Nanotechnology Now





Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > Cheap catalyst made easy: CWRU researchers aim to bring fuel cells within reach

Abstract:
Catalysts made of carbon nanotubes dipped in a polymer solution equal the energy output and otherwise outperform platinum catalysts in fuel cells, a team of Case Western Reserve University engineers has found.

Cheap catalyst made easy: CWRU researchers aim to bring fuel cells within reach

Cleveland, OH | Posted on March 22nd, 2011

The researchers are certain that they'll be able to boost the power output and maintain the other advantages by matching the best nanotube layout and type of polymer.

But already they've proved the simple technique can knock down one of the major roadblocks to fuel cell use: cost.

Platinum, which represents at least a quarter of the cost of fuel cells, currently sells for about $65,000 per kilogram. These researchers say their activated carbon nanotubes cost about $100 per kilogram.

Their work is published in the online edition of Journal of the American Chemical Society at pubs.acs.org/doi/full/10.1021/ja1112904.

"This is a breakthrough," said Liming Dai, a professor of chemical engineering and the research team leader.

Dai and research associates Shuangyin Wang and Dingshan Yu found that by simply soaking carbon nanotubes in a water solution of the polymer polydiallyldimethylammoniumn chloride for a couple of hours, the polymer coats the nanotube surface and pulls an electron partially from the carbon, creating a net positive charge.

They placed the nanotubes on the cathode of an alkaline fuel cell. There, the charged material acts as a catalyst for the oxygen-reduction reaction that produces electricity while electrochemically combining hydrogen and oxygen.

In testing, the fuel cell produced as much power as an identical cell using a platinum catalyst.

But the activated nanotubes last longer and are more stable, the researchers said. Unlike platinum, the carbon-based catalyst: doesn't lose catalytic activity and, therefore, efficiency, over time; isn't fouled by carbon monooxide poising; and is free from the crossover effect with methanol. Methanol, a liquid fuel that's easier to store and transport than hydrogen, reduces activity of a platinum catalyst when the fuel crosses over from the anode to the cathode in a fuel cell.

The new process builds on the Dai lab's earlier work using nitrogen-doped carbon nanotubes as a catalyst. In that process, nitrogen, which was chemically bonded to the carbon, pulled electron partially from the carbon to create a charge. Testing showed the doped tubes tripled the energy output of platinum.

Dai said the new process is far simpler and cheaper than using nitrogen-doped carbon nanotubes and he's confident his lab will increase the energy output as well. "We have not optimized the system yet."

####

For more information, please click here

Contacts:
Kevin Mayhood

216-368-4442

Copyright © Case Western Reserve University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Basel physicists develop efficient method of signal transmission from nanocomponents May 23rd, 2015

This Slinky lookalike 'hyperlens' helps us see tiny objects: The photonics advancement could improve early cancer detection, nanoelectronics manufacturing and scientists' ability to observe single molecules May 23rd, 2015

Visualizing How Radiation Bombardment Boosts Superconductivity: Atomic-level flyovers show how impact sites of high-energy ions pin potentially disruptive vortices to keep high-current superconductivity flowing May 23rd, 2015

Conversion of Greenhouse Gases to Syngas in Presence of Nanocatalysts in Iran May 22nd, 2015

Nanotubes/Buckyballs/Fullerenes

Basel physicists develop efficient method of signal transmission from nanocomponents May 23rd, 2015

Researchers develop new way to manufacture nanofibers May 21st, 2015

Sandia researchers first to measure thermoelectric behavior by 'Tinkertoy' materials May 20th, 2015

Cotton fibres instead of carbon nanotubes May 9th, 2015

Discoveries

Basel physicists develop efficient method of signal transmission from nanocomponents May 23rd, 2015

This Slinky lookalike 'hyperlens' helps us see tiny objects: The photonics advancement could improve early cancer detection, nanoelectronics manufacturing and scientists' ability to observe single molecules May 23rd, 2015

Visualizing How Radiation Bombardment Boosts Superconductivity: Atomic-level flyovers show how impact sites of high-energy ions pin potentially disruptive vortices to keep high-current superconductivity flowing May 23rd, 2015

Conversion of Greenhouse Gases to Syngas in Presence of Nanocatalysts in Iran May 22nd, 2015

Announcements

Basel physicists develop efficient method of signal transmission from nanocomponents May 23rd, 2015

This Slinky lookalike 'hyperlens' helps us see tiny objects: The photonics advancement could improve early cancer detection, nanoelectronics manufacturing and scientists' ability to observe single molecules May 23rd, 2015

Visualizing How Radiation Bombardment Boosts Superconductivity: Atomic-level flyovers show how impact sites of high-energy ions pin potentially disruptive vortices to keep high-current superconductivity flowing May 23rd, 2015

New Antibacterial Wound Dressing in Iran Can Display Replacement Time May 22nd, 2015

Fuel Cells

Unique microscopic images provide new insights into ionic liquids April 28th, 2015

Expanding the reach of metallic glass April 22nd, 2015

Newly-Developed Nanocatalysts Increase Performance of Fuel Cells April 16th, 2015

Cobalt film a clean-fuel find: Rice University discovery is efficient, robust at drawing hydrogen and oxygen from water April 15th, 2015

NanoNews-Digest
The latest news from around the world, FREE




  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More










ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project