Nanotechnology Now

Our NanoNews Digest Sponsors





Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > Molecular frameworks show potential for better solar cells

Fernando Uribe-Romo
Molecular building blocks assemble on graphene to provide oriented and ordered covalent organic frameworks.
Fernando Uribe-Romo
Molecular building blocks assemble on graphene to provide oriented and ordered covalent organic frameworks.

Abstract:
Solar cells made from organic materials are inexpensive, lightweight and flexible, but their performance lags behind cells that contain silicon or other inorganic materials. Cornell chemist William Dichtel and colleagues have found a way to synthesize ordered organic films that could be a major step toward solving this problem.

Molecular frameworks show potential for better solar cells

Ithaca, NY | Posted on April 11th, 2011

It's the first time researchers have been able to coax materials known as covalent organic frameworks (COFs) out of their common powdered form into flat sheets of precisely ordered molecules on a conductive surface. That clears a major hurdle toward using COFs to replace the more expensive, less versatile materials used in solar cells and other electronics today.

The research appears in the April 8 issue of Science.

COFs have a variety of properties that are not found in traditional organic polymers, including excellent thermal stability, high surface area and permanent porosity. But while researchers have identified them as intriguing candidates for such devices, they have been hamstrung by the fact that the materials normally exist only as insoluble powders.

Dichtel, assistant professor of chemistry and chemical biology, and colleagues developed a simple process for growing thin (25-400 nanometers thick) films of COFs on a surface of graphene, a single-atom-thick sheet of carbon. They used X-ray diffraction at the Cornell High Energy Synchrotron Source (CHESS) to determine the materials' structure and orientation. The COFs grow as continuous films of well ordered, stacked layers on the graphene surfaces.

Unlike the powder form, the films grown on transparent surfaces can be probed using modern optical measurements. Researchers can also vary the properties of the frameworks by altering the structure of their components.

"These materials are so versatile -- we can tune the properties rationally, rather than relying on molecules to pack into films unpredictably," Dichtel said.

To demonstrate, the researchers created three variations of the frameworks. Of the three, one shows particular promise for solar cells -- it uses molecules called phthalocyanines, which are commonly found in industrial dyes used in products from blue jeans to ink pens.

Phthalocyanines, which are related to chlorophyll, absorb light over most of the solar spectrum -- a rare property for a single organic material.

"Obtaining these materials as films on electrode materials is a major step toward studying and using them in devices," Dichtel said. "This method represents a general way to assemble molecules on surfaces predictably. This work opens the door to take these materials in many other directions."

The research was funded by Cornell and the National Science Foundation.

####

For more information, please click here

Contacts:
Media Contact:
Blaine Friedlander
(607) 254-8093


Cornell Chronicle:
Susan Lang
(607) 255-3613


Lauren Gold


Chronicle Online
312 College Ave.
Ithaca, NY 14850
607.255.4206

Copyright © Cornell University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Multi-million pound project to use nanotechnology to improve safety September 4th, 2015

Magnetic wormhole connecting 2 regions of space created for the first time: The device could have applications in medicine, opening up ways to make MRIs more comfortable for patients September 4th, 2015

Tongfang Global and QD Vision Partner to Bring Wide Color Gamut to Global Television Lines: Color IQTM quantum dots help boost company’s focus on superior color reproduction September 3rd, 2015

QEOS and GLOBALFOUNDRIES to Offer Industry’s First CMOS Platform for MillimeterWave Markets: GLOBALSOLUTIONSSM Partnership will enable next-generation wireless technologies for applications in IoT, 5G and automotive September 3rd, 2015

Thin films

Atomic Force Microscopes from Asylum Research Guide the Development of Thin Film Deposition and Etch Processes September 2nd, 2015

Hot electrons point the way to perfect light absorption: Physicists study how to achieve perfect absorption of light with the help of rough ultrathin films September 1st, 2015

Using ultrathin sheets to discover new class of wrapped shapes: UMass Amherst materials researchers describe a new regime of wrapped shapes August 31st, 2015

Graphene

For 2-D boron, it's all about that base: Rice University theorists show flat boron form would depend on metal substrates September 2nd, 2015

Phagraphene, a 'relative' of graphene, discovered September 2nd, 2015

Govt.-Legislation/Regulation/Funding/Policy

Magnetic wormhole connecting 2 regions of space created for the first time: The device could have applications in medicine, opening up ways to make MRIs more comfortable for patients September 4th, 2015

Making nanowires from protein and DNA September 3rd, 2015

Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel September 3rd, 2015

Reversible Writing with Light: Self-assembling nanoparticles take their cues from their surroundings September 3rd, 2015

Discoveries

Magnetic wormhole connecting 2 regions of space created for the first time: The device could have applications in medicine, opening up ways to make MRIs more comfortable for patients September 4th, 2015

QEOS and GLOBALFOUNDRIES to Offer Industry’s First CMOS Platform for MillimeterWave Markets: GLOBALSOLUTIONSSM Partnership will enable next-generation wireless technologies for applications in IoT, 5G and automotive September 3rd, 2015

Making nanowires from protein and DNA September 3rd, 2015

Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel September 3rd, 2015

Announcements

Multi-million pound project to use nanotechnology to improve safety September 4th, 2015

Magnetic wormhole connecting 2 regions of space created for the first time: The device could have applications in medicine, opening up ways to make MRIs more comfortable for patients September 4th, 2015

Making nanowires from protein and DNA September 3rd, 2015

Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel September 3rd, 2015

Energy

Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel September 3rd, 2015

For 2-D boron, it's all about that base: Rice University theorists show flat boron form would depend on metal substrates September 2nd, 2015

Phagraphene, a 'relative' of graphene, discovered September 2nd, 2015

RUSNANOPRIZE Directorate Announces New Deadline for Nominations Submission – September 11, 2015 September 1st, 2015

Solar/Photovoltaic

Making fuel from light: Argonne research sheds light on photosynthesis and creation of solar fuel September 3rd, 2015

Phagraphene, a 'relative' of graphene, discovered September 2nd, 2015

Hot electrons point the way to perfect light absorption: Physicists study how to achieve perfect absorption of light with the help of rough ultrathin films September 1st, 2015

Artificial leaf harnesses sunlight for efficient fuel production August 30th, 2015

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







Car Brands
Buy website traffic