Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > ORNL scientists reveal battery behavior at the nanoscale

A new electrochemical strain microscopy (ESM) technique developed at Oak Ridge National Laboratory can map lithium ion flow through a battery’s cathode material. This 1 micron x 1 micron composite image demonstrates how regions on a cathode surface display varying electrochemical behaviors when probed with ESM.
A new electrochemical strain microscopy (ESM) technique developed at Oak Ridge National Laboratory can map lithium ion flow through a battery’s cathode material. This 1 micron x 1 micron composite image demonstrates how regions on a cathode surface display varying electrochemical behaviors when probed with ESM.

Abstract:
As industries and consumers increasingly seek improved battery power sources, cutting-edge microscopy performed at the Department of Energy's Oak Ridge National Laboratory is providing an unprecedented perspective on how lithium-ion batteries function.

ORNL scientists reveal battery behavior at the nanoscale

Oak Ridge, TN | Posted on October 20th, 2010

A research team led by ORNL's Nina Balke, Stephen Jesse and Sergei Kalinin has developed a new type of scanning probe microscopy called electrochemical strain microscopy (ESM) to examine the movement of lithium ions through a battery's cathode material. The research, "Nanoscale mapping of ion diffusion in a lithium-ion battery cathode" (Balke et al.), is published in Nature Nanotechnology.

"We can provide a detailed picture of ionic motion in nanometer volumes, which exceeds state-of-the-art electrochemical techniques by six to seven orders of magnitude," Kalinin said. Researchers achieved the results by applying voltage with an ESM probe to the surface of the battery's layered cathode. By measuring the corresponding electrochemical strain, or volume change, the team was able to visualize how lithium ions flowed through the material. Conventional electrochemical techniques, which analyze electric current instead of strain, do not work on a nanoscale level because the electrochemical currents are too small to measure, Kalinin explained.

"These are the first measurements, to our knowledge, of lithium ion flow at this spatial resolution," Kalinin said.

Lithium-ion batteries, which power electronic devices from cell phones to electric cars, are valued for their low weight, high energy density and recharging ability. Researchers hope to extend the batteries' performance by lending engineers a finely tuned knowledge of battery components and dynamics.

"We want to understand - from a nanoscale perspective - what makes one battery work and one battery fail. This can be done by examining its functionality at the level of a single grain or an extended defect," Balke said.

The team's ESM imaging can display features such as individual grains, grain clusters and defects within the cathode material. The high-resolution mapping showed, for example, that the lithium ion flow can concentrate along grain boundaries, which could lead to cracking and battery failure. Researchers say these types of nanoscale phenomena need to be examined and correlated to overall battery functionality.

"Very small changes at the nanometer level could have a huge impact at the device level," Balke said. "Understanding the batteries at this length scale could help make suggestions for materials engineering."

Although the research focused on lithium-ion batteries, the team expects that its technique could be used to measure other electrochemical solid-state systems, including other battery types, fuel cells and similar electronic devices that use nanoscale ionic motion for information storage.

"We see this method as an example of the kinds of higher dimensional scanning probe techniques that we are developing at CNMS that enable us to see the inner workings of complex materials at the nanoscale," Jesse said. "Such capabilities are particularly relevant to the increasingly important area of energy research."

Balke, Jesse and Kalinin are research scientists at ORNL's Center for Nanophase Materials Science. The research team includes Nancy Dudney, Yoongu Kim and Leslie Adamczyk from ORNL's Materials Sciences and Technology Division. The key theoretical results in the work were obtained by Anna Morozovska and Eugene Eliseev at the National Academy of Science of Ukraine and Tony Chung and Edwin Garcia at Purdue University.

This research was supported as part of the Fluid Interface Reactions, Structures and Transport Center, an Energy Frontier Research Center funded by the Department of Energy, Office of Science.

Part of this work was supported by the Center for Nanophase Materials Sciences (CNMS) at ORNL. CNMS is one of the five DOE Nanoscale Science Research Centers supported by the DOE Office of Science, premier national user facilities for interdisciplinary research at the nanoscale. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE's Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos national laboratories.

