Nanotechnology Now

Our NanoNews Digest Sponsors

Heifer International

Wikipedia Affiliate Button

Home > Press > Layered Graphene Sheets Could Solve Hydrogen Storage Issues

A graphene-oxide framework (GOF), formed of layers of graphene connected by boron-carboxylic “pillars.” GOFs such as this one are just beginning to be explored as a potential storage medium for hydrogen and other gases. Credit: NIST
A graphene-oxide framework (GOF), formed of layers of graphene connected by boron-carboxylic “pillars.” GOFs such as this one are just beginning to be explored as a potential storage medium for hydrogen and other gases. Credit: NIST

Abstract:
Graphene—carbon formed into sheets a single atom thick—now appears to be a promising base material for capturing hydrogen, according to recent research* at the National Institute of Standards and Technology (NIST) and the University of Pennsylvania. The findings suggest stacks of graphene layers could potentially store hydrogen safely for use in fuel cells and other applications.

Layered Graphene Sheets Could Solve Hydrogen Storage Issues

Gaithersburg, MD | Posted on March 19th, 2010

Graphene has become something of a celebrity material in recent years due to its conductive, thermal and optical properties, which could make it useful in a range of sensors and semiconductor devices. The material does not store hydrogen well in its original form, according to a team of scientists studying it at the NIST Center for Neutron Research. But if oxidized graphene sheets are stacked atop one another like the decks of a multilevel parking lot, connected by molecules that both link the layers to one another and maintain space between them, the resulting graphene-oxide framework (GOF) can accumulate hydrogen in greater quantities.

Inspired to create GOFs by the metal-organic frameworks that are also under scrutiny for hydrogen storage, the team is just beginning to uncover the new structures' properties. "No one else has ever made GOFs, to the best of our knowledge," says NIST theorist Taner Yildirim. "What we have found so far, though, indicates GOFs can hold at least a hundred times more hydrogen molecules than ordinary graphene oxide does. The easy synthesis, low cost and non-toxicity of graphene make this material a promising candidate for gas storage applications."

The GOFs can retain 1 percent of their weight in hydrogen at a temperature of 77 degrees Kelvin and ordinary atmospheric pressure—roughly comparable to the 1.2 percent that some well-studied metal-organic frameworks can hold, Yildirim says.

Another of the team's potentially useful discoveries is the unusual relationship that GOFs exhibit between temperature and hydrogen absorption. In most storage materials, the lower the temperature, the more hydrogen uptake normally occurs. However, the team discovered that GOFs behave quite differently. Although a GOF can absorb hydrogen, it does not take in significant amounts at below 50 Kelvin (-223 degrees Celsius). Moreover, it does not release any hydrogen below this "blocking temperature"—suggesting that, with further research, GOFs might be used both to store hydrogen and to release it when it is needed, a fundamental requirement in fuel cell applications.

Some of the GOFs' capabilities are due to the linking molecules themselves. The molecules the team used are all benzene-boronic acids that interact strongly with hydrogen in their own right. But by keeping several angstroms of space between the graphene layers—akin to the way pillars hold up a ceiling—they also increase the available surface area of each layer, giving it more spots for the hydrogen to latch on.

According to the team, GOFs will likely perform even better once the team explores their parameters in more detail. "We are going to try to optimize the performance of the GOFs and explore other linking molecules as well," says Jacob Burress, also of NIST. "We want to explore the unusual temperature dependence of absorption kinetics, as well as whether they might be useful for capturing greenhouse gases such as carbon dioxide and toxins like ammonia."

The research is funded in part by the Department of Energy.

* J. Burress, J. Simmons, J. Ford and T.Yildirim. "Gas adsorption properties of graphene-oxide-frameworks and nanoporous benzene-boronic acid polymers." To be presented at the March meeting of the American Physical Society (APS) in Portland, Ore., March 18, 2010. An abstract is available at meetings.aps.org/Meeting/MAR10/Event/122133

####

About NIST
From automated teller machines and atomic clocks to mammograms and semiconductors, innumerable products and services rely in some way on technology, measurement, and standards provided by the National Institute of Standards and Technology.

Founded in 1901, NIST is a non-regulatory federal agency within the U.S. Department of Commerce. NIST's mission is to promote U.S. innovation and industrial competitiveness by advancing measurement science, standards, and technology in ways that enhance economic security and improve our quality of life.

