Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > New iron catalyst promises green future for hydrogenation

Iron nanoparticles (diameter: 90 micrometers)
Iron nanoparticles (diameter: 90 micrometers)

Abstract:
A new iron nanoparticle catalyst developed by researchers in Japan and Canada promises to drastically improve the efficiency of hydrogenation, a key chemical process used in a wide array of industrial applications. Cleaner, safer and cheaper than traditional rare metal-based catalysts, the new, more environmentally friendly technique marks a breakthrough for the emerging field of green chemistry.

New iron catalyst promises green future for hydrogenation

Wako, Japan | Posted on June 28th, 2013

Hydrogenation, the reaction of molecular hydrogen with another compound or element, is one of the world's most highly studied chemical reactions, with industrial applications ranging from petrochemistry, to food production, to pharmaceuticals.

Most such applications of hydrogenation use rare metal catalysts such as palladium or platinum to speed up chemical reactions. While highly efficient, these metals are expensive and limited in supply, posing environmental and economic challenges.

To get around these problems, researchers at McGill University, the RIKEN Center for Sustainable Resource Science and the Institute for Molecular Science developed their new technique using iron, a much less expensive and far more abundant element. Iron has been ruled out in the past due to the fact that it rusts in the presence of oxygen and water, negating its catalytic effect.

The new technique, described in a paper published in the journal Green Chemistry, produces iron nanoparticles directly inside a polymer matrix, which protects the iron surface from rusting while allowing the reactants to reach it and react. The resulting system of polymer-stabilized iron nanoparticles in water is the first of its kind: a safe, cheap and environmentally friendly catalyst system for hydrogenation reactions.

"Our aim is to develop iron-based catalysts not only for hydrogenation but also a variety of organic transformations that can be used in future industrial applications," explains RIKEN researcher Dr. Yoichi M. A. Yamada, one of the authors of the paper. "If rare metal-based catalysts can be replaced by iron-based ones, then we can overcome our costly and dangerous dependency on rare metals."

Full bibliographic information

Reuben Hudson, Go Hamasaka, Takao Osako, Yochi M. A. Yamada, Chao-Jun Li, Yasuhiro Uozumi, and Audrey Moores. Highly Efficient Iron(0) Nanoparticle-Catalyzed Hydrogenation in Water in Flow, Green Chemistry. doi:10.1039/C3GC40789F

####

About RIKEN
RIKEN is Japan’s flagship research institute devoted to basic and applied research. Over 2500 papers by RIKEN researchers are published every year in reputable scientific and technical journals, covering topics ranging across a broad spectrum of disciplines including physics, chemistry, biology, medical science and engineering. RIKEN’s advanced research environment and strong emphasis on interdisciplinary collaboration has earned itself an unparalleled reputation for scientific excellence in Japan and around the world.

Reach us on Twitter: @rikenresearch

For more information, please click here

Contacts:
Juliette Savin
RIKEN
Global Relations and Research Coordination Office

Copyright © AlphaGalileo

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Arrowhead Pharmaceuticals to Webcast Fiscal 2017 Third Quarter Results July 27th, 2017

Strange electrons break the crystal symmetry of high-temperature superconductors: Brookhaven Lab scientists discover spontaneous voltage perpendicular to applied current that may help unravel the mystery of high-temperature superconductors July 27th, 2017

Getting closer to porous, light-responsive materials: A new flexible material changes its porous nature when exposed to light July 27th, 2017

First Capacitive Transducer with 13nm Gap July 27th, 2017

Living computers: RNA circuits transform cells into nanodevices July 27th, 2017

Chemistry

Getting closer to porous, light-responsive materials: A new flexible material changes its porous nature when exposed to light July 27th, 2017

Discoveries

Physicists gain new insights into nanosystems with spherical confinement: Enormous potential for the targeted delivery of pharmaceutical agents and the creation of tailored nanoparticles July 27th, 2017

Strange electrons break the crystal symmetry of high-temperature superconductors: Brookhaven Lab scientists discover spontaneous voltage perpendicular to applied current that may help unravel the mystery of high-temperature superconductors July 27th, 2017

Getting closer to porous, light-responsive materials: A new flexible material changes its porous nature when exposed to light July 27th, 2017

First Capacitive Transducer with 13nm Gap July 27th, 2017

Announcements

Rice U. scientists map ways forward for lithium-ion batteries for extreme environments: Paper details developments toward high-temperature batteries July 27th, 2017

Ultracold molecules hold promise for quantum computing: New approach yields long-lasting configurations that could provide long-sought “qubit” material July 27th, 2017

Atomic discovery opens door to greener, faster, smaller electronic circuitry: Scientists find way to correct communication pathways in silicon chips, making them perfect July 27th, 2017

Physicists gain new insights into nanosystems with spherical confinement: Enormous potential for the targeted delivery of pharmaceutical agents and the creation of tailored nanoparticles July 27th, 2017

Industrial

3-D-printed jars in ball-milling experiments June 29th, 2017

Rice U. chemists create 3-D printed graphene foam June 22nd, 2017

Alloying materials of different structures offers new tool for controlling properties June 19th, 2017

Carbodeon demonstrates NanoDiamond nickel coatings with enhanced tribological properties June 7th, 2017

Research partnerships

Strange electrons break the crystal symmetry of high-temperature superconductors: Brookhaven Lab scientists discover spontaneous voltage perpendicular to applied current that may help unravel the mystery of high-temperature superconductors July 27th, 2017

Getting closer to porous, light-responsive materials: A new flexible material changes its porous nature when exposed to light July 27th, 2017

Regulation of two-dimensional nanomaterials: New driving force for lithium-ion batteries July 26th, 2017

Studying Argon Gas Trapped in Two-Dimensional Array of Tiny "Cages": Understanding how individual atoms enter and exit the nanoporous frameworks could help scientists design new materials for gas separation and nuclear waste remediation July 17th, 2017

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project