For more information about the DOE NSRCs, please visit nano.energy.gov.

ORNL is managed by UT-Battelle for the Department of Energy's Office of Science.

####

For more information, please click here

Copyright © Oak Ridge National Laboratory

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Ag/ZnO-Nanorods Schottky diodes based UV-PDs are fabricated and tested May 26th, 2017

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Controlling 3-D behavior of biological cells using laser holographic techniques May 26th, 2017

Unveiling the quantum necklace: Researchers simulate quantum necklace-like structures in superfluids May 26th, 2017

Govt.-Legislation/Regulation/Funding/Policy

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Controlling 3-D behavior of biological cells using laser holographic techniques May 26th, 2017

Unveiling the quantum necklace: Researchers simulate quantum necklace-like structures in superfluids May 26th, 2017

Researchers find new way to control light with electric fields May 25th, 2017

Possible Futures

Ag/ZnO-Nanorods Schottky diodes based UV-PDs are fabricated and tested May 26th, 2017

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Controlling 3-D behavior of biological cells using laser holographic techniques May 26th, 2017

Unveiling the quantum necklace: Researchers simulate quantum necklace-like structures in superfluids May 26th, 2017

Materials/Metamaterials

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Stanford scientists use nanotechnology to boost the performance of key industrial catalyst May 18th, 2017

Self-healing tech charges up performance for silicon-containing battery anodes May 15th, 2017

Discovery of new transparent thin film material could improve electronics and solar cells: Conductivity is highest-ever for thin film oxide semiconductor material May 6th, 2017

Announcements

Ag/ZnO-Nanorods Schottky diodes based UV-PDs are fabricated and tested May 26th, 2017

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Controlling 3-D behavior of biological cells using laser holographic techniques May 26th, 2017

Unveiling the quantum necklace: Researchers simulate quantum necklace-like structures in superfluids May 26th, 2017

Tools

New metamaterial-enhanced MRI technique tested on humans May 26th, 2017

Nanometrics Announces Retirement Plans of CEO Timothy Stultz: Dr. Stultz to Continue as Director May 25th, 2017

Nanomechanics, Inc. to Exhibit at the SEM Conference: Nanoindentation experts will attend and exhibit their instruments at the Conference and Exposition on Experimental and Applied Mechanics in Indianapolis May 25th, 2017

Plasmon-powered upconversion nanocrystals for enhanced bioimaging and polarized emission: Plasmonic gold nanorods brighten lanthanide-doped upconversion superdots for improved multiphoton bioimaging contrast and enable polarization-selective nonlinear emissions for novel nanoscal May 19th, 2017

Energy

Three-dimensional graphene: Experiment at BESSY II shows that optical properties are tuneable May 24th, 2017

Stanford scientists use nanotechnology to boost the performance of key industrial catalyst May 18th, 2017

Fed grant backs nanofiber development: Rice University joins Department of Energy 'Next Generation Machines' initiative May 10th, 2017

Discovery of new transparent thin film material could improve electronics and solar cells: Conductivity is highest-ever for thin film oxide semiconductor material May 6th, 2017

Battery Technology/Capacitors/Generators/Piezoelectrics/Thermoelectrics/Energy storage

Graphene-nanotube hybrid boosts lithium metal batteries: Rice University prototypes store 3 times the energy of lithium-ion batteries May 19th, 2017

Self-healing tech charges up performance for silicon-containing battery anodes May 15th, 2017

Gas gives laser-induced graphene super properties: Rice University study shows inexpensive material can be superhydrophilic or superhydrophobic May 15th, 2017

Is this the 'holey' grail of batteries? May 12th, 2017

Research partnerships

Ag/ZnO-Nanorods Schottky diodes based UV-PDs are fabricated and tested May 26th, 2017

Three-dimensional graphene: Experiment at BESSY II shows that optical properties are tuneable May 24th, 2017

Zap! Graphene is bad news for bacteria: Rice, Ben-Gurion universities show laser-induced graphene kills bacteria, resists biofouling May 22nd, 2017

Sensors detect disease markers in breath May 19th, 2017

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project