and put it in a furnace at 800 degrees (Celsius), and it will be gone," he said. "You take hexagonal-boron nitride and do the same, and it will still be there smiling at you.

"That gives you an idea of how stable it is, and that’s the problem we wanted to address," Martí said. "The material is good for certain applications, but to control its properties for manufacturing, you have to graft different groups onto the surface."

He said a 20-to-1 molar ratio of lithium to h-BN optimized the process of grafting carbon chains to the surface and edges. Because the base h-BN remains stable under high temperatures, it can be returned to its pristine state by simply burning off the functional chains.

While h-BN is naturally hydrophilic (water-attracting), the functional carbons make them nearly superhydrophobic (water-avoiding), a good property for making protective films, Martí said. But even when enhanced, the flakes remain amenable to dispersion in non-polar solvents.

Martí said his group is exploring what other kinds of molecules can be grafted onto white graphene. "What about benzene groups? What about ethers? What about groups that will make it compatible with other materials?

"There's a lot of interest in making composite materials between h-BN, boron nitride nanotubes and polymers," he said. "Ultimately, we'd like to graft different groups onto h-BN and build a library, kind of a toolbox, of functional groups that can be used with these materials."

Rice alumnus Carlos de los Reyes is lead author of the paper. Co-authors are Rice undergraduate Katharyn Hernández, graduate students Cecilia Martínez-Jiménez, Cedric Ginestra and Ashleigh Smith McWilliams, research assistant Kendahl Walz-Mitra and Matteo Pasquali, the A.J. Hartsook Professor of Chemical and Biomolecular Engineering, a professor of materials science and nanoengineering and of chemistry. Martí is an associate professor of chemistry, of bioengineering and of materials science and nanoengineering.

The National Science Foundation, the Air Force Office of Scientific Research and the Welch Foundation supported the research.

####

About Rice University
Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation’s top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,962 undergraduates and 3,027 graduate students, Rice’s undergraduate student-to-faculty ratio is just under 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice is ranked No. 1 for lots of race/class interaction and No. 4 for quality of life by the Princeton Review. Rice is also rated as a best value among private universities by Kiplinger’s Personal Finance.

Follow Rice News and Media Relations on Twitter @RiceUNews.

For more information, please click here

Contacts:
Jeff Falk
713-348-6775


Mike Williams
713-348-6728

Copyright © Rice University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Read the abstract at:

New nano building block takes a bow:

Angel Martí Group:

Rice Department of Chemistry:

Wiess School of Natural Sciences:

Related News Press

News and information

Researchers develop artificial building blocks of life March 8th, 2024

How surface roughness influences the adhesion of soft materials: Research team discovers universal mechanism that leads to adhesion hysteresis in soft materials March 8th, 2024

Two-dimensional bimetallic selenium-containing metal-organic frameworks and their calcinated derivatives as electrocatalysts for overall water splitting March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

2 Dimensional Materials

First human trial shows ‘wonder’ material can be developed safely: A revolutionary nanomaterial with huge potential to tackle multiple global challenges could be developed further without acute risk to human health, research suggests February 16th, 2024

NRL discovers two-dimensional waveguides February 16th, 2024

$900,000 awarded to optimize graphene energy harvesting devices: The WoodNext Foundation's commitment to U of A physicist Paul Thibado will be used to develop sensor systems compatible with six different power sources January 12th, 2024

Graphene/ Graphite

First human trial shows ‘wonder’ material can be developed safely: A revolutionary nanomaterial with huge potential to tackle multiple global challenges could be developed further without acute risk to human health, research suggests February 16th, 2024

NRL discovers two-dimensional waveguides February 16th, 2024

Govt.-Legislation/Regulation/Funding/Policy

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

Researchers’ approach may protect quantum computers from attacks March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

Optically trapped quantum droplets of light can bind together to form macroscopic complexes March 8th, 2024

Possible Futures

Two-dimensional bimetallic selenium-containing metal-organic frameworks and their calcinated derivatives as electrocatalysts for overall water splitting March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Discoveries

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

Researchers’ approach may protect quantum computers from attacks March 8th, 2024

High-tech 'paint' could spare patients repeated surgeries March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Materials/Metamaterials/Magnetoresistance

How surface roughness influences the adhesion of soft materials: Research team discovers universal mechanism that leads to adhesion hysteresis in soft materials March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Focused ion beam technology: A single tool for a wide range of applications January 12th, 2024

Catalytic combo converts CO2 to solid carbon nanofibers: Tandem electrocatalytic-thermocatalytic conversion could help offset emissions of potent greenhouse gas by locking carbon away in a useful material January 12th, 2024

Announcements

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers/Posters

Researchers develop artificial building blocks of life March 8th, 2024

How surface roughness influences the adhesion of soft materials: Research team discovers universal mechanism that leads to adhesion hysteresis in soft materials March 8th, 2024

Curcumin nanoemulsion is tested for treatment of intestinal inflammation: A formulation developed by Brazilian researchers proved effective in tests involving mice March 8th, 2024

Nanoscale CL thermometry with lanthanide-doped heavy-metal oxide in TEM March 8th, 2024

Military

What heat can tell us about battery chemistry: using the Peltier effect to study lithium-ion cells March 8th, 2024

The Access to Advanced Health Institute receives up to $12.7 million to develop novel nanoalum adjuvant formulation for better protection against tuberculosis and pandemic influenza March 8th, 2024

New chip opens door to AI computing at light speed February 16th, 2024

NRL discovers two-dimensional waveguides February 16th, 2024

Grants/Sponsored Research/Awards/Scholarships/Gifts/Contests/Honors/Records

Discovery of new Li ion conductor unlocks new direction for sustainable batteries: University of Liverpool researchers have discovered a new solid material that rapidly conducts lithium ions February 16th, 2024

$900,000 awarded to optimize graphene energy harvesting devices: The WoodNext Foundation's commitment to U of A physicist Paul Thibado will be used to develop sensor systems compatible with six different power sources January 12th, 2024

Catalytic combo converts CO2 to solid carbon nanofibers: Tandem electrocatalytic-thermocatalytic conversion could help offset emissions of potent greenhouse gas by locking carbon away in a useful material January 12th, 2024

'Sudden death' of quantum fluctuations defies current theories of superconductivity: Study challenges the conventional wisdom of superconducting quantum transitions January 12th, 2024

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project