Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Nanosheets and nanowires

This is a typical TEM image of as-prepared GeS nanowires with the inset showing a selected area electron diffraction pattern taken from GeS nanowires.

Credit: Liang Shi and Yumei Dai
This is a typical TEM image of as-prepared GeS nanowires with the inset showing a selected area electron diffraction pattern taken from GeS nanowires.

Credit: Liang Shi and Yumei Dai

Abstract:
Researchers in China, [J. Appl. Cryst. (2014). 47, 527-531] have found a convenient way to selectively prepare germanium sulfide nanostructures, including nanosheets and nanowires, that are more active than their bulk counterparts and could open the way to lower cost and safer optoelectronics, solar energy conversion and faster computer circuitry.

Nanosheets and nanowires

UK | Posted on April 1st, 2014

Germanium monosulfide, GeS, is emerging as one of the most important "IV-VI" semiconductor materials with potential in opto-electronics applications for telecommunications and computing, and as an absorber of light for use in solar energy conversion. One important property is its much lower toxicity and environmental impact when compared to other semiconductors made with cadmium, lead and mercury. It is less costly than other materials made with rare and noble metal elements. Indeed, glassy GeS has been used in lasers, fibre optic devices and infrared lenses as well as rewritable optical discs and non-volatile memory devices for several years. It is also used extensively as a solid electrolyte in conductive bridging random access memory (RAM) devices.

The repertoire of this material might be extended much further with the extra control that its use as nanostructured systems might allow. Liang Shi and Yumei Dai of the University of Science and Technology of China, in Hefei, point out that research in this area has lagged behind that with other IV-VI semiconductors. They hope to change that and have focused on how nanosheets and nanowires of GeS might be readily formed. They have used X-ray powder diffraction, transmission electron microscopy, energy-dispersive X-ray spectrometry and scanning electron microscopy to investigate the structure, morphology, composition and optical absorption properties of their samples.

The team used simple "wet" chemistry to synthesis their products using germanium dichloride-dioxane complex, thiourea and oleylamine (OLA) as starting materials. The ingredients were mixed in a sealed reaction flask, blasted with ultrasound to exclude air and then stirred and heated. The team was able to make nanosheets of GeS this way if the process was carried out for several hours at 593 Kelvin. At higher temperature, 613 Kelvin, they found that the sheets wind up into nanowires. Indeed, the precise heating time and temperature allowed them to control the structure of the final product. The team suggests that the rolling up of the nanosheets into nanowires is driven by the surface tension between the sheet and the OLA molecules during the heating.

Having proven the structural integrity of their GeS nanowires and nanosheets, the team built several test devices - a photoresponsive unit - which they used to evaluate the optical and electronic properties of the products. The team says that they have demonstrated "outstanding photoresponsive behaviour". This "indicates the potential use of as-synthesized GeS nanosheets and nanowires in solar energy conversion systems, such as the fabrication of photovoltaic devices".

####

About International Union of Crystallography
The IUCr is a scientific union adhering to the International Council for Science (ICSU). Its objectives are to promote international cooperation in crystallography and to contribute to all aspects of crystallography, to promote international publication of crystallographic research, to facilitate standardization of methods, units, nomenclatures and symbols, and to form a focus for the relations of crystallography to other sciences.

The IUCr fulfils these objectives by publishing in print and electronically primary scientific journals through Crystallography Journals Online, the series of reference volumes International Tables for Crystallography, distributing the quarterly IUCr Newsletter, maintaining the online World Directory/Database of Crystallographers, awarding the Ewald Prize and organising the triennial Congress and General Assembly.

