Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Titanium dioxide nanoreactor

The titanium dioxide nanoparticles crystallize in a polymer network at room temperature.
The titanium dioxide nanoparticles crystallize in a polymer network at room temperature.

Abstract:
Tiny particles of titanium dioxide are found as key ingredients in wall paints, sunscreens, and toothpaste; they act as reflectors of light or as abrasives. However with decreasing particle size and a corresponding change in their surface-to-volume ratio, their properties change so that crystalline titanium dioxide nanoparticles acquire catalytic ability: Activated by the UV component in sunlight, they break down toxins or catalyze other relevant reactions.

Titanium dioxide nanoreactor

Germany | Posted on February 21st, 2013

Now, Dr. Katja Henzler and a team of chemists at the Helmholtz Centre Berlin have developed a synthesis to produce nanoparticles at room temperature in a polymer network. Their analysis, conducted at BESSY II, Berlin's synchrotron radiation source, has revealed the crystalline structure of the nanoparticles. This represents a major step forward in the usage of polymeric nanoreactors since, until recently, the nanoparticles had to be thoroughly heated to get them to crystallize. The last synthesis step can be spared due to the special environment inside the PNIPAM network.

The Henzler team's polymeric nanoreactors consist of a polystyrene core surrounded by a network of PNIPAM chains. A titanium compound was added to an ethanolic solution of the polymer colloids, which did trigger the formation of small titanium dioxide particles within the PNIPAM network. The BESSY II experiments showed that the chemists were able to control the speed of these processes while at the same time affecting the quality of the nanocrystals that had formed.

Using the novel combination of x-ray microscopy and spectroscopy (NEXAFS-TXM, U41-SGM) at BESSY II, Henzler and the microscopy team were able to show that the nanoparticles are homogeneously distributed over the polymeric nanoreactors. The researchers examined their samples in a cryogenic aqueous environment, which prevents artifact formation due to sample drying. Their analysis showed that the nanoparticles have a crystalline structure. "The nanocrystals have a tetragonal anatase structure and this crystalline structure is a key to their catalytic performance. Additionally, our new analytic method allows us to control the quality of the synthesized particles so that we can optimize them for relevant applications," says Katja Henzler.

####

For more information, please click here

Contacts:
Katja Henzler

49-030-806-243-198

Press Office
Dr. Antonia Rötger
Tel (030) 8062 - 43733
Fax (030) 8062 - 42998

Copyright © Helmholtz Association of German Research Centres

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Nano Letters, 2013, 13 (2), pp 824–828; DOI: 10.1021/nl3046798:

Related News Press

News and information

Dr Barbara Armbruster promoted to Worldwide Sales and Marketing Director for XEI Scientific September 27th, 2016

Fighting cancer with sticky nanoparticles September 27th, 2016

Gold nanoparticles conjugated quercetin inhibits epithelial-mesenchymal transition, angiogenesis and invasiveness via EGFR/VEGFR-2 mediated pathway in breast cancer September 27th, 2016

UNAM develops successful nano edible coating which increases life food September 27th, 2016

Researchers at the Catalan Institute of Nanoscience and Nanotechnology show that bending semiconductors generates electricity September 26th, 2016

Laboratories

Crystalline Fault Lines Provide Pathway for Solar Cell Current: New tomographic AFM imaging technique reveals that microstructural defects, generally thought to be detrimental, actually improve conductivity in cadmium telluride solar cells September 26th, 2016

Chemistry

Chains of nanogold – forged with atomic precision September 23rd, 2016

Imaging

Oxford Instruments is ‘Bringing the Nanoworld Together’ in India once again - 22 - 23 November 2016 | IISc Bangalore September 21st, 2016

Bruker Introduces Complete Commercial AFM-Based SECM Solution: PeakForce SECM Mode Enables Previously Unobtainable Electrochemical Information September 20th, 2016

Iran to hold intl. school on application of nanomaterials in medicine September 20th, 2016

Oxford Instruments Asylum Research Announces New SurfRider Econo Board Probes for Routine AFM Measurements September 19th, 2016

Discoveries

Fighting cancer with sticky nanoparticles September 27th, 2016

Gold nanoparticles conjugated quercetin inhibits epithelial-mesenchymal transition, angiogenesis and invasiveness via EGFR/VEGFR-2 mediated pathway in breast cancer September 27th, 2016

UNAM develops successful nano edible coating which increases life food September 27th, 2016

Crystalline Fault Lines Provide Pathway for Solar Cell Current: New tomographic AFM imaging technique reveals that microstructural defects, generally thought to be detrimental, actually improve conductivity in cadmium telluride solar cells September 26th, 2016

Announcements

Dr Barbara Armbruster promoted to Worldwide Sales and Marketing Director for XEI Scientific September 27th, 2016

Fighting cancer with sticky nanoparticles September 27th, 2016

Gold nanoparticles conjugated quercetin inhibits epithelial-mesenchymal transition, angiogenesis and invasiveness via EGFR/VEGFR-2 mediated pathway in breast cancer September 27th, 2016

UNAM develops successful nano edible coating which increases life food September 27th, 2016

Tools

Dr Barbara Armbruster promoted to Worldwide Sales and Marketing Director for XEI Scientific September 27th, 2016

Oxford Instruments is ‘Bringing the Nanoworld Together’ in India once again - 22 - 23 November 2016 | IISc Bangalore September 21st, 2016

Bruker Introduces Complete Commercial AFM-Based SECM Solution: PeakForce SECM Mode Enables Previously Unobtainable Electrochemical Information September 20th, 2016

Oxford Instruments Asylum Research Announces New SurfRider Econo Board Probes for Routine AFM Measurements September 19th, 2016

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







Car Brands
Buy website traffic