- About Us
- Nano-Social Network
- Nano Consulting
- My Account
|Researchers at Rensselaer Polytechnic Institute developed an entirely new type of nanomaterial that could enable the next generation of high-power rechargeable lithium (Li)-ion batteries for electric automobiles, laptop computers, mobile phones, and other devices. The material, called a “nanoscoop” because it resembles a cone with a scoop of ice cream on top, is shown in the above scanning electron microscope image. Nanoscoops can withstand extremely high rates of charge and discharge that would cause today’s Li-ion batteries to rapidly deteriorate and fail.|
New nanoengineered batteries developed at Rensselaer exhibit remarkable power density, charging more than 40 times faster than today's lithium-ion batteries
An entirely new type of nanomaterial developed at Rensselaer could enable the next generation of high-power rechargeable lithium (Li)-ion batteries for electric automobiles, as well as batteries for laptop computers, mobile phones, and other portable devices.
The new material, dubbed a "nanoscoop" because its shape resembles a cone with a scoop of ice cream on top, can withstand extremely high rates of charge and discharge that would cause conventional electrodes used in today's Li-ion batteries to rapidly deteriorate and fail. The nanoscoop's success lies in its unique material composition, structure, and size.
The Rensselaer research team, led by Professor Nikhil Koratkar, demonstrated how a nanoscoop electrode could be charged and discharged at a rate 40 to 60 times faster than conventional battery anodes, while maintaining a comparable energy density. This stellar performance, which was achieved over 100 continuous charge/discharge cycles, has the team confident that their new technology holds significant potential for the design and realization of high-power, high-capacity Li-ion rechargeable batteries.
"Charging my laptop or cell phone in a few minutes, rather than an hour, sounds pretty good to me," said Koratkar, a professor in the Department of Mechanical, Aerospace, and Nuclear Engineering at Rensselaer. "By using our nanoscoops as the anode architecture for Li-ion rechargeable batteries, this is a very real prospect. Moreover, this technology could potentially be ramped up to suit the demanding needs of batteries for electric automobiles."
Batteries for all-electric vehicles must deliver high power densities in addition to high energy densities, Koatkar said. These vehicles today use supercapacitors to perform power-intensive functions, such as starting the vehicle and rapid acceleration, in conjunction with conventional batteries that deliver high energy density for normal cruise driving and other operations. Koratkar said the invention of nanoscoops may enable these two separate systems to be combined into a single, more efficient battery unit.
Results of the study were detailed in the paper "Functionally Strain-Graded Nanoscoops for High Power Li-Ion Battery Anodes," published Thursday by the journal Nano Letters. See the full paper at: pubs.acs.org/doi/abs/10.1021/nl102981d
The anode structure of a Li-ion battery physically grows and shrinks as the battery charges or discharges. When charging, the addition of Li ions increases the volume of the anode, while discharging has the opposite effect. These volume changes result in a buildup of stress in the anode. Too great a stress that builds up too quickly, as in the case of a battery charging or discharging at high speeds, can cause the battery to fail prematurely. This is why most batteries in today's portable electronic devices like cell phones and laptops charge very slowly - the slow charge rate is intentional and designed to protect the battery from stress-induced damage.
The Rensselaer team's nanoscoop, however, was engineered to withstand this buildup of stress. Made from a carbon (C) nanorod base topped with a thin layer of nanoscale aluminum (Al) and a "scoop" of nanoscale silicon (Si), the structures are flexible and able to quickly accept and discharge Li ions at extremely fast rates without sustaining significant damage. The segmented structure of the nanoscoop allows the strain to be gradually transferred from the C base to the Al layer, and finally to the Si scoop. This natural strain gradation provides for a less abrupt transition in stress across the material interfaces, leading to improved structural integrity of the electrode.
The nanoscale size of the scoop is also vital since nanostructures are less prone to cracking than bulk materials, according to Koratkar.
"Due to their nanoscale size, our nanoscoops can soak and release Li at high rates far more effectively than the macroscale anodes used in today's Li-ion batteries," he said. "This means our nanoscoop may be the solution to a critical problem facing auto companies and other battery manufacturers - how can you increase the power density of a battery while still keeping the energy density high?"
A limitation of the nanoscoop architecture is the relatively low total mass of the electrode, Koratkar said. To solve this, the team's next steps are to try growing longer scoops with greater mass, or develop a method for stacking layers of nanoscoops on top of each other. Another possibility the team is exploring includes growing the nanoscoops on large flexible substrates that can be rolled or shaped to fit along the contours or chassis of the automobile.
Along with Koratkar, authors on the paper are Toh-Ming Lu, the R.P. Baker Distinguished Professor of Physics and associate director of the Center for Integrated Electronics at Rensselaer; and Rahul Krishnan, a graduate student in the Department of Materials Science and Engineering at Rensselaer.
This study was supported by the National Science Foundation (NSF) and the New York State Energy Research and Development Authority (NYSERDA).
For more information, please click here
Phone: (518) 276-6161
Copyright © Rensselaer Polytechnic InstituteIf you have a comment, please Contact us.
Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.
|Related News Press|
News and information
Better living through pressure: Functional nanomaterials made easy April 19th, 2017
SUNY Polytechnic Institute Announces Total of 172 Teams Selected to Compete in Solar in Your Community Challenge: Teams from 40 states, plus Washington, DC, 2 Territories, and 4 American Indian Reservations, Will Deploy Solar in Underserved Communities April 20th, 2017
AIM Photonics Welcomes Coventor as Newest Member: US-Backed Initiative Taps Process Modeling Specialist to Enable Manufacturing of High-Yield, High-Performance Integrated Photonic Designs March 16th, 2017
Nanotubes that build themselves April 14th, 2017
Intertronics introduce new nanoparticle deagglomeration technology March 15th, 2017
New stem cell technique shows promise for bone repair January 25th, 2017
ATTOPSEMI Technology Joins FDXcelerator Program to Deliver Advanced Non-Volatile Memory IP to GLOBALFOUNDRIES 22 FDX® Technology Platform: Leading-edge I-fuse™ brings higher reliability, smaller cell size and ease of programmability for consumer, automotive, and IoT applications March 27th, 2017
Promising results obtained with a new electrocatalyst that reduces the need for platinum: Researchers from Aalto University have succeeded in manufacturing electrocatalysts used for storing electric energy with one-hundredth of the amount of platinum that is usually needed March 24th, 2017
Battery Technology/Capacitors/Generators/Piezoelectrics/Thermoelectrics/Energy storage
Forge Nano 2017: 1st Quarter Media Update April 20th, 2017
Argon is not the 'dope' for metallic hydrogen March 24th, 2017