Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Lighting the Way to Graphene-based Devices: Berkeley Lab Researchers Use Light to Dope Graphene Boron Nitride Heterostructures

Semiconductors made from graphene and boron nitride can be charge-doped using light. When the GBN heterostructure is exposed to light (green arrows), positive charges move from the graphene layer (purple) to boron nitride layer (blue).
Semiconductors made from graphene and boron nitride can be charge-doped using light. When the GBN heterostructure is exposed to light (green arrows), positive charges move from the graphene layer (purple) to boron nitride layer (blue).

Abstract:
Graphene continues to reign as the next potential superstar material for the electronics industry, a slimmer, stronger and much faster electron conductor than silicon. With no natural energy band-gap, however, graphene's superfast conductance can't be switched off, a serious drawback for transistors and other electronic devices. Various techniques have been deployed to overcome this problem with one of the most promising being the integration of ultrathin layers of graphene and boron nitride into two-dimensional heterostructures. As conductors, these bilayered hybrids are almost as fast as pure graphene, plus they are well-suited for making devices. However, tailoring the electronic properties of graphene boron nitride (GBN) heterostructures has been a tricky affair, involving chemical doping or electrostatic-gating - until now.

Lighting the Way to Graphene-based Devices: Berkeley Lab Researchers Use Light to Dope Graphene Boron Nitride Heterostructures

Berkeley, CA | Posted on May 18th, 2014

Researchers with Berkeley Lab and the University of California (UC) Berkeley have demonstrated a technique whereby the electronic properties of GBN heterostructures can be modified with visible light. Feng Wang, a condensed matter physicist with Berkeley Lab's Materials Sciences Division and UC Berkeley's Physics Department, as well as an investigator for the Kavli Energy NanoSciences Institute at Berkeley, led a study in which photo-induced doping of GBN heterostructures was used to create p-n junctions and other useful doping profiles while preserving the material's remarkably high electron mobility.

"We've demonstrated that visible light can induce a robust writing and erasing of charge-doping in GBN heterostructures without sacrificing high carrier mobility," Wang says. "The use of visible light gives us incredible flexibility and, unlike electrostatic gating and chemical doping, does not require multi-step fabrication processes that reduce sample quality. Additionally, different patterns can be imparted and erased at will, which was not possible with doping techniques previously used on GBN heterostructures."

Graphene is a single layer of carbon atoms arranged in a hexagonal lattice. Boron nitride is a layered compound that features a similar hexagonal lattice - in fact hexagonal boron nitride is sometimes referred to as "white graphene." Bound together by the relatively weak intermolecular attraction known as the van der Waals force, GBN heterostructures have shown high potential to serve as platforms not only for high-electron-mobility transistors, but also for optoelectronic applications, including photodetectors and photovoltaic cells. The key to future success will be the ability to dope these materials in a commercially scalable manner. The photo-induced modulation doping technique developed by Wang and a large team of collaborators meets this requirement as it is comparable to the photolithography schemes widely used today for mass production in the semiconductor industry. Illumination of a GBN heterostructure even with just an incandescent lamp can modify electron-transport in the graphene layer by inducing a positive-charge distribution in the boron nitride layer that becomes fixed when the illumination is turned off.

"We've shown show that this photo-induced doping arises from microscopically coupled optical and electrical responses in the GBN heterostructures, including optical excitation of defect transitions in boron nitride, electrical transport in graphene, and charge transfer between boron nitride and graphene," Wang says. "This is analogous to the modulation doping first developed for high-quality semiconductors."

While the photo-induced modulation doping of GBN heterostructures only lasted a few days if the sample was kept in darkness - further exposure to light erased the effect - this is not a concern as Wang explains.

"A few days of modulation doping are sufficient for many avenues of scientific inquiry, and for some device applications, the rewritability we can provide is needed more than long term stability," he says. "For the moment, what we have is a simple technique for inhomogeneous doping in a high-mobility graphene material that opens the door to novel scientific studies and applications."

A paper on this research has been published in the journal Nature Nanotechnology entitled "Photoinduced doping in heterostructures of graphene and boron nitride." Co-authors are Long Ju, Jairo Velasco Jr., Edwin Huang, Salman Kahn, Casey Nosiglia, Hsin-Zon Tsai, Wei Yang, Takashi Taniguchi, Kenji Watanabe, Yuanbo Zhang, Guangyu Zhang, Michael Crommie and Alex Zettl.