For more information, please click here

Contacts:
Dr. Jonathan Agbenyega

44-124-434-2878

Copyright © International Union of Crystallography

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Tunable diamond string may hold key to quantum memory: A process similar to guitar tuning improves storage time of quantum memory May 24th, 2018

Remote control of transport through nanopores: New study outlines key factors affecting the transfer of molecules through biological channels May 24th, 2018

2018 Kavli Prizes in Astrophysics, Nanoscience, and Neuroscience to be Announced Live on May 31: Live announcement at the Norwegian Academy of Science and Letters to be streamed live at World Science Festival Event May 24th, 2018

Law enforcement/Anti-Counterfeiting/Security/Loss prevention

The dispute about the origins of terahertz photoresponse in graphene results in a draw April 26th, 2018

Graphene origami as a mechanically tunable plasmonic structure for infrared detection April 25th, 2018

Nuclear radiation detecting device could lead to new homeland security tool: New device can detect gamma rays and identify radioactive isotopes April 25th, 2018

Leti & Mapper announce cyber-security breakthrough that encrypts individual chips with a code: Low-Cost Cyber-Security Breakthrough that Encrypts Individual Chips With a Unique Code Presented at SPIE Advanced Lithography 2018 in San Jose March 2nd, 2018

Chip Technology

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Columbia Researchers Squeeze Light into Nanoscale Devices and Circuits: Team is first to directly image propagation and dynamics of graphene plasmons at very low temperatures; findings could impact optical communications and signal processing May 23rd, 2018

Supersonic waves may help electronics beat the heat May 18th, 2018

Deeper understanding of quantum chaos may be the key to quantum computers May 16th, 2018

Optical computing/Photonic computing

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Tunable diamond string may hold key to quantum memory: A process similar to guitar tuning improves storage time of quantum memory May 24th, 2018

Columbia Researchers Squeeze Light into Nanoscale Devices and Circuits: Team is first to directly image propagation and dynamics of graphene plasmons at very low temperatures; findings could impact optical communications and signal processing May 23rd, 2018

Strain improves performance of atomically thin semiconductor material May 11th, 2018

Discoveries

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Tunable diamond string may hold key to quantum memory: A process similar to guitar tuning improves storage time of quantum memory May 24th, 2018

Remote control of transport through nanopores: New study outlines key factors affecting the transfer of molecules through biological channels May 24th, 2018

'Spooky action at a distance': Researchers develop module for quantum repeater May 23rd, 2018

Announcements

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Tunable diamond string may hold key to quantum memory: A process similar to guitar tuning improves storage time of quantum memory May 24th, 2018

Remote control of transport through nanopores: New study outlines key factors affecting the transfer of molecules through biological channels May 24th, 2018

2018 Kavli Prizes in Astrophysics, Nanoscience, and Neuroscience to be Announced Live on May 31: Live announcement at the Norwegian Academy of Science and Letters to be streamed live at World Science Festival Event May 24th, 2018

Energy

Remote control of transport through nanopores: New study outlines key factors affecting the transfer of molecules through biological channels May 24th, 2018

Team achieves two-electron chemical reactions using light energy, gold May 15th, 2018

Hematene joins parade of new 2D materials: Rice University-led team extracts 3-atom-thick sheets from common iron oxide May 8th, 2018

A designer's toolkit for constructing complex nanoparticles May 5th, 2018

Photonics/Optics/Lasers

Switching with molecules: Molecular switch will facilitate the development of pioneering electro-optical devices May 25th, 2018

Columbia Researchers Squeeze Light into Nanoscale Devices and Circuits: Team is first to directly image propagation and dynamics of graphene plasmons at very low temperatures; findings could impact optical communications and signal processing May 23rd, 2018

A micro-thermometer to record tiny temperature changes May 15th, 2018

Strain improves performance of atomically thin semiconductor material May 11th, 2018

Solar/Photovoltaic

Team achieves two-electron chemical reactions using light energy, gold May 15th, 2018

Hematene joins parade of new 2D materials: Rice University-led team extracts 3-atom-thick sheets from common iron oxide May 8th, 2018

Harvesting clean hydrogen fuel through artificial photosynthesis May 3rd, 2018

Research gives new ray of hope for solar fuel April 27th, 2018

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project