For more information, please click here

Contacts:
Media Contact
Chad Boutin

(301) 975-4261

Copyright © NIST

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

GLOBALFOUNDRIES Announces Availability of 45nm RF SOI to Advance 5G Mobile Communications: Optimized RF features deliver high-performance solutions for mmWave beam forming applications in 5G smartphones and base stations February 22nd, 2017

EmTech Asia breaks new barriers with potential applications of space exploration with NASA and MIT February 22nd, 2017

JPK selects compact tensile stage from Deben for their NanoWizard® AFM platform to broaden capabilities for materials characterisation February 22nd, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Possible Futures

EmTech Asia breaks new barriers with potential applications of space exploration with NASA and MIT February 22nd, 2017

Tiny nanoclusters could solve big problems for lithium-ion batteries February 21st, 2017

Nominations Invited for $250,000 Kabiller Prize in Nanoscience: Major international prize recognizes a visionary nanotechnology researcher February 20th, 2017

Breakthrough with a chain of gold atoms: In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport February 20th, 2017

Discoveries

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Tiny nanoclusters could solve big problems for lithium-ion batteries February 21st, 2017

Oxford Instruments announces Dr Brad Ramshaw of Cornell University, as winner of the 2017 Lee Osheroff Richardson Science Prize February 20th, 2017

Breakthrough with a chain of gold atoms: In the field of nanoscience, an international team of physicists with participants from Konstanz has achieved a breakthrough in understanding heat transport February 20th, 2017

Materials/Metamaterials

EmTech Asia breaks new barriers with potential applications of space exploration with NASA and MIT February 22nd, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Tiny nanoclusters could solve big problems for lithium-ion batteries February 21st, 2017

Oxford Instruments announces Dr Brad Ramshaw of Cornell University, as winner of the 2017 Lee Osheroff Richardson Science Prize February 20th, 2017

Announcements

GLOBALFOUNDRIES Announces Availability of 45nm RF SOI to Advance 5G Mobile Communications: Optimized RF features deliver high-performance solutions for mmWave beam forming applications in 5G smartphones and base stations February 22nd, 2017

EmTech Asia breaks new barriers with potential applications of space exploration with NASA and MIT February 22nd, 2017

JPK selects compact tensile stage from Deben for their NanoWizard® AFM platform to broaden capabilities for materials characterisation February 22nd, 2017

Molecular phenomenon discovered by advanced NMR facility: Cutting edge technology has shown a molecule self-assembling into different forms when passing between solution state to solid state, and back again - a curious phenomenon in science - says research by the University of Wa February 22nd, 2017

Energy

Strem Chemicals and Dotz Nano Ltd. Sign Distribution Agreement for Graphene Quantum Dots Collaboration February 21st, 2017

'Lossless' metamaterial could boost efficiency of lasers and other light-based devices February 20th, 2017

In-cell molecular sieve from protein crystal February 14th, 2017

NREL research pinpoints promise of polycrystalline perovskites February 8th, 2017

Automotive/Transportation

Leti Coordinating Project to Adapt Obstacle-Detection Technology Used in Autonomous Cars for Portable and Wearable Systems: INSPEX to Combine Knowhow of Nine European Organizations to Create Portable and Wearable Spatial-Exploration Systems February 2nd, 2017

Metallic hydrogen, once theory, becomes reality: Harvard physicists succeed in creating 'the holy grail of high-pressure physics' January 28th, 2017

Nanoscale view of energy storage January 16th, 2017

Illinois team advances GaN-on-Silicon for scalable high electron mobility transistors January 10th, 2017

Fuel Cells

Scientists boost catalytic activity for key chemical reaction in fuel cells: New platinum-based catalysts with tensile surface strain could improve fuel cell efficiency December 19th, 2016

It's basic: Alternative fuel cell technology reduces cost: Study sets performance targets for metal-free fuel cell membrane December 13th, 2016

Keeping electric car design on the right road: A closer look at the life-cycle impacts of lithium-ion batteries and proton exchange membrane fuel cells December 9th, 2016

Water vapor sets some oxides aflutter: Newly discovered phenomenon could affect materials in batteries and water-splitting devices October 3rd, 2016

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project