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|Georgia Tech researchers Markus Kindermann, Mei-Yin Chou and Salvador Barraza-Lopez pose with a graphic from their study of metal contacts on graphene. Georgia Tech Photo|
New Study Quantifies the Electron Transport Effects of Placing Metal Contacts onto Graphene
By John Toon
Using large-scale supercomputer calculations, researchers have analyzed how the placement of metallic contacts on graphene changes the electron transport properties of the material as a factor of junction length, width and orientation. The work is believed to be the first quantitative study of electron transport through metal-graphene junctions to examine earlier models in significant detail.
Information on the ways in which attaching metal contacts affects electron transport in graphene will be important to scientists studying the material - and to designers who may one day fabricate electronic devices from the carbon-lattice material.
"Graphene devices will have to communicate with the external world, and that means we will have to fabricate contacts to transport current and data," said Mei-Yin Chou, a professor and department chair in the School of Physics at the Georgia Institute of Technology. "When they put metal contacts onto graphene to measure transport properties, researchers and device designers need to know that they may not be measuring the instrinsic properties of pristine graphene. Coupling between the contacts and the material must be taken into account."
Information on the effects of metal contacts on graphene was reported in the journal Physical Review Letters on February 19th. The research was supported by the U.S. Department of Energy, and involved interactions with researchers at the National Science Foundation (NSF)-supported Materials Research Science and Engineering Center (MRSEC) at Georgia Tech.
Using large-scale, first-principles calculations done at two different NSF-supported supercomputer centers, the Georgia Tech research team - which included postdoctoral fellows Salvador Barraza-Lopez and Mihajlo Vanevic, and assistant professor Markus Kindermann - conducted detailed atomic-level calculations of aluminum contacts grown on graphene.
The calculations studied two contacts up to 14 nanometers apart, with graphene suspended between them. In their calculations, the researchers allowed the aluminum to grow as it would in the real world, then studied how electron transfer was induced in the area surrounding the contacts.
"People have been able to come up with phenomenological models that they use to find out what the effects are with metallic contacts," Chou explained. "Our calculations went a few steps farther because we built contacts atom-by-atom. We built atomistically-resolved contacts, and by doing that, we solved this problem at the atomic level and tried to do everything consistent with quantum mechanics."
Because metals typically have excess electrons, physically attaching the contacts to graphene causes a charge transfer from the metal. Charge begins to be transferred as soon as the contracts are constructed, but ultimately the two materials reach equilibrium, Chou said.
The study showed that charge transfer at the leads and into the freestanding section of the material creates an electron-hole asymmetry in the conductance. For leads that are sufficiently long, the effect creates two conductance minima at the energies of the Dirac points for the suspended and clamped regions of the graphene, according to Barraza-Lopez.
"These results could be important to the design of future graphene devices," he said. "Edge effects and the impact of nanoribbon width have been studied in significant detail, but the effects of charge transfer at the contacts may potentially be just as important."
The researchers modeled aluminum, but believe their results will apply to other metals such as copper and gold that do not form chemical bonds with graphene. However, other metals such as chromium and titanium do chemically alter the material, so the effects they have on electron transport may be different.
Beyond the new information provided by the calculations, the research further proposes quantitative models that can be used under certain circumstances to describe the impact of the contacts.
"Earlier models had been based on physical insights, but nobody really knew how faithfully they described the material," Kindermann said. "This is the first calculation to show that these earlier models apply under certain circumstances for the systems that we studied."
Data from the study may one day help device designers engineer graphene circuits by helping them understand the effects they are seeing.
"When we modify graphene, we need to understand what changes occur as a result of adding materials," added Chou. "This is really fundamental research to understand these effects and to have a numerical prediction for what is going on. We are helping to understand the basic physics of graphene."
This research was supported by Department of Energy grant DE-FG02-97ER45632. Comments and conclusions in this article are those of the researchers and do not necessarily reflect the views of the Department of Energy.
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