Nanotechnology Now

Our NanoNews Digest Sponsors


Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > Fabrication Method Can Affect the Use of Block Copolymer Thin Films

The method of creating a thin film can have great effect on the material, such as the orientation of the tiny cylinders in this film proposed for use in computer memory. One method of film creation is far more effective at creating copolymer films with cylinders that stand on end (b), as they must to be usable. Scale bar represents 200 nanometers.
Credit: NIST
The method of creating a thin film can have great effect on the material, such as the orientation of the tiny cylinders in this film proposed for use in computer memory. One method of film creation is far more effective at creating copolymer films with cylinders that stand on end (b), as they must to be usable. Scale bar represents 200 nanometers.

Credit: NIST

Abstract:
A new study by a team including scientists from the National Institute of Standards and Technology (NIST) indicates that thin polymer films can have different properties depending on the method by which they are made. The results* suggest that deeper work is necessary to explore the best way of creating these films, which are used in applications ranging from high-tech mirrors to computer memory devices.

Fabrication Method Can Affect the Use of Block Copolymer Thin Films

Gaithersburg, MD | Posted on May 4th, 2012

Thin films spread atop a surface have many applications in industry. Inexpensive organic solar cells might be made of such films, to name one potential use. Typically they're made by dissolving the polymer, and then spreading a small amount of the liquid out on a surface, called a substrate. The solution becomes a film as the solvent dries and the remainder solidifies. But as this happens, stresses develop within the film that can affect its structure.

Manufacturers would like to know more about how to control these stresses to ensure the film does what they want. But scientists who study film formation often use a different method of casting films than a manufacturer would. One method used in industry is "flow coating"—similar to spreading frosting across a cake. Another method is "spin casting"—placing a drop of liquid on a substrate that spins rapidly and spreads the droplet out evenly by centrifugal force. Both methods create smooth films generally, but the team decided to examine whether the two methods create different effects in finished films consisting of a self-assembling block copolymer.

"It's an important question because some proposed applications intend to take advantage of these effects," Douglas says.

The team's comparison led to results that surprised them. Although the rapid spinning of spin casting is very dynamic, suggesting it would convey more stress to the resulting film, it actually led to fewer residual stresses than flow coating did. As previous studies have shown that leftover solvent can lead to stresses in the film, the team's new theory is that because the solvent evaporates from the developing film more slowly in flow coating, this solvent discourages the film solids from arranging themselves into the equilibrium structure.

For one example, the practical benefits of this understanding could help manufacturers who propose making computer memory devices from thin films in which the solids arrange themselves as tiny cylinders in the film. Such devices would require the cylinders to stand on end, not lay down flat.

"We find we can get them to stand up much more easily with one casting method than another," Douglas says. "If we can get better results simply by varying the mode of film casting, we need to explore more deeply what happens when you make films by different methods."
* X. Zhang, J.F. Douglas and R.L. Jones. Influence of film casting method on block copolymer ordering in thin films. Soft Matter, Mar. 21, 2012. doi:10.1039/C2SM07308K.

####

About National Institute of Standards and Technology (NIST)
The National Institute of Standards and Technology (NIST) is an agency of the U.S. Department of Commerce.

For more information, please click here

Contacts:
Chad Boutin
301-975-4261

Copyright © National Institute of Standards and Technology (NIST)

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Personal cooling units on the horizon April 29th, 2016

Exploring phosphorene, a promising new material April 29th, 2016

Arrowhead Pharmaceuticals Files for Regulatory Clearance to Begin Phase 1/2 Study of ARC-521 April 28th, 2016

The Translational Research Center at the University Hospital of Erlangen in Germany uses the ZetaView from Particle Metrix to quantify extracellular vesicles such as exosomes April 28th, 2016

JPK reports on the use of a NanoWizard AFM system at the University of Kaiserslautern to study the interaction of bacteria with microstructured surfaces April 28th, 2016

Laboratories

Exploring phosphorene, a promising new material April 29th, 2016

Brookhaven's Oleg Gang Named a Battelle 'Inventor of the Year': Recognized for work using DNA to guide and regulate the self-assembly of nanoparticles into clusters and arrays with controllable properties April 25th, 2016

Cleaning up hybrid battery electrodes improves capacity and lifespan: New way of building supercapacitor-battery electrodes eliminates interference from inactive components April 22nd, 2016

Thin films

Flipping a chemical switch helps perovskite solar cells beat the heat April 26th, 2016

Thin-film solar cells: How defects appear and disappear in CIGSe cells: Concentration of copper plays a crucial role April 23rd, 2016

Govt.-Legislation/Regulation/Funding/Policy

Personal cooling units on the horizon April 29th, 2016

Exploring phosphorene, a promising new material April 29th, 2016

Nanoparticles hold promise as double-edged sword against genital herpes April 28th, 2016

Arrowhead Pharmaceuticals Files for Regulatory Clearance to Begin Phase 1/2 Study of ARC-521 April 28th, 2016

Memory Technology

Hybrid nanoantennas -- next-generation platform for ultradense data recording April 28th, 2016

Magnetic vortices defy temperature fluctuations: Common magnetic mineral is reliable witness to Earth's history April 19th, 2016

A single-atom magnet breaks new ground for future data storage April 15th, 2016

Topology explains queer electrical current boost in non-magnetic metal: Scientists reduce resistance in PdCoO2 with magnetic fields April 12th, 2016

Discoveries

Personal cooling units on the horizon April 29th, 2016

Exploring phosphorene, a promising new material April 29th, 2016

Nanoparticles hold promise as double-edged sword against genital herpes April 28th, 2016

Researchers create a first frequency comb of time-bin entangled qubits: Discovery is a significant step toward multi-channel quantum communication and higher capacity quantum computers April 28th, 2016

Announcements

Personal cooling units on the horizon April 29th, 2016

Exploring phosphorene, a promising new material April 29th, 2016

Arrowhead Pharmaceuticals Files for Regulatory Clearance to Begin Phase 1/2 Study of ARC-521 April 28th, 2016

The Translational Research Center at the University Hospital of Erlangen in Germany uses the ZetaView from Particle Metrix to quantify extracellular vesicles such as exosomes April 28th, 2016

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







Car Brands
Buy website traffic