Nanotechnology Now

Our NanoNews Digest Sponsors





Heifer International

Wikipedia Affiliate Button


android tablet pc

Home > Press > Molecular frameworks show potential for better solar cells

Fernando Uribe-Romo
Molecular building blocks assemble on graphene to provide oriented and ordered covalent organic frameworks.
Fernando Uribe-Romo
Molecular building blocks assemble on graphene to provide oriented and ordered covalent organic frameworks.

Abstract:
Solar cells made from organic materials are inexpensive, lightweight and flexible, but their performance lags behind cells that contain silicon or other inorganic materials. Cornell chemist William Dichtel and colleagues have found a way to synthesize ordered organic films that could be a major step toward solving this problem.

Molecular frameworks show potential for better solar cells

Ithaca, NY | Posted on April 11th, 2011

It's the first time researchers have been able to coax materials known as covalent organic frameworks (COFs) out of their common powdered form into flat sheets of precisely ordered molecules on a conductive surface. That clears a major hurdle toward using COFs to replace the more expensive, less versatile materials used in solar cells and other electronics today.

The research appears in the April 8 issue of Science.

COFs have a variety of properties that are not found in traditional organic polymers, including excellent thermal stability, high surface area and permanent porosity. But while researchers have identified them as intriguing candidates for such devices, they have been hamstrung by the fact that the materials normally exist only as insoluble powders.

Dichtel, assistant professor of chemistry and chemical biology, and colleagues developed a simple process for growing thin (25-400 nanometers thick) films of COFs on a surface of graphene, a single-atom-thick sheet of carbon. They used X-ray diffraction at the Cornell High Energy Synchrotron Source (CHESS) to determine the materials' structure and orientation. The COFs grow as continuous films of well ordered, stacked layers on the graphene surfaces.

Unlike the powder form, the films grown on transparent surfaces can be probed using modern optical measurements. Researchers can also vary the properties of the frameworks by altering the structure of their components.

"These materials are so versatile -- we can tune the properties rationally, rather than relying on molecules to pack into films unpredictably," Dichtel said.

To demonstrate, the researchers created three variations of the frameworks. Of the three, one shows particular promise for solar cells -- it uses molecules called phthalocyanines, which are commonly found in industrial dyes used in products from blue jeans to ink pens.

Phthalocyanines, which are related to chlorophyll, absorb light over most of the solar spectrum -- a rare property for a single organic material.

"Obtaining these materials as films on electrode materials is a major step toward studying and using them in devices," Dichtel said. "This method represents a general way to assemble molecules on surfaces predictably. This work opens the door to take these materials in many other directions."

The research was funded by Cornell and the National Science Foundation.

####

For more information, please click here

Contacts:
Media Contact:
Blaine Friedlander
(607) 254-8093


Cornell Chronicle:
Susan Lang
(607) 255-3613


Lauren Gold


Chronicle Online
312 College Ave.
Ithaca, NY 14850
607.255.4206

Copyright © Cornell University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

Thin films

Like a hall of mirrors, nanostructures trap photons inside ultrathin solar cells April 22nd, 2014

Nanomaterial Outsmarts Ions April 22nd, 2014

Graphene

Nanomaterial Outsmarts Ions April 22nd, 2014

News and information

Berkeley Lab Researchers Demonstrate First Size-based Chromatography Technique for the Study of Living Cells April 22nd, 2014

PETA science consortium to present hazard testing strategy at nanotoxicology meeting: High tech field ripe for use of sophisticated non-animal testing strategies April 22nd, 2014

Harris & Harris Group Notes the Receipt of Proceeds From the Sale of Molecular Imprints' Semiconductor Business to Canon April 22nd, 2014

National Space Society Congratulates SpaceX on the Success of CRS-3 and the First Flight of the Falcon 9R April 22nd, 2014

Govt.-Legislation/Regulation/Funding/Policy

Cloaked DNA nanodevices survive pilot mission: Successful foray opens door to virus-like DNA nanodevices that could diagnose diseased tissues and manufacture drugs to treat them April 22nd, 2014

Berkeley Lab Researchers Demonstrate First Size-based Chromatography Technique for the Study of Living Cells April 22nd, 2014

Progress made in developing nanoscale electronics: New research directs charges through single molecules April 21st, 2014

'Exotic' material is like a switch when super thin April 18th, 2014

Discoveries

Like a hall of mirrors, nanostructures trap photons inside ultrathin solar cells April 22nd, 2014

Nanomaterial Outsmarts Ions April 22nd, 2014

Vacuum Ultraviolet Lamp of the Future Created in Japan: First Solid-State Vacuum UV Phosphor, Described in APL-Materials, Promises Smaller, Safer, Longer Lasting, Low Power Lamps for Industrial Applications April 22nd, 2014

Berkeley Lab Researchers Demonstrate First Size-based Chromatography Technique for the Study of Living Cells April 22nd, 2014

Announcements

Berkeley Lab Researchers Demonstrate First Size-based Chromatography Technique for the Study of Living Cells April 22nd, 2014

PETA science consortium to present hazard testing strategy at nanotoxicology meeting: High tech field ripe for use of sophisticated non-animal testing strategies April 22nd, 2014

Harris & Harris Group Notes the Receipt of Proceeds From the Sale of Molecular Imprints' Semiconductor Business to Canon April 22nd, 2014

National Space Society Congratulates SpaceX on the Success of CRS-3 and the First Flight of the Falcon 9R April 22nd, 2014

Energy

Like a hall of mirrors, nanostructures trap photons inside ultrathin solar cells April 22nd, 2014

Global leader in solar cell manufacturing eyes New York for major expansion outside of Japan: CNSE and Solar Frontier Explore $700 Million Investment, Job Creation in New York State April 22nd, 2014

Nanoreporters tell 'sour' oil from 'sweet': Rice University's hydrogen sulfide nanoreporters gather intel on oil before pumping April 22nd, 2014

High-temperature plasmonics eyed for solar, computer innovation April 17th, 2014

Solar/Photovoltaic

Like a hall of mirrors, nanostructures trap photons inside ultrathin solar cells April 22nd, 2014

Global leader in solar cell manufacturing eyes New York for major expansion outside of Japan: CNSE and Solar Frontier Explore $700 Million Investment, Job Creation in New York State April 22nd, 2014

High-temperature plasmonics eyed for solar, computer innovation April 17th, 2014

A molecular approach to solar power: Switchable material could harness the power of the sun ó even when itís not shining April 15th, 2014

NanoNews-Digest
The latest news from around the world, FREE







  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More














ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







© Copyright 1999-2014 7th Wave, Inc. All Rights Reserved PRIVACY POLICY :: CONTACT US :: STATS :: SITE MAP :: ADVERTISE