Nanotechnology Now

Our NanoNews Digest Sponsors





Heifer International

Wikipedia Affiliate Button


android tablet pc

Home > Press > Essential armchair reading for nanotube researchers: Rice, NIST kick off collaboration with comprehensive look at the fundamentals of most desirable nanotubes

Armchair carbon nanotubes, so named for the arrangement of atoms that make their ends look like armchairs, are the most desirable among nanotube researchers for their superior electrical properties. They are the subject of a new paper by Rice University and the National Institute of Standards and Technology. (Credit: Erik Hároz/Rice University)
Armchair carbon nanotubes, so named for the arrangement of atoms that make their ends look like armchairs, are the most desirable among nanotube researchers for their superior electrical properties. They are the subject of a new paper by Rice University and the National Institute of Standards and Technology.

(Credit: Erik Hároz/Rice University)

Abstract:
The first fruits of a cooperative venture between scientists at Rice University and the National Institute of Standards and Technology (NIST) have appeared in a paper that brings together a wealth of information for those who wish to use the unique properties of metallic carbon nanotubes.

Essential armchair reading for nanotube researchers: Rice, NIST kick off collaboration with comprehensive look at the fundamentals of most desirable nanotubes

Houston, TX | Posted on February 5th, 2013

The feature article published recently in the Royal Society of Chemistry journal Nanoscale gathers research about the separation and fundamental characteristics of armchair carbon nanotubes, which have been of particular interest to researchers trying to tune their electronic and optical properties.

This paper, said Rice physicist Junichiro Kono, provides scientists a valuable resource for detailed information about metallic carbon nanotubes, especially armchair nanotubes. "Basically, we summarized all our recent findings as well as all information we could find in the literature about metallic nanotubes, along with detailed accounts of preparation methods for metal-enriched nanotube samples, to show the community just how much we now understand about these one-dimensional metals," he said.

As part of the lengthy work, the team compiled and published tables of essential statistics, including optical properties, for a variety of metallic nanotubes. "We provide fundamental theoretical backgrounds and then show very detailed experimental results on unique properties of metallic nanotubes," Kono said. "This paper summarizes what kind of aspects are understood, and what is not, about fundamental optical processes in nanotubes and will make it easier for researchers to identify their spectroscopic features and transition energies."

Nanotubes come in many flavors, depending on their chirality. Chirality is a characteristic akin to the angles at which a flat sheet of paper might align when wrapped into a tube. Cut the tube in half and the atoms at the open edge would line up in the shape of an armchair, a zigzag or some variant. Even though their raw material is identical - chicken-wire-like hexagons of carbon - the chirality makes all the difference in how nanotubes transmit electricity.

Armchairs are the most coveted because they have no band gap; electrons flow through without resistance. Cables made with armchair nanotubes have the potential to move electricity over great distances with virtually no loss. That makes them the gold standard as the basic element of armchair quantum wire. The ongoing development of this very strong, lightweight, high-capacity cable could improve further the record properties of multifunctional carbon nanotube fibers that are being developed by the group of Rice Professor Matteo Pasquali.

The new work led by Kono and Robert Hauge, a distinguished faculty fellow in chemistry at Rice, along with scientists at NIST and Los Alamos National Laboratory, looks beyond the armchair's established electrical properties to further detail their potential for electronic, sensing, optical and photonic devices.

"Of course, to get there, we need really good samples," Kono said. "Many applications will rely on our ability to separate carbon nanotubes and then assemble macroscopically ordered structures consisting of single-chirality nanotubes. Nobody can do that at this point."

When a batch of nanotubes comes out of a furnace, it's a jumble of types. That makes detailed analysis of their characteristics -- let alone their practical use -- a challenge.

But techniques developed in recent years at Rice and by NIST scientist Ming Zheng to purify metallic nanotubes are beginning to change that. Rice graduate student Erik Hároz said recent experiments established "unambiguous evidence" that a process he and Kono are using called density gradient ultracentrifugation can enrich ensemble samples of armchairs. Taking things further, Zheng's method of DNA-based ion-exchange chromatography provides very small samples of ultrapure armchair nanotubes of a single chirality.

