Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Engineers teach old chemical new tricks to make cleaner fuels, fertilizers: Researchers from Denmark and Stanford show how to produce industrial quantities of hydrogen without emitting carbon into the atmosphere

On the left, a scanning tunneling microscope image captures the bright shape of the moly sulfide nanocluster on a graphite surface. The grey spots are carbon atoms. Together the moly sulfide and graphite make the electrode. The diagram on the right shows how two positive hydrogen ions gain electrons through a chemical reaction at the moly sulfide nanocluster to form pure molecular hydrogen.

Credit: Jakob Kibsgaard
On the left, a scanning tunneling microscope image captures the bright shape of the moly sulfide nanocluster on a graphite surface. The grey spots are carbon atoms. Together the moly sulfide and graphite make the electrode. The diagram on the right shows how two positive hydrogen ions gain electrons through a chemical reaction at the moly sulfide nanocluster to form pure molecular hydrogen.

Credit: Jakob Kibsgaard

Abstract:
University researchers from two continents have engineered an efficient and environmentally friendly catalyst for the production of molecular hydrogen (H2), a compound used extensively in modern industry to manufacture fertilizer and refine crude oil into gasoline.

Engineers teach old chemical new tricks to make cleaner fuels, fertilizers: Researchers from Denmark and Stanford show how to produce industrial quantities of hydrogen without emitting carbon into the atmosphere

Stanford, CA | Posted on January 27th, 2014

Although hydrogen is abundant element, it is generally not found as the pure gas H2but is generally bound to oxygen in water (H2O) or to carbon in methane (CH4), the primary component in natural gas. At present, industrial hydrogen is produced from natural gas using a process that consumes a great deal of energy while also releasing carbon into the atmosphere, thus contributing to global carbon emissions.

In an article published today (Jan. 26, 1300 EST) in Nature Chemistry, nanotechnology experts from Stanford Engineering and from Denmark's Aarhus University explain how to liberate hydrogen from water on an industrial scale by using electrolysis .

In electrolysis, electrical current flows through a metallic electrode immersed in water. This electron flow induces a chemical reaction that breaks the bonds between hydrogen and oxygen atoms. The electrode serves as a catalyst, a material that can spur one reaction after another without ever being used up. Platinum is the best catalyst for electrolysis. If cost were no object, platinum might be used to produce hydrogen from water today.

But money matters. The world consumes about 55 billion kilograms of hydrogen per year. It now costs about $1 to $2 per kilogram to produce hydrogen from methane. So any competing process, even if it's greener, must hit that production cost, which rules out electrolysis based on platinum.

In their Nature Chemistry paper, the researchers describe how they re-engineered the atomic structure of a cheap and common industrial material to make it nearly as efficient at electrolysis as platinum - a finding that has the potential to revolutionize industrial hydrogen production.

The project was conceived by Jakob Kibsgaard, a post-doctoral researcher with Thomas Jaramillo, an assistant professor of chemical engineering at Stanford. Kibsgaard started this project while working with Flemming Besenbacher, a professor at the Interdisciplinary Nanoscience Center (iNANO) at Aarhus.

Subhead: Meet Moly Sulfide

Since World War II petroleum engineers have used molybdenum sulfide - moly sulfide for short - to help refine oil.

Until now, however, this chemical was not considered a good catalyst for making moly sulfide to produce hydrogen from water through electrolysis. Eventually scientists and engineers came to understand why: the most commonly used moly sulfide materials had an unsuitable arrangement of atoms at their surface.

Typically, each sulfur atom on the surface of a moly sulfide crystal is bound to three molybdenum atoms underneath. For complex reasons involving the atomic bonding properties of hydrogen, that configuration isn't conducive to electrolysis.

In 2004, Stanford chemical engineering professor Jens Norskov, then at the Technical University of Denmark, made an important discovery. Around the edges of the crystal, some sulfur atoms are bound to just two molybdenum atoms. At these edge sites, which are characterized by double rather than triple bonds, moly sulfide was much more effective at forming H2.

Armed with that knowledge, Kibsgaard found a 30-year-old recipe for making a form of moly sulfide with lots of these double-bonded sulfurs at the edge.

Using simple chemistry, he synthesized nanoclusters of this special moly sulfide. He deposited these nanoclusters onto a sheet of graphite, a material that conducts electricity. Together the graphite and moly sulfide formed a cheap electrode. It was meant to be a substitute for platinum, the ideal but expensive catalyst for electrolysis.

The question then became: could this composite electrode efficiently spur the chemical reaction that rearranges hydrogen and oxygen atoms in water?

As Jaramillo put it: "Chemistry is all about where electrons want to go, and catalysis is about getting those electrons to move to make and break chemical bonds."

