Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > Scientists build 'nanobowls' to protect catalysts needed for better biofuel production

Abstract:
It may sound like a post-season football game for very tiny players, but the "nanobowl" has nothing to do with sports and everything to do with improving the way biofuels are produced. That's the hope of a team of scientists from the Institute for Atom Efficient Chemical Transformations (IACT), an Energy Frontier Research Center led by Argonne National Laboratory (ANL), and including Northwestern University, the University of Wisconsin and Purdue University. The team is using a layering technique developed for microchip manufacturing to build nanoscale (billionth of a meter) "bowls" that protect miniature metal catalysts from the harsh conditions of biofuel refining. Furthermore, the size, shape, and composition of the nanobowls can easily be tailored to enhance their functionality and specificity.

Scientists build 'nanobowls' to protect catalysts needed for better biofuel production

College Park, MD | Posted on October 28th, 2012

The team, led by Jeffrey Elam, principal chemist in ANL's Energy Systems Division, will present its research during the AVS 59th International Symposium and Exhibition, held Oct. 28-Nov. 2, 2012, in Tampa, Fla.

In recent years, nanoparticles of metals such as platinum, iridium and palladium supported on metal oxide surfaces have been considered as catalysts to convert biomass - organic matter from plants such as corn, sugarcane and sorghum - into alternative fuels as efficiently as possible. Unfortunately, under typical biorefining conditions where liquid water may reach temperatures of 200 degrees Celsius (392 degrees Fahrenheit) and pressures of 4,100 kilopascals (600 pounds per square inch), the tiny metal nanoparticles can agglomerate into much larger particles which are not catalytically active. Additionally, these extreme conditions can dissolve the support.

"We needed a method to protect the catalysts without reducing their ability to function as desired during biorefining," Elam says. "Our solution was to use atomic layer deposition [ALD], a process commonly employed by the semiconductor industry to lay down single-atom thick layers of material, to build a 'nanobowl' around the metal particle."

To create a matrix of nanobowls containing active catalysts, the researchers first use ALD to deposit millions of metal nanoparticles (the eventual nanocatalysts) onto a support surface. The next step is to add an organic species that will only bind to the metal nanoparticles and not to the support. This organic "protecting group" serves as the mold around which the nanobowls are shaped.

"Again using ALD, we deposit layer upon layer of an inorganic material known as niobia [niobium pentoxide] around the protecting group to define the shape of the nanobowls in our matrix," Elam says. "Once the desired niobia thickness is reached, we remove the protecting groups and leave our metal nanoparticles sheltered in nanobowls that prevent them from agglomerating. In addition, the niobia coating protects the substrate from the extreme conditions encountered during biorefining."

Elam says that the nanobowls themselves can be made to enhance the overall functionality of the catalyst matrix being produced. "At a specific height, we can put down ALD layers of catalytically active material into the nanobowl walls and create a co-catalyst that will work in tandem with the nanocatalysts. Also, by carefully selecting the organic protecting group, we can tune the size and shape of the nanobowl cavities to target specific molecules in the biomass mixture."

Elam and his colleagues have shown in the laboratory that the nanobowl/nanoparticle combination can survive the high-pressure, high-temperature aqueous environment of biomass refining. They also have demonstrated size and shape selectivity for the nanobowl catalysts. The next goal, he says, is to precisely measure how well the catalysts perform in an actual biomass refining process.

MORE INFORMATION ABOUT THE AVS 59th INTERNATIONAL SYMPOSIUM & EXHIBITION

The Tampa Convention Center is located along the Riverwalk in the heart of downtown Tampa at 333 S. Franklin St., Tampa, Florida, 33602.

ABOUT AVS

Founded in 1953, AVS is a not-for-profit professional society that promotes communication between academia, government laboratories, and industry for the purpose of sharing research and development findings over a broad range of technologically relevant topics. Its symposia and journals provide an important forum for the dissemination of information in many areas of science and technology, enabling a critical gateway for the rapid insertion of scientific breakthroughs into manufacturing realities.