Rice and NIST are now looking at ways to combine the methods to get larger batches of a specific armchair chirality, Kono said.

If anyone can accomplish such a breakthrough, these labs can, he said. "Our team has the best possible armchair samples available due to these two methods, and we have recently made significant progress in increasing our understanding of the properties of armchair nanotubes, as described in this Nanoscale article."

Co-authors of the paper with Hároz, Hauge, Zheng and Kono are Juan Duque, who earned his doctorate at Rice and is now a research scientist at Los Alamos; Xiaomin Tu, a former postdoctoral researcher at NIST, now an intellectual property subject matter expert at Chevron; Angela Hight Walker, project leader in the Semiconductor and Dimensional Metrology Division at NIST; and Stephen Doorn, science partner leader in the Center for Integrated Nanotechnologies at Los Alamos. Kono is a professor of electrical and computer engineering and of physics and astronomy at Rice. Pasquali is a professor of chemical and biomolecular engineering and of chemistry.

The National Science Foundation, the Department of Energy, the Air Force Research Laboratories, Los Alamos National Laboratory, the Robert A. Welch Foundation, NASA and the World Class University Program at Sungkyunkwan University supported the research.

####

About Rice University
Located on a 300-acre forested campus in Houston, Rice University is consistently ranked among the nation's top 20 universities by U.S. News & World Report. Rice has highly respected schools of Architecture, Business, Continuing Studies, Engineering, Humanities, Music, Natural Sciences and Social Sciences and is home to the Baker Institute for Public Policy. With 3,708 undergraduates and 2,374 graduate students, Rice's undergraduate student-to-faculty ratio is 6-to-1. Its residential college system builds close-knit communities and lifelong friendships, just one reason why Rice has been ranked No. 1 for best quality of life multiple times by the Princeton Review and No. 2 for "best value" among private universities by Kiplinger's Personal Finance. To read "What they're saying about Rice," go to tinyurl.com/AboutRiceU.

Follow Rice News and Media Relations via Twitter @RiceUNews

For more information, please click here

Contacts:
David Ruth
713-348-6327


Mike Williams
713-348-6728

Copyright © Rice University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Read the abstract at:

Richard E. Smalley Institute for Nanoscale Science and Technology:

Nano parfait a treat for scientists:

DNA-assisted dispersion and separation of carbon nanotubes:

Related News Press

News and information

First Observation of Electronic Structure in Ag-Rh Alloy Nanoparticles Having Hydrogen Absorbing: Storage Property –Attempting to solve the mystery of why Ag-Rh alloy nanoparticles have a similar property to Pd– October 30th, 2014

Iranians Present Model to Predict Photocatalytic Process in Removal of Pollutants October 30th, 2014

Production of Biocompatible Polymers in Iran October 30th, 2014

Amorphous Coordination Polymer Particles as alternative to classical nanoplatforms for nanomedicine October 30th, 2014

Lomiko Signs Licensing Agreement to Produce and Supply Power Converter Systems to E-Commerce Customers October 29th, 2014

Laboratories

Tiny carbon nanotube pores make big impact October 29th, 2014

New evidence for an exotic, predicted superconducting state October 27th, 2014

National Synchrotron Light Source II Achieves 'First Light' October 23rd, 2014

Govt.-Legislation/Regulation/Funding/Policy

'Electronic skin' could improve early breast cancer detection October 29th, 2014

New solar power material converts 90 percent of captured light into heat: SunShot Project aims to make solar cost competitive October 29th, 2014

Tiny carbon nanotube pores make big impact October 29th, 2014

Microrockets fueled by water neutralize chemical and biological warfare agents October 29th, 2014

Nanotubes/Buckyballs

Tiny carbon nanotube pores make big impact October 29th, 2014

Materials for the next generation of electronics and photovoltaics: MacArthur Fellow develops new uses for carbon nanotubes October 21st, 2014