Subhead: The acid test

So the experimenters put their system to the acid test -- literally.

They immersed their composite electrode into water that was slightly acidified, meaning it contained positively charged hydrogen ions. These positive ions were attracted to the moly sulfide clusters. Their double-bonded shape gave them just the right atomic characteristic to pass electrons from the graphite conductor up to the positive ions. This electron transfer turned the positive ions into neutral molecular hydrogen, which bubbled up and away as a gas.

Most importantly, the experimenters found that their cheap, moly sulfide catalyst had the potential to liberate hydrogen from water on something approaching the efficiency of a system based on prohibitively expensive platinum.

Subhead: Yes, but does it scale?

But in chemical engineering, success in a beaker is only the beginning.

The larger questions were: could this technology scale to the 55 billion kilograms per year global demand for hydrogen, and at what finished cost per kilogram?

Last year, Jaramillo and a dozen co-authors studied four factory-scale production schemes in an article for The Royal Society of Chemistry's journal of Energy and Environmental Science.

They concluded that it could be feasible to produce hydrogen in factory-scale electrolysis facilities at costs ranging from $1.60 and $10.40 per kilogram - competitive at the low end with current practices based on methane -- though some of their assumptions were based on new plant designs and materials.

"There are many pieces of the puzzle still needed to make this work, and much effort ahead to realize them," Jaramillo said. "However, we can get huge returns by moving from carbon-intensive resources to renewable, sustainable technologies to produce the chemicals we need for food and energy."

####

For more information, please click here

Contacts:
Tom Abate

650-736-2245

Copyright © Stanford School of Engineering

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

European & Korean Project To Demo World’s First 5G Platform During Winter Games February 15th, 2018

Chemistry

Ultra-efficient removal of carbon monoxide using gold nanoparticles on a molecular support: New method and mechanism for state-of-the-art gas purification February 9th, 2018

Fast-spinning spheres show nanoscale systems' secrets: Rice University lab demonstrates energetic properties of colloids in spinning magnetic field February 7th, 2018

New filters could enable manufacturers to perform highly-selective chemical separation January 23rd, 2018

Nanowrinkles could save billions in shipping and aquaculture Surfaces inspired by carnivorous plants delay degradation by marine fouling January 17th, 2018

Discoveries

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Announcements

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

Arrowhead Receives Regulatory Clearance to Begin Phase 1/2 Study of ARO-HBV for Treatment of Hepatitis B February 15th, 2018

Arrowhead Pharmaceuticals Receives Orphan Drug Designation for ARO-AAT February 15th, 2018

European & Korean Project To Demo World’s First 5G Platform During Winter Games February 15th, 2018

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals/White papers

Photonic chip guides single photons, even when there are bends in the road February 16th, 2018

'Living bandages': NUST MISIS scientists develop biocompatible anti-burn nanofibers February 15th, 2018

Rutgers-Led Innovation Could Spur Faster, Cheaper, Nano-Based Manufacturing: Scalable and cost-effective manufacturing of thin film devices February 14th, 2018

Understanding brain functions using upconversion nanoparticles: Researchers can now send light deep into the brain to study neural activities February 14th, 2018

Food/Agriculture/Supplements

Graphene on toast, anyone? Rice University scientists create patterned graphene onto food, paper, cloth, cardboard February 13th, 2018

Silk fibers could be high-tech ‘natural metamaterials’ January 31st, 2018

Nanowrinkles could save billions in shipping and aquaculture Surfaces inspired by carnivorous plants delay degradation by marine fouling January 17th, 2018

Rice U.'s one-step catalyst turns nitrates into water and air: NSF-funded NEWT Center aims for catalytic converter for nitrate-polluted water January 5th, 2018

Energy

Round-the-clock power from smart bowties February 5th, 2018

Silk fibers could be high-tech ‘natural metamaterials’ January 31st, 2018

A simple new approach to plastic solar cells: Osaka University researchers intelligently design new highly efficient organic solar cells based on amorphous electronic materials with potential for easy printing January 28th, 2018

Nature paper by Schlumberger researchers used photothermal based nanoscale IR spectroscopy to analyze heterogeneous process of petroleum generation January 23rd, 2018

Industrial

Ultra-efficient removal of carbon monoxide using gold nanoparticles on a molecular support: New method and mechanism for state-of-the-art gas purification February 9th, 2018

A simple new approach to plastic solar cells: Osaka University researchers intelligently design new highly efficient organic solar cells based on amorphous electronic materials with potential for easy printing January 28th, 2018

Nature paper by Schlumberger researchers used photothermal based nanoscale IR spectroscopy to analyze heterogeneous process of petroleum generation January 23rd, 2018

New filters could enable manufacturers to perform highly-selective chemical separation January 23rd, 2018

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project