Nanotechnology Now

Our NanoNews Digest Sponsors





Heifer International

Wikipedia Affiliate Button


DHgate

Home > Press > DARPA awards research team $1.2M grant to study surface enhanced Raman scattering

Abstract:
The Defense Advanced Research Projects Agency (DARPA) has awarded a $1.2 million grant to an interdisciplinary team of Harvard University researchers to study surface enhanced Raman scattering (SERS) for the first phase of a potential three-year effort.

DARPA awards research team $1.2M grant to study surface enhanced Raman scattering

Cambridge, MA | Posted on July 17th, 2008

If all phases of the development program are completed, researchers could receive up a total of up to $2.9 million in funding.

Ken Crozier, Assistant Professor of Electrical Engineering at the School of Engineering and Applied Sciences (SEAS) will serve as the principal investigator for the grant. His co-investigators include Eric Mazur, Balkanski Professor of Physics and Applied Physics at SEAS and the Department of Physics and Alán Aspuru-Guzik, Assistant Professor of Chemistry and Chemical Biology at the Department of Chemistry and Chemical Biology.

SERS relies upon a fundamental phenomenon in physics called the Raman effect—the change in the frequency of monochromatic light (such as a laser) when it passes through a substance. Properly harnessed, Raman scattering can identify specific molecules by detecting their characteristic spectral fingerprints. Potential applications of SERS include the sensing and identification of a range of materials, including chemical and biological agents, improvised explosive devices, and toxic industrial waste.

"While SERS offers enormous potential for chemical detection and sensing, its practical use has been hampered by the need for improved knowledge of the fundamentals of the enhancement mechanisms," says Crozier.

It turns out that Raman scattering cross sections are very small, about 1012-1014 times smaller than fluorescence cross sections. In the 1970's scientists discovered that by placing molecules on roughened metal surfaces they could achieve significantly larger Raman signals, enabling the detection of molecules. Nevertheless the gain has not been enough to make SERS readily usable in detection devices.

"By applying recent advances in optical antennas, laser nanostructuring, and theoretical chemistry, we aim to elucidate the fundamental mechanisms underlying SERS and demonstrate high-performance SERS substrates that will enable the technology to go to the next stage of development," says Crozier.

In particular, the team will utilize Crozier's recent work on optical antennas, metallic nanostructures that are able to generate intense electric fields, by modelling, fabricating and characterizing SERS optical antenna chips. SERS measurements on these chips will allow precise determination of the effects of optical antenna parameters, such as size, shape and spacing requirements, on SERS enhancement.

Likewise, to fabricate large area SERS substrates, the researchers will employ Mazur's expertise in femtosecond laser-nanostructured (FSLN) semiconductor surfaces, or what is more commonly known as "black silicon." Because not all metallic nanoparticles are equally SERS-active, they will also create a screening process to separate the two.

Finally, by relying on Aspuru-Guzik's expertise in theoretical modeling the team will investigate the interplay between chemical and electromagnetic enhancement and, based upon their findings, develop an integrated electronic structure package in a complex electromagnetic environment.

To help foster the research, Crozier plans to collaborate with two existing Harvard-based centers, the Nanoscale Science and Engineering Center and the Center for Nanoscale Systems, a member of the National Nanotechnology Infrastructure Network.

####

For more information, please click here

Contacts:
Michael Patrick Rutter

617-496-3815

Copyright © Harvard University

If you have a comment, please Contact us.

Issuers of news releases, not 7th Wave, Inc. or Nanotechnology Now, are solely responsible for the accuracy of the content.

Bookmark:
Delicious Digg Newsvine Google Yahoo Reddit Magnoliacom Furl Facebook

Related News Press

News and information

Reversible Writing with Light: Self-assembling nanoparticles take their cues from their surroundings September 3rd, 2015

For 2-D boron, it's all about that base: Rice University theorists show flat boron form would depend on metal substrates September 2nd, 2015

Silk bio-ink could help advance tissue engineering with 3-D printers September 2nd, 2015

Phagraphene, a 'relative' of graphene, discovered September 2nd, 2015

Govt.-Legislation/Regulation/Funding/Policy

Reversible Writing with Light: Self-assembling nanoparticles take their cues from their surroundings September 3rd, 2015

For 2-D boron, it's all about that base: Rice University theorists show flat boron form would depend on metal substrates September 2nd, 2015

Silk bio-ink could help advance tissue engineering with 3-D printers September 2nd, 2015

A marine creature's magic trick explained: Crystal structures on the sea sapphire's back appear differently depending on the angle of reflection September 2nd, 2015

Announcements

Reversible Writing with Light: Self-assembling nanoparticles take their cues from their surroundings September 3rd, 2015

Silk bio-ink could help advance tissue engineering with 3-D printers September 2nd, 2015

Phagraphene, a 'relative' of graphene, discovered September 2nd, 2015

A marine creature's magic trick explained: Crystal structures on the sea sapphire's back appear differently depending on the angle of reflection September 2nd, 2015

Military

Seeing quantum motion August 30th, 2015

These microscopic fish are 3-D-printed to do more than swim: Researchers demonstrate a novel method to build microscopic robots with complex shapes and functionalities August 26th, 2015

Nanotechnology that will impact the Security & Defense sectors to be discussed at NanoSD2015 conference August 25th, 2015

Industrial Nanotech, Inc. Provides Update On Hospital Project, PCAOB Audit, and New Heat Shield™ Line August 24th, 2015

Grants/Awards/Scholarships/Gifts/Contests/Honors/Records

Reversible Writing with Light: Self-assembling nanoparticles take their cues from their surroundings September 3rd, 2015

A marine creature's magic trick explained: Crystal structures on the sea sapphire's back appear differently depending on the angle of reflection September 2nd, 2015

RUSNANOPRIZE Directorate Announces New Deadline for Nominations Submission – September 11, 2015 September 1st, 2015

$200K Awarded to Develop In Vitro Lung Test for Toxicity of Inhaled Nanomaterials: In Vitro Lung Test Designed to Protect Human Health and Replace Animal Testing September 1st, 2015

NanoNews-Digest
The latest news from around the world, FREE



  Premium Products
NanoNews-Custom
Only the news you want to read!
 Learn More
NanoTech-Transfer
University Technology Transfer & Patents
 Learn More
NanoStrategies
Full-service, expert consulting
 Learn More











ASP
Nanotechnology Now Featured Books




NNN

The Hunger Project







Car Brands
Buy website traffic