Special UO microscope captures defects in nanotubes: University of Oregon chemists provide a detailed view of traps that disrupt energy flow, possibly pointing toward improved charge-carrying devices October 21st, 2014

Imaging electric charge propagating along microbial nanowires October 20th, 2014

Sensors

Tiny carbon nanotube pores make big impact October 29th, 2014

MEMS & Sensors Technology Showcase: Finalists Announced for MEMS Executive Congress US 2014 October 23rd, 2014

Journal Nanotechnology Progress International (JONPI), 2014, Volume 5, Issue 1, pp 1-24 October 22nd, 2014

Imaging electric charge propagating along microbial nanowires October 20th, 2014

Discoveries

First Observation of Electronic Structure in Ag-Rh Alloy Nanoparticles Having Hydrogen Absorbing: Storage Property –Attempting to solve the mystery of why Ag-Rh alloy nanoparticles have a similar property to Pd– October 30th, 2014

Iranians Present Model to Predict Photocatalytic Process in Removal of Pollutants October 30th, 2014

Production of Biocompatible Polymers in Iran October 30th, 2014

Amorphous Coordination Polymer Particles as alternative to classical nanoplatforms for nanomedicine October 30th, 2014

Announcements

First Observation of Electronic Structure in Ag-Rh Alloy Nanoparticles Having Hydrogen Absorbing: Storage Property –Attempting to solve the mystery of why Ag-Rh alloy nanoparticles have a similar property to Pd– October 30th, 2014

Iranians Present Model to Predict Photocatalytic Process in Removal of Pollutants October 30th, 2014

Production of Biocompatible Polymers in Iran October 30th, 2014

Amorphous Coordination Polymer Particles as alternative to classical nanoplatforms for nanomedicine October 30th, 2014

Interviews/Book Reviews/Essays/Reports/Podcasts/Journals

First Observation of Electronic Structure in Ag-Rh Alloy Nanoparticles Having Hydrogen Absorbing: Storage Property –Attempting to solve the mystery of why Ag-Rh alloy nanoparticles have a similar property to Pd– October 30th, 2014

Iranians Present Model to Predict Photocatalytic Process in Removal of Pollutants October 30th, 2014

Production of Biocompatible Polymers in Iran October 30th, 2014

Amorphous Coordination Polymer Particles as alternative to classical nanoplatforms for nanomedicine October 30th, 2014

Military

Microrockets fueled by water neutralize chemical and biological warfare agents October 29th, 2014

Breakthrough in molecular electronics paves the way for DNA-based computer circuits in the future: DNA-based programmable circuits could be more sophisticated, cheaper and simpler to make October 27th, 2014

NanoTechnology for Defense (NT4D) October 22nd, 2014

Imaging electric charge propagating along microbial nanowires October 20th, 2014

Photonics/Optics/Lasers

Watching the hidden life of materials: Ultrafast electron diffraction experiments open a new window on the microscopic world October 27th, 2014

Physicists build reversible laser tractor beam October 20th, 2014

Magnetic mirrors enable new technologies by reflecting light in uncanny ways October 16th, 2014

IRLYNX and CEA-Leti to Streamline New CMOS-based Infrared Sensing Modules Dedicated to Human-activities Characterization October 15th, 2014

Research partnerships

First Observation of Electronic Structure in Ag-Rh Alloy Nanoparticles Having Hydrogen Absorbing: Storage Property –Attempting to solve the mystery of why Ag-Rh alloy nanoparticles have a similar property to Pd– October 30th, 2014

Sussex physicists find simple solution for quantum technology challenge October 28th, 2014

Molecular beacons shine light on how cells 'crawl' October 27th, 2014

New evidence for an exotic, predicted superconducting state October 27th, 2014

NanoNews-Digest
The latest news from around the world, FREE





  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More














ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







© Copyright 1999-2014 7th Wave, Inc. All Rights Reserved PRIVACY POLICY :: CONTACT US :: STATS :: SITE MAP :: ADVERTISE