####

For more information, please click here

Contacts:
Catherine Meyers

301-209-3088

Copyright © American Institute of Physics (AIP)

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related Links

Main meeting website:

Technical Program:

Housing and Travel Information:

Related News Press

News and information

Study reveals how herpes virus tricks the immune system February 5th, 2016

Hepatitis virus-like particles as potential cancer treatment February 5th, 2016

Organic crystals allow creating flexible electronic devices: The researchers from the Faculty of Physics of the Moscow State University have grown organic crystals that allow creating flexible electronic devices February 5th, 2016

Researchers discover new phase of boron nitride and a new way to create pure c-BN February 5th, 2016

Laboratories

Scientists guide gold nanoparticles to form 'diamond' superlattices: DNA scaffolds cage and coax nanoparticles into position to form crystalline arrangements that mimic the atomic structure of diamond February 4th, 2016

Polar vortices observed in ferroelectric: New state of matter holds promise for ultracompact data storage and processing February 4th, 2016

Putting silicon 'sawdust' in a graphene cage boosts battery performance: Approach could remove major obstacles to increasing the capacity of lithium-ion batteries January 30th, 2016

Breakthrough enables ultra-fast transport of electrical charges in polymers January 30th, 2016

Chemistry

Nature Materials: Smallest lattice structure worldwide: 3-D lattice with glassy carbon struts and braces of less than 200 nm in diameter has higher specific strength than most solids February 3rd, 2016

Researchers develop completely new kind of polymer: Hybrid polymers could lead to new concepts in self-repairing materials, drug delivery and artificial muscles January 30th, 2016

Govt.-Legislation/Regulation/Funding/Policy

Hepatitis virus-like particles as potential cancer treatment February 5th, 2016

Researchers discover new phase of boron nitride and a new way to create pure c-BN February 5th, 2016

Scientists guide gold nanoparticles to form 'diamond' superlattices: DNA scaffolds cage and coax nanoparticles into position to form crystalline arrangements that mimic the atomic structure of diamond February 4th, 2016

Polar vortices observed in ferroelectric: New state of matter holds promise for ultracompact data storage and processing February 4th, 2016

Discoveries

Study reveals how herpes virus tricks the immune system February 5th, 2016

Hepatitis virus-like particles as potential cancer treatment February 5th, 2016

Researchers discover new phase of boron nitride and a new way to create pure c-BN February 5th, 2016

Joint Efforts by Iranian, Malaysian Scientists Produce Antibacterial Coatings for Isolated Areas February 4th, 2016

Announcements

Study reveals how herpes virus tricks the immune system February 5th, 2016

Hepatitis virus-like particles as potential cancer treatment February 5th, 2016

Organic crystals allow creating flexible electronic devices: The researchers from the Faculty of Physics of the Moscow State University have grown organic crystals that allow creating flexible electronic devices February 5th, 2016

Researchers discover new phase of boron nitride and a new way to create pure c-BN February 5th, 2016

Energy

February 4th, 2016

Putting silicon 'sawdust' in a graphene cage boosts battery performance: Approach could remove major obstacles to increasing the capacity of lithium-ion batteries January 30th, 2016

Simplifying solar cells with a new mix of materials: Berkeley Lab-led research team creates a high-efficiency device in 7 steps January 29th, 2016

Scientists provide new guideline for synthesis of fullerene electron acceptors January 28th, 2016

Events/Classes

Nanotech Security to Present at the Optical Document Security Conference February 11, 2016 February 4th, 2016

New research uses nanotechnology to prevent preterm birth: March of Dimes honors abstract on prematurity at SMFM Annual Meeting February 2nd, 2016

NBC LEARN DEBUTS SIX-PART VIDEO SERIES, “NANOTECHNOLOGY: SUPER SMALL SCIENCE” Produced by NBC Learn in partnership with the National Science Foundation, and narrated by NBC News/MSNBC’s Kate Snow, series highlights leading research in nanotechnology January 25th, 2016

Leti to Host Workshop on New Photonics Applications During SPIE Photonics West: Researchers also Will Present Four Invited Papers At Feb. 13-18 Conference, 14 Papers, Overall January 25th, 2016

Research partnerships

Polar vortices observed in ferroelectric: New state of matter holds promise for ultracompact data storage and processing February 4th, 2016

Spin dynamics in an atomically thin semi-conductor February 1st, 2016

Graphene shown to safely interact with neurons in the brain January 31st, 2016

Are some people more likely to develop adverse reactions to nanoparticle-based medicines? January 31st, 2016

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







Car Brands
Buy website traffic