This research was supported by the U.S. Department of Energy's Office of Science and the Office of Naval Research.

####

For more information, please click here

Contacts:
Lynn Yarris

510-486-5375

Copyright © DOE/Lawrence Berkeley National Laboratory

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Download article:

For more about the research of Feng Wang go here:

Related News Press

Laboratories

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

Francis Alexander Named Deputy Director of Brookhaven Lab's Computational Science Initiative February 16th, 2017

News and information

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

New nano approach could cut dose of leading HIV treatment in half February 24th, 2017

Atom-scale oxidation mechanism of nanoparticles helps develop anti-corrosion materials February 24th, 2017

Atomic force imaging used to study nematodes: KFU bionanotechnology lab (head - Dr. Rawil Fakhrullin) has obtained 3-D images of nematodes' cuticles February 23rd, 2017

Graphene/ Graphite

Strem Chemicals and Dotz Nano Ltd. Sign Distribution Agreement for Graphene Quantum Dots Collaboration February 21st, 2017

Oxford Instruments announces Dr Brad Ramshaw of Cornell University, as winner of the 2017 Lee Osheroff Richardson Science Prize February 20th, 2017

Graphene foam gets big and tough: Rice University's nanotube-reinforced material can be shaped, is highly conductive February 13th, 2017

Physics

Breakthrough with a chain of gold atoms: In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport February 20th, 2017

Research reveals novel quantum state in strange insulating materials February 14th, 2017

Govt.-Legislation/Regulation/Funding/Policy

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

Atom-scale oxidation mechanism of nanoparticles helps develop anti-corrosion materials February 24th, 2017

Atomic force imaging used to study nematodes: KFU bionanotechnology lab (head - Dr. Rawil Fakhrullin) has obtained 3-D images of nematodes' cuticles February 23rd, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Chip Technology

GLOBALFOUNDRIES Announces Availability of 45nm RF SOI to Advance 5G Mobile Communications: Optimized RF features deliver high-performance solutions for mmWave beam forming applications in 5G smartphones and base stations February 22nd, 2017

Strem Chemicals and Dotz Nano Ltd. Sign Distribution Agreement for Graphene Quantum Dots Collaboration February 21st, 2017

Particles from outer space are wreaking low-grade havoc on personal electronics February 19th, 2017

Liquid metal nano printing set to revolutionize electronics: Creating integrated circuits just atoms thick February 18th, 2017

Discoveries

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

New nano approach could cut dose of leading HIV treatment in half February 24th, 2017

Atom-scale oxidation mechanism of nanoparticles helps develop anti-corrosion materials February 24th, 2017

Atomic force imaging used to study nematodes: KFU bionanotechnology lab (head - Dr. Rawil Fakhrullin) has obtained 3-D images of nematodes' cuticles February 23rd, 2017

Announcements

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

New nano approach could cut dose of leading HIV treatment in half February 24th, 2017

Atom-scale oxidation mechanism of nanoparticles helps develop anti-corrosion materials February 24th, 2017

Atomic force imaging used to study nematodes: KFU bionanotechnology lab (head - Dr. Rawil Fakhrullin) has obtained 3-D images of nematodes' cuticles February 23rd, 2017

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

New nano approach could cut dose of leading HIV treatment in half February 24th, 2017

Atom-scale oxidation mechanism of nanoparticles helps develop anti-corrosion materials February 24th, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Military

'Lossless' metamaterial could boost efficiency of lasers and other light-based devices February 20th, 2017

Engineers shrink microscope to dime-sized device February 17th, 2017

Graphene foam gets big and tough: Rice University's nanotube-reinforced material can be shaped, is highly conductive February 13th, 2017

Meta-lenses bring benchtop performance to small, hand-held spectrometer: Game-changing nanostructure-based lenses allow smaller devices, increased functionality February 9th, 2017

Research partnerships

Sandia use confined nanoparticles to improve hydrogen storage materials performance: Big changes from a small package for hydrogen storage February 25th, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Graphene foam gets big and tough: Rice University's nanotube-reinforced material can be shaped, is highly conductive February 13th, 2017

Cedars-Sinai, UCLA Scientists Use New ‘Blood Biopsies’ With Experimental Device to Speed Cancer Diagnosis and Predict Disease Spread: Leading-Edge Research Is Part of National Cancer Moonshot Initiative February 13th, 